LANTHANUM TRIS[BIS(TRIMETHYLSILYL)AMIDE]

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Product Name: LANTHANUM TRIS[BIS(TRIMETHYLSILYL)AMIDE]
CAS No.: 175923-07-6
Chemical Name: LANTHANUM TRIS[BIS(TRIMETHYLSILYL)AMIDE]
Synonyms: )amide]L;LANTHANUM TRIS(HEXAMETHYLDISILAZIDE);LANTHANUM TRIS[BIS(TRIMETHYLSILYL)AMIDE];bis(trimethylsilyl)azanide,lanthanum(3+);TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDO]LANTHANUM;Tris[N,N-bis(trimethylsilyl)amide]lanthanum;Tris[N,N-bis(trimethylsilyl)amide]lanthanum(Ⅲ);TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]LANTHANUM (III);Lanthanum (III) tris[N,N-bis(trimethylsiyl)amide];TrisN,N-bis(trimethylsilyl)amideülanthanum(III), 97%
CBNumber: CB9113132
Molecular Formula: C18H54LaN3Si6
Formula Weight: 620.06
MOL File: 175923-07-6.mol

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LANTHANUM TRIS[BIS(TRIMETHYLSILYL)AMIDE] Property

Melting point:: 149-153 °C(lit.)
Flash point:: 36 °F
form: Powder
color: white
Sensitive: Air & Moisture Sensitive

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Safety

Hazard Codes: F,C
Risk Statements: 11-14/15-34
Safety Statements: 16-26-36/37/39-43-45-7/8
RIDADR: UN 3396 4.3/PG 2
WGK Germany: 3
HazardClass: 4.1
PackingGroup: II

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H228Flammable solid

H261In contact with water releases flammable gas

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P231+P232Handle under inert gas. Protect from moisture.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 547778
Product name: Tris[N,N-bis(trimethylsilyl)amide]lanthanum(III)
Purity: 98%
Packaging: 1g
Price: $106
Updated: 2023/06/20

Strem Chemicals

Product number: 57-0510
Product name: Tris(N,N-bis(trimethylsilyl)amide)lanthanum(III), min. 98% (99.9%-La) (REO)
Packaging: 5g
Price: $275
Updated: 2021/12/16

Strem Chemicals

Product number: 57-0510
Product name: Tris(N,N-bis(trimethylsilyl)amide)lanthanum(III), min. 98% (99.9%-La) (REO)
Packaging: 1g
Price: $68
Updated: 2021/12/16

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LANTHANUM TRIS[BIS(TRIMETHYLSILYL)AMIDE] Chemical Properties,Usage,Production

Reactions

Catalyst precursor for enantioselective intramolecular hydroamination of aminoalkenes and aminodienes.
Catalyzes a mild and highly selective addition of terminal alkynes to nitriles to form conjugated ynones.
Catalytic amidation of aldehydes with amines.

reaction suitability

core: lanthanum
reagent type: catalyst

LANTHANUM TRIS[BIS(TRIMETHYLSILYL)AMIDE] Preparation Products And Raw materials

Raw materials

Preparation Products

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LANTHANUM TRIS[BIS(TRIMETHYLSILYL)AMIDE] Suppliers

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