(9-ANTHRYLMETHYLENE)MALONONITRILE
- Product Name
- (9-ANTHRYLMETHYLENE)MALONONITRILE
- CAS No.
- 55490-87-4
- Chemical Name
- (9-ANTHRYLMETHYLENE)MALONONITRILE
- Synonyms
- TIMTEC-BB SBB000932;RARECHEM AL BX 0006;(9-Anthrylmethylene)malonoitrile;(9-ANTHRYLMETHYLENE)MALONONITRILE;(9-anthrylmethylene)-malononitril;2-(9-ANTHRYLMETHYLENE)MALONONITRILE;2-(9-Anthrylmethylidene)malononitrile;2-(anthracen-9-ylMethylene)Malononitrile;(Anthracen-9-ylmethylidene)propanedinitrile;Propanedinitrile, 2-(9-anthracenylmethylene)-
- CBNumber
- CB9123827
- Molecular Formula
- C18H10N2
- Formula Weight
- 254.29
- MOL File
- 55490-87-4.mol
(9-ANTHRYLMETHYLENE)MALONONITRILE Property
- storage temp.
- 2-8°C
Safety
- Hazard Codes
- Xi
- HazardClass
- IRRITANT
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- R128503
- Product name
- 2-(9-ANTHRYLMETHYLENE)MALONONITRILE
- Purity
- AldrichCPR
- Packaging
- 50MG
- Price
- $30.7
- Updated
- 2025/07/31
- Product number
- 5550AE
- Product name
- (9-Anthrylmethylene)malononitrile
- Packaging
- 100mg
- Price
- $158
- Updated
- 2021/12/16
- Product number
- 016553
- Product name
- (9-Anthrylmethylene)malononitrile
- Purity
- 98%
- Packaging
- 250mg
- Price
- $205
- Updated
- 2021/12/16
- Product number
- 5550AE
- Product name
- (9-Anthrylmethylene)malononitrile
- Packaging
- 1g
- Price
- $482
- Updated
- 2021/12/16
- Product number
- CHM0960530
- Product name
- (9-ANTHRYL METHYLENE)METHANE-1,1-DICARBONITRILE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $497.99
- Updated
- 2021/12/16
(9-ANTHRYLMETHYLENE)MALONONITRILE Chemical Properties,Usage,Production
Synthesis
642-31-9
109-77-3
55490-87-4
GENERAL METHODS: A mixture of 9-anthracenecarboxaldehyde (10.0 mmol), malononitrile (11.0 mmol) and pyridine (10.0 mmol) was stirred for 6 hours at 95 °C. The reaction process was monitored by thin layer chromatography (TLC). After completion of the reaction, water (10 mL) was added to the reaction mixture and extracted with dichloromethane (3 x 10 mL). The organic layers were combined and dried with anhydrous sodium sulfate, followed by evaporation of the solvent under vacuum. The crude product was purified by column chromatography using hexane as eluent, resulting in (9-anthracenemethylene)malononitrile (1a-m), which was structurally characterized.
References
[1] Journal of Chemical Research, 2012, vol. 36, # 6, p. 328 - 332
[2] Journal of the Chinese Chemical Society, 2013, vol. 60, # 1, p. 35 - 44
[3] Synthetic Communications, 2018, vol. 48, # 17, p. 2169 - 2176
[4] Journal of the American Chemical Society, 2017, vol. 139, # 14, p. 4995 - 4998
[5] Journal of the American Chemical Society, 2008, vol. 130, # 12, p. 3937 - 3941
(9-ANTHRYLMETHYLENE)MALONONITRILE Preparation Products And Raw materials
Raw materials
Preparation Products
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