ethyl 3-cyanobenzoate
- Product Name
- ethyl 3-cyanobenzoate
- CAS No.
- 2463-16-3
- Chemical Name
- ethyl 3-cyanobenzoate
- Synonyms
- ethyl 3-cyanobenzoate;Benzoic acid, 3-cyano-, ethyl ester
- CBNumber
- CB91560915
- Molecular Formula
- C10H9NO2
- Formula Weight
- 175.18
- MOL File
- 2463-16-3.mol
ethyl 3-cyanobenzoate Property
- Melting point:
- 56 °C
- Boiling point:
- 140-141 °C(Press: 10 Torr)
- Density
- 1.14±0.1 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- Appearance
- Off-white to light yellow Solid
Safety
- HS Code
- 2926907090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
N-Bromosuccinimide Price
- Product number
- E926338
- Product name
- Ethyl3-cyanobenzoate
- Packaging
- 250mg
- Price
- $115
- Updated
- 2021/12/16
- Product number
- E926338
- Product name
- Ethyl3-cyanobenzoate
- Packaging
- 500mg
- Price
- $175
- Updated
- 2021/12/16
- Product number
- E926338
- Product name
- Ethyl3-cyanobenzoate
- Packaging
- 1g
- Price
- $250
- Updated
- 2021/12/16
- Product number
- 449092
- Product name
- Ethyl 3-cyanobenzoate
- Packaging
- 100mg
- Price
- $319
- Updated
- 2021/12/16
- Product number
- FC66858
- Product name
- 3-Cyanobenzoic acid ethyl ester
- Packaging
- 5G
- Price
- $75
- Updated
- 2021/12/16
ethyl 3-cyanobenzoate Chemical Properties,Usage,Production
Synthesis
64-17-5
24964-64-5
2463-16-3
General procedure for the synthesis of ethyl 3-cyanobenzoate from ethanol and 3-cyanobenzaldehyde: A mixture of chlorobrominated resin and K2CO3 in MeOH-H2O (8:2, 3 mL) was placed in a round-bottomed flask equipped with a magnetic stirrer. 3-Cyanobenzaldehyde (1 mmol, 1 eq.) was added dropwise to the reaction system and the reaction mixture was continuously stirred at room temperature. The reaction process was monitored by thin layer chromatography (TLC). After completion of the reaction, the reaction mixture was filtered and the filtrate was extracted with ether (Et2O). The separated ether layer was washed sequentially with water and saturated brine and subsequently dried with anhydrous sodium sulfate (Na2SO4). The dried organic phase was filtered and concentrated to give the crude product. For further purification, the residue can be purified by silica gel column chromatography (60-120 mesh) using a mixture of petroleum ether (PE) and ethyl acetate (EtOAc) (9:1) as eluent.
References
[1] Synlett, 2016, vol. 27, # 9, p. 1344 - 1348
[2] Bulletin of the Korean Chemical Society, 2011, vol. 32, # 6, p. 2070 - 2072
ethyl 3-cyanobenzoate Preparation Products And Raw materials
Raw materials
Preparation Products
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