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vanadium dichloride oxide

Product Name
vanadium dichloride oxide
CAS No.
10213-09-9
Chemical Name
vanadium dichloride oxide
Synonyms
VANADYLOXYCHLORIDE;Vanadyl dichloride;dichlorooxovanadium;VANADYLOXYDICHLORIDE;dichlorooxo-Vanadium;Vanadium oxydichloride;Vanadium, dichlorooxo-;Dichlorooxovanadium(IV);Vanadium(IV) oxychloride;vanadium dichloride oxide
CBNumber
CB8930824
Molecular Formula
Cl2OV+
Formula Weight
137.8469
MOL File
10213-09-9.mol
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vanadium dichloride oxide Property

Density 
2.88
solubility 
reacts with H2O; soluble in ethanol
form 
green hygroscopic crystals
color 
green hygroscopic crystals, crystalline
Water Solubility 
slowly decomposed in water; soluble absolute alcohol, glacial acetic acid [MER06]
EPA Substance Registry System
Vanadium, dichlorooxo- (10213-09-9)
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Safety

RIDADR 
2923
HazardClass 
8
PackingGroup 
III
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P363Wash contaminated clothing before reuse.

P405Store locked up.

P501Dispose of contents/container to..…

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vanadium dichloride oxide Chemical Properties,Usage,Production

Chemical Properties

Green, deliquescent crystal. Usual technical product is a dark-green, syrupymass, 76–82% pure, or a solution. Slowly decomposed by water; soluble in water, alcohol, and acetic acid; may react violently with potassium.

Uses

Vanadium Dichloride Oxide has been used as mordant in printing fabrics.

Preparation

A thoroughly ground mixture of 3.6 g. of dry V2O5 and 9.4 g. of VCl3 is placed at the closed end of a l-m.-longtube, and 0.9 ml. of VOCl3 is then added. The upper part of the tube must be free of traces of these substances. The tube, filled with air, is melt-sealed, and is covered along its entire length with a sheet-metal jacket; its lower third, in a slightly inclined position, is then heated to about 600℃ with a tubular electric furnace. The sheet-metal jacket provides a temperature gradient along which the product VOCl2 sublimes out of the hot reaction zone. This procedure requires at least 4-5 days. However, the yield can be increased by longer heating time. Green needlelike crystals of VOCl2 are deposited in the cold part of the tube. The tube is opened at a suitable spot; the product is suspended in petroleum ether, ethyl ether or CCl4 to dissolve some adhering VOCl3, and then suction-filtered on a coarse fritted-glass filter. The relatively coarse filter separates the VOCl2 crystals from traces of finely divided hydrolysis products. The VOCl2 is freed of adhering solvent and stored under anhydrous conditions.

Hazard

Strong irritant to tissue.

vanadium dichloride oxide Preparation Products And Raw materials

Raw materials

Preparation Products

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vanadium dichloride oxide Suppliers

Shaanxi Dideu Newmaterial Co., Ltd.
Tel
029-87576359 15353716720
Email
1039@dideu.com
Country
China
ProdList
10009
Advantage
58
Baoji Funuokang Industrial Co., Ltd
Tel
13220096790
Email
1754423088@qq.com
Country
China
ProdList
2998
Advantage
58
Shaanxi Didu New Materials Co. Ltd
Tel
+86-89586680 +86-13289823923
Email
1026@dideu.com
Country
China
ProdList
8670
Advantage
58

10213-09-9, vanadium dichloride oxideRelated Search:


  • vanadium dichloride oxide
  • Vanadium oxydichloride
  • Vanadyl dichloride
  • VANADYLOXYCHLORIDE
  • VANADYLOXYDICHLORIDE
  • dichlorooxovanadium
  • dichlorooxo-Vanadium
  • Dichlorooxovanadium(IV)
  • Vanadium(IV) dichloride oxide
  • Vanadium(IV) dichlorideoxide
  • Vanadium(IV) oxidedichloride
  • Vanadium(IV) oxychloride
  • Vanadium, dichlorooxo-
  • oxovanadium,dihydrochloride
  • 10213-09-9