2,2,6-TRIMETHYLCYCLOHEXANONE

Product Name: 2,2,6-TRIMETHYLCYCLOHEXANONE
CAS No.: 2408-37-9
Chemical Name: 2,2,6-TRIMETHYLCYCLOHEXANONE
Synonyms: Cyclohexanone, 2,2,6-trimethyl-;2,6,6-Trimethylcyclohexanone;2,2,6-Trimethylcyclohexan-1-one;FEMA 3473;2,2,6-TRIMETHYLCYCLOHEXANONE;2,2,6-trimethyl-cyclohexanon;1,1,3-Trimethyl-2-cyclohexanone;2 2 6-TRIMETHYLCYCLOHEXANONE 98+%;2,2,6-TRIMETHYLCYCLOHEXANONE, 98.5+%;2,2,6-TRIMETHYLCYCLOHEXANONE 98.5+% (GC)
CBNumber: CB9155613
Molecular Formula: C9H16O
Formula Weight: 140.22
MOL File: 2408-37-9.mol

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2,2,6-TRIMETHYLCYCLOHEXANONE Property

Melting point:: -31.8°C
Boiling point:: 178-179 °C(lit.)
Density: 0.904 g/mL at 25 °C(lit.)
refractive index: n20/D 1.447(lit.)
FEMA: 3473 | 2,2,6-TRIMETHYLCYCLOHEXANONE
Flash point:: 125 °F
storage temp.: Flammables area
solubility: Chloroform (Slightly), Methanol (Slightly)
form: Oil
color: Colourless
Specific Gravity: 0.904
Odor: at 10.00 % in dipropylene glycol. pungent thujone labdanum honey cistus
Odor Type: thujonic
Water Solubility: Slightly miscible with water.
JECFA Number: 1108
BRN: 1905593
LogP: 2.41
CAS DataBase Reference: 2408-37-9(CAS DataBase Reference)
EPA Substance Registry System: 2,2,6-Trimethylcyclohexanone (2408-37-9)

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Safety

Risk Statements: 10
Safety Statements: 23-24/25
RIDADR: UN 1224 3/PG 3
WGK Germany: 3
TSCA: Yes
HazardClass: 3
PackingGroup: III

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Alfa Aesar

Product number: B21111
Product name: 2,2,6-Trimethylcyclohexanone, 97%
Packaging: 1g
Price: $56.65
Updated: 2024/03/01

Alfa Aesar

Product number: B21111
Product name: 2,2,6-Trimethylcyclohexanone, 97%
Packaging: 5g
Price: $211.65
Updated: 2024/03/01

Alfa Aesar

Product number: B21111
Product name: 2,2,6-Trimethylcyclohexanone, 97%
Packaging: 25g
Price: $809.65
Updated: 2024/03/01

TRC

Product number: T797573
Product name: 2,2,6-Trimethylcyclohexanone
Packaging: 5g
Price: $910
Updated: 2021/12/16

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2,2,6-TRIMETHYLCYCLOHEXANONE Chemical Properties,Usage,Production

Chemical Properties

CLEAR COLOURLESS LIQUID

Occurrence

Reported found in bilberries, passion fruit and tea. Also reported found in apricot, bilberry, white wine, black tea, green tea, microbial fermented tea, brewed tea, yellow passion fruit juice and dill herb.

Uses

2,2,6-Trimethylcyclohexanone is used as a flavoring agent. It is also used to prepare terpene viz. beta-ionone.

Aroma threshold values

Detection: 100 ppb; recognition: 310 ppb

Synthesis Reference(s)

Journal of the American Chemical Society, 80, p. 4072, 1958 DOI: 10.1021/ja01548a061
The Journal of Organic Chemistry, 27, p. 1615, 1962 DOI: 10.1021/jo01052a031

Purification Methods

Purify it via the semicarbazone (m 218o, from MeOH or EtOH), decompose this in the usual way (cf p 65 and 67, or MEK, p 106) and fractionally distil the liquid ketone through a vigreux column (p 11) at ~760mm. [Chakravarti J Chem Soc 1567 1947, Milas et al. J Am Chem Soc 70 1831 1948, Beilstein 7 I 24, 7 II 32, 7 III 7.]

2,2,6-TRIMETHYLCYCLOHEXANONE Preparation Products And Raw materials

Raw materials

Preparation Products

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2,2,6-TRIMETHYLCYCLOHEXANONE Suppliers

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View Lastest Price from 2,2,6-TRIMETHYLCYCLOHEXANONE manufacturers

Career Henan Chemical Co

Product: 2,2,6-TRIMETHYLCYCLOHEXANONE 2408-37-9
Price: US $1.00/KG
Min. Order: 1IU
Purity: 99.0%
Supply Ability: 100kg
Release date: 2020-01-07

2408-37-9, 2,2,6-TRIMETHYLCYCLOHEXANONERelated Search:

2-OXO-1,1,3,3-CYCLOHEXANETETRAPROPIONIC ACID Fenchone 2,2,6,6-TETRAMETHYLCYCLOHEXANONE (-)-CAMPHORCARBOXYLIC ACID 2,2,6-TRIMETHYLCYCLOHEXANONE 3-TRIFLUOROACETYL-D-CAMPHOR 3-HEPTAFLUOROBUTYRYL-(+)-CAMPHOR 1,1-Bis(tert-butylperoxy)-3,3,5-trimethylcyclohexanone 3,3,5-TRIMETHYLCYCLOHEXANONE 98+%,3,3,5-TRIMETHYLCYCLOHEXANONE METHYLCYCLOHEXANONE 3-(HEPTAFLUOROBUTYRYL)-I-CAMPHOR 6-CARBETHOXY-2,2,6-TRIMETHYLCYCLOHEXANONE,2,2,6-Trimethylcyclohexanone-4-carboxylic acid ethyl ester,6-CARBETHOXY-2,2,6-TRIMETHYLCYCLOHEXANONE 97% (+)-CAMPHORCARBOXYLIC ACID 2,4,4-Trimethylcyclohexanone 3-cyano-3,5,5-trimethylcyclohexanone O-(2-hydroxy-3-(tert-butylamino)propyl)-3,3,5-trimethylcyclohexanone oxime 3-Hydroxy-3,5,5-trimethylcyclohexanone HEXAMETHYLCYCLOHEXANE-1,3,5-TRIONE

1,1,3-Trimethyl-2-cyclohexanone

2,2,6-Trimethylcyclohexan-1-one

2,2,6-trimethyl-cyclohexanon

2,6,6-Trimethylcyclohexanone

2,2,6-TRIMETHYLCYCLOHEXANONE

2 2 6-TRIMETHYLCYCLOHEXANONE 98+%

Cyclohexanone, 2,2,6-trimethyl-

2,2,6-TRIMETHYLCYCLOHEXANONE 98.5+% (GC)

FEMA 3473

2,2,6-TRIMETHYLCYCLOHEXANONE, 98.5+%

2408-37-9

CH33C6H7O

C9

Carbonyl Compounds

Building Blocks

Organic Building Blocks

Ketones

Alphabetical Listings

Flavors and Fragrances

Q-Z

C9

Carbonyl Compounds

Ketones