cyclopropanol
- Product Name
- cyclopropanol
- CAS No.
- 16545-68-9
- Chemical Name
- cyclopropanol
- Synonyms
- cyclopropyl alcohol;opropanoL;cyclopropanol;2-Cyclopropanol;Cyclopropane-1-ol;(1α)-Cyclopropanol;Hydroxycyclopropane;16545-68-9, CFCD16545689;Cyclopropanol (7CI, 8CI, 9CI, ACI);1H-Benzimidazole-1-carboxylicacid,2,3-dihydro-3-oxo-,ethylester
- CBNumber
- CB91318019
- Molecular Formula
- C3H6O
- Formula Weight
- 58.08
- MOL File
- 16545-68-9.mol
cyclopropanol Property
- Melting point:
- 180℃
- Boiling point:
- 101-102℃ (760 Torr)
- Density
- 9.9110 g/cm3
- refractive index
- 1.4129 (589.3 nm 20℃)
- storage temp.
- 2-8°C
- pka
- 15.31±0.20(Predicted)
- Appearance
- Colorless to light yellow Liquid
- InChI
- InChI=1S/C3H6O/c4-3-1-2-3/h3-4H,1-2H2
- InChIKey
- YOXHCYXIAVIFCZ-UHFFFAOYSA-N
- SMILES
- C1(O)CC1
Safety
- RIDADR
- UN1993
- HazardClass
- 3
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H301Toxic if swalloed
H318Causes serious eye damage
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P310Immediately call a POISON CENTER or doctor/physician.
P321Specific treatment (see … on this label).
P330Rinse mouth.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- C992575
- Product name
- Cyclopropanol
- Packaging
- 1g
- Price
- $105
- Updated
- 2021/12/16
- Product number
- FC46491
- Product name
- Cyclopropanol
- Packaging
- 100mg
- Price
- $70
- Updated
- 2021/12/16
- Product number
- FC46491
- Product name
- Cyclopropanol
- Packaging
- 250mg
- Price
- $125
- Updated
- 2021/12/16
- Product number
- FC46491
- Product name
- Cyclopropanol
- Packaging
- 500mg
- Price
- $200
- Updated
- 2021/12/16
- Product number
- FC46491
- Product name
- Cyclopropanol
- Packaging
- 1g
- Price
- $300
- Updated
- 2021/12/16
cyclopropanol Chemical Properties,Usage,Production
Description
Cyclopropanols can be readily synthesized via synthetic transformations such as the Kulinkovich cyclopropanation and the Simmons-Smith reaction [1]. Due to the high strains built intrinsically in the three-membered ring, cyclopropanols and their derivatives are highly reactive and can undergo various ring opening/expansion/fragmentation reactions. A significant amount of these ring opening/expansion/fragmentation reactions are catalyzed/promoted by transition metal complexes. In many of these cases, cyclopropanols and their derivatives are considered as the equivalents of homoenolates or β-alkyl radicals.
Uses
Cyclopropanol is a basic building block.
Definition
ChEBI: Cyclopropanol is a cyclopropane in which a hydrogen atom is replaced by a hydroxy group. It is a member of cyclopropanes and an aliphatic alcohol.
Synthesis
411235-57-9
16545-68-9
Step 1: Synthesis of cyclopropyl-1-ol Cyclopropylboronic acid (10 g, 0.116 mol) and aqueous sodium hydroxide (8.37 g, 0.209 mol, dissolved in 100 mL of water) were added to a 1 L reaction flask. Under the cooling of an ice bath, 34% hydrogen peroxide (80 mL) was slowly added dropwise, keeping the reaction temperature not higher than 5 °C. After the dropwise addition, the reaction mixture was continued to be stirred at 5°C for 1 hour. Upon completion of the reaction, saturated aqueous sodium thiosulfate solution was added slowly and dropwise to quench the reaction until the potassium iodide-starch test paper no longer showed color. The reaction solution was extracted with ether three times, the organic phases were combined, washed with saturated brine, dried with anhydrous desiccant, filtered and concentrated under reduced pressure at 0 °C to give cyclopropan-1-ol (colorless oil, 4 g, 60% yield). The product did not need further purification and could be used directly in the subsequent reaction. (MS detection: [M+1] not observed)
References
[1] Xinpei Cai, Mingji Dai, Weida Liang. “Total syntheses via cyclopropanols.” Tetrahedron 75 2 (2019): Pages 193-208.
cyclopropanol Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from cyclopropanol manufacturers
- Product
- cyclopropanol 16545-68-9
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98.0%
- Supply Ability
- 10000KGS
- Release date
- 2025-07-04
- Product
- cyclopropanol 16545-68-9
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 96%
- Supply Ability
- 500kg
- Release date
- 2018-08-20