4-(AMINOMETHYL)TETRAHYDRO-2H-PYRAN-4-AMINE

Product Name: 4-(AMINOMETHYL)TETRAHYDRO-2H-PYRAN-4-AMINE
CAS No.: 50289-16-2
Chemical Name: 4-(AMINOMETHYL)TETRAHYDRO-2H-PYRAN-4-AMINE
Synonyms: 4-(Aminomethyl);4-(aminomethyl)oxan-4-amine;2H-Pyran-4-methanamine, 4-aminotetrahydro-;4-(AMINOMETHYL)TETRAHYDRO-2H-PYRAN-4-AMINE
CBNumber: CB9161360
Molecular Formula: C6H14N2O
Formula Weight: 130.19
MOL File: 50289-16-2.mol

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4-(AMINOMETHYL)TETRAHYDRO-2H-PYRAN-4-AMINE Property

storage temp.: Keep in dark place,Inert atmosphere,Room temperature

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: A395645
Product name: 4-(Aminomethyl)tetrahydro-2H-pyran-4-amine
Packaging: 10mg
Price: $45
Updated: 2021/12/16

TRC

Product number: A395645
Product name: 4-(Aminomethyl)tetrahydro-2H-pyran-4-amine
Packaging: 100mg
Price: $285
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0237562
Product name: 4-(AMINOMETHYL)TETRAHYDRO-2H-PYRAN-4-AMINE
Purity: 98.00%
Packaging: 1G
Price: $1070.84
Updated: 2021/12/16

AK Scientific

Product number: W6562
Product name: 4-(Aminomethyl)tetrahydro-2H-pyran-4-amine
Packaging: 1g
Price: $1081
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0237562
Product name: 4-(AMINOMETHYL)TETRAHYDRO-2H-PYRAN-4-AMINE
Purity: 98.00%
Packaging: 2.5G
Price: $1635.3
Updated: 2021/12/16

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4-(AMINOMETHYL)TETRAHYDRO-2H-PYRAN-4-AMINE Chemical Properties,Usage,Production

Synthesis

50289-12-8

50289-16-2

GENERAL STEPS: 4-Aminotetrahydro-2H-pyran-4-carbonitrile (10 g, 80 mmol) was slowly added to a suspension of LiAlH4 (9.1 g, 240 mmol) in methyl tertiary butyl ether (MTBE, 120 mL) at room temperature. The reaction mixture was stirred continuously at 40 °C for 2 hours. Upon completion of the reaction, the reaction was quenched by sequential addition of water (9.1 mL) and 15% aqueous NaOH solution (9.1 mL), followed by water (27.3 mL). After continued stirring for 1 h, the reaction mixture was filtered and the filter cake was washed with MTBE (20 mL x 2). After combining the filtrates, 4-(aminomethyl)tetrahydro-2H-pyran-4-amine (6 g, 46.1 mmol) was obtained by vacuum concentration, and the product could be used in subsequent reactions without further purification.

References

[1] Patent: WO2018/5860, 2018, A1. Location in patent: Page/Page column 172; 197; 198
[2] Patent: WO2018/5863, 2018, A1. Location in patent: Page/Page column 127

4-(AMINOMETHYL)TETRAHYDRO-2H-PYRAN-4-AMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-(AMINOMETHYL)TETRAHYDRO-2H-PYRAN-4-AMINE Suppliers

China 9 United States 2 Global 11

Hangzhou Milestone Pharmtech Co., Ltd.

Tel: 0571-82896630 18969958410
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Block Chemical Technology (Shanghai) Co., Ltd.

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Heze Xingda Pharmaceutical Technology Co., Ltd.

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Hangzhou MolCore BioPharmatech Co.,Ltd.

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50289-16-2, 4-(AMINOMETHYL)TETRAHYDRO-2H-PYRAN-4-AMINERelated Search:

4-(Aminomethyl)tetrahydro-2H-pyran METHYL-(4-PYRROLIDIN-1-YLMETHYL-TETRAHYDRO-PYRAN-4-YL)-CARBAMIC ACID BENZYL ESTER TERT-BUTYL 4-[4-(AMINOMETHYL)TETRAHYDRO-2H-PYRAN-4-YL]PIPERAZINE-1-CARBOXYLATE Tert-butyl(4-aminotetrahydro-2H-pyran-4-yl)methylcarbamate METHYL-(4-PYRROLIDIN-1-YLMETHYL-TETRAHYDRO-PYRAN-4-YL)-AMINE 4-(Aminomethyl)-N,N-dimethyltetrahydro-2H-pyran-4-amine 1-[4-(4-METHYLPIPERAZIN-1-YL)TETRAHYDRO-2H-PYRAN-4-YL]METHANAMINE 1-[4-(3,3-DIMETHYLPIPERAZIN-1-YL)TETRAHYDRO-2H-PYRAN-4-YL]METHANAMINE 4-(AMINOMETHYL)TETRAHYDRO-2H-PYRAN-4-AMINE 1-[4-(4-ISOPROPYLPIPERAZIN-1-YL)TETRAHYDRO-2H-PYRAN-4-YL]METHANAMINE 1-(4-MORPHOLIN-4-YLTETRAHYDRO-2H-PYRAN-4-YL)METHANAMINE

4-(Aminomethyl)

4-(AMINOMETHYL)TETRAHYDRO-2H-PYRAN-4-AMINE

4-(aminomethyl)oxan-4-amine

2H-Pyran-4-methanamine, 4-aminotetrahydro-

50289-16-2