[1,1-Biphenyl]-2-ol,3-methyl-(9CI)
- Product Name
- [1,1-Biphenyl]-2-ol,3-methyl-(9CI)
- CAS No.
- 17755-10-1
- Chemical Name
- [1,1-Biphenyl]-2-ol,3-methyl-(9CI)
- Synonyms
- 3-Methylbiphenyl-2-ol;2-Methyl-6-phenylphenol;2-(3-Methylphenyl)phenol;1,1-Biphenyl]-2-ol, 3-Methyl;3-Methyl-[1,1'-biphenyl]-2-ol;[1,1-Biphenyl]-2-ol,3-methyl-(9CI)
- CBNumber
- CB91302726
- Molecular Formula
- C13H12O
- Formula Weight
- 184.23
- MOL File
- 17755-10-1.mol
[1,1-Biphenyl]-2-ol,3-methyl-(9CI) Property
- Density
- 1.087
- storage temp.
- Sealed in dry,Room Temperature
- Appearance
- Colorless to light yellow Liquid
N-Bromosuccinimide Price
- Product number
- 9319AA
- Product name
- 3-Methyl-[1,1'-biphenyl]-2-ol
- Packaging
- 100mg
- Price
- $151
- Updated
- 2021/12/16
- Product number
- FB151932
- Product name
- [1,1-Biphenyl]-2-ol,3-methyl-(9ci)
- Packaging
- 250mg
- Price
- $200
- Updated
- 2021/12/16
- Product number
- FB151932
- Product name
- [1,1-Biphenyl]-2-ol,3-methyl-(9ci)
- Packaging
- 500mg
- Price
- $300
- Updated
- 2021/12/16
- Product number
- FB151932
- Product name
- [1,1-Biphenyl]-2-ol,3-methyl-(9ci)
- Packaging
- 1g
- Price
- $450
- Updated
- 2021/12/16
- Product number
- CHM0389283
- Product name
- 3-METHYL-[1,1'-BIPHENYL]-2-OL
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $495.19
- Updated
- 2021/12/16
[1,1-Biphenyl]-2-ol,3-methyl-(9CI) Chemical Properties,Usage,Production
Synthesis
95-48-7
144930-50-7
17755-10-1
The general procedure for the synthesis of 3-methylbiphenyl-2-ol from o-cresol and homotrimethylphenyl(phenyl)iodonium trifluoromethanesulfonate was as follows: to a reaction tube containing [Rh(cod)Cl]2 (3.08 mg, 0.00625 mmol), tBuOLi (40.0 mg, 0.5 mmol), diaryl iodide trifluoromethanesulfonate (0.325 mmol , 1.3 equiv) and CH3CN (2.0 mL) were added to o-cresol (0.25 mmol) and P(NMe2)3 (8.16 mg, 0.05 mmol) in a reaction tube. The reaction mixture was stirred at 130 °C for 12 h under nitrogen protection. After completion of the reaction, it was cooled to room temperature and ethyl acetate (10.0 mL) and aqueous 2N hydrochloric acid (5.0 mL) were added to the mixture and stirred vigorously for 30 min. Subsequently, the aqueous phase was extracted three times with ethyl acetate, and the organic phases were combined and washed with saturated NaHCO3 solution. The organic phase was dried with anhydrous MgSO4, filtered and passed through a diatomaceous earth pad and finally concentrated under reduced pressure. The crude product was purified by fast chromatography using hexane/ethyl acetate (30:1) as eluent.
References
[1] Tetrahedron, 2017, vol. 73, # 26, p. 3591 - 3595
[1,1-Biphenyl]-2-ol,3-methyl-(9CI) Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from [1,1-Biphenyl]-2-ol,3-methyl-(9CI) manufacturers
- Product
- [1,1-Biphenyl]-2-ol,3-methyl-(9CI) 17755-10-1
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98% HPLC
- Supply Ability
- 10 tons
- Release date
- 2020-02-02