(CARBOETHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATE

Product Name: (CARBOETHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATE
CAS No.: 17577-28-5
Chemical Name: (CARBOETHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATE
Synonyms: (ETHOXYCARBONYLMETHYL)TRIPHENYL PHOSPHO&;ethyl (triphenylphosphonio)acetate chloride;CARBETHOXYMETHYLTRIPHENYLPHOSPHONIUM CHLORIDE;(CARBOETHOXYMETHYL)-TRIPHENYLPHOSPHONIUMCHLORID;(4-ETHOXYCARBONYL)TRIPHENYLPHOSPHONIUM CHLORIDE;(CARBOETHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE;(2-ethoxy-2-oxoethyl)triphenylphosphonium chloride;(ETHOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE;(ETHOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE 97%;(CARBOETHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATE
CBNumber: CB9136801
Molecular Formula: C22H22O2P.Cl
Formula Weight: 384.84
MOL File: 17577-28-5.mol

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(CARBOETHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATE Property

Melting point:: 120-123 °C (dec.) 120-123 °C (lit.)
storage temp.: 2-8°C
Appearance: White to off-white Solid
Sensitive: Hygroscopic
BRN: 3924139
InChI: 1S/C22H22O2P.ClH/c1-2-24-22(23)18-25(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21;/h3-17H,2,18H2,1H3;1H/q+1;/p-1
InChIKey: DJGHVEPNEJKZBF-UHFFFAOYSA-M
SMILES: [Cl-].CCOC(=O)C[P+](c1ccccc1)(c2ccccc2)c3ccccc3
CAS DataBase Reference: 17577-28-5(CAS DataBase Reference)
EPA Substance Registry System: Phosphonium, (2-ethoxy-2-oxoethyl)triphenyl-, chloride (17577-28-5)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3
F: 9
TSCA: TSCA listed
HS Code: 29319019
Storage Class: 11 - Combustible Solids
Hazard Classifications: Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 02615
Product name: (Ethoxycarbonylmethyl)triphenylphosphonium chloride
Purity: technical, ≥90% (AT)
Packaging: 100g
Price: $313
Updated: 2023/06/20

American Custom Chemicals Corporation

Product number: ING0003216
Product name: (ETHOXY CARBONYLMETHYL)TRIPHENYL PHOSPHONIUM CHLORIDE
Purity: 95.00%
Packaging: 100G
Price: $2811.15
Updated: 2021/12/16

Ambeed

Product number: A1372051
Product name: (2-Ethoxy-2-oxoethyl)triphenylphosphoniumchloride
Purity: 97%
Packaging: 25g
Price: $16
Updated: 2021/12/16

Ambeed

Product number: A1372051
Product name: (2-Ethoxy-2-oxoethyl)triphenylphosphoniumchloride
Purity: 97%
Packaging: 500g
Price: $200
Updated: 2021/12/16

Ambeed

Product number: A1372051
Product name: (2-Ethoxy-2-oxoethyl)triphenylphosphoniumchloride
Purity: 97%
Packaging: 100g
Price: $60
Updated: 2021/12/16

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(CARBOETHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATE Chemical Properties,Usage,Production

Chemical Properties

white to off-white crystals or crystalline powder

Uses

Reactant for:

Preparation of disubstituted tetrahydrofurans as selective serotonin re-uptake inhibitors for the treatment of depression
Ring-opening reactions with Wittig reagents
Enantioselective total synthesis of the phytotoxic lactone herbarumin III via Keck′s asymmetric allylation and Sharpless epoxidation
Synthesis of fluorobenzofurans via microwave-assisted tandem intramolecular Wittig and Claisen rearrangement reactions
Preparation of phosphonium derivatives of coumarin

reaction suitability

reaction type: C-C Bond Formation

(CARBOETHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATE Preparation Products And Raw materials

Raw materials

Preparation Products

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(CARBOETHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATE Suppliers

Belgium 1 Canada 1 China 47 France 2 Germany 3 India 2 Japan 3 Slovakia 1 South Korea 1 Switzerland 2 The Netherlands 1 United Kingdom 8 United States 8 Global 80

Creasyn Finechem(Tianjin) Co., Ltd.

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J & K SCIENTIFIC LTD.

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Thermo Fisher Scientific

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Bide Pharmatech Ltd.

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ORGANICA Feinchemie GmbH

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Shanghai Xingui Biotechnology Co., Ltd.

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17577-28-5, (CARBOETHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATERelated Search:

Methyl triphenyl phosphonium chloride Methyl(triphenyl)phosphonium chloride ETHOXY-ETHOXYCARBONYL-METHYLTRIPHENYLPHOSPHONIUM CHLORIDE (2-ethoxy-1-methyl-2-oxoethyl)triphenylphosphonium chloride (ALLYLOXYCARBONYL)METHYLTRIPHENYLPHOSPHONIUM CHLORIDE (TERT-BUTOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE (CARBOETHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATE

CARBETHOXYMETHYLTRIPHENYLPHOSPHONIUM CHLORIDE

(CARBOETHOXYMETHYL)-TRIPHENYLPHOSPHONIUMCHLORID

(CARBOETHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE

(CARBOETHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATE

(ETHOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE

(4-ETHOXYCARBONYL)TRIPHENYLPHOSPHONIUM CHLORIDE

(2-ethoxy-2-oxoethyl)triphenylphosphonium chloride

(ETHOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONI UM CHLORIDE, TECH., 80%

(ETHOXYCARBONYLMETHYL)TRIPHENYL PHOSPHO&

ethyl (triphenylphosphonio)acetate chloride

(ETHOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE 97%

[(Ethoxycarbonyl)methyl]triphenylphosphonium chloride, 97 %

(CARBOETHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATE17577-28-5

(2-ETHOXY-2-OXOETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATE

(Carboethoxymethyl)triphenylphosphonium chloride hydrate,97%

(2-Ethoxy-2-oxoethyl)triphenylphosphonium chloride - [E88915]

17577-28-5

C22H22ClO2P

CH3CH2OCOCH2PClC6H53

C22H22ClO2PxH2O

CH3CH2O2CCH2PC6H53Cl

C22H24ClO3P

C22H22O2PCl

Olefination

Synthetic Reagents

Wittig Reagents

C-C Bond Formation