METHYL 1-METHYL-4-NITRO-1H-IMIDAZOLE-2-CARBOXYLATE
- Product Name
- METHYL 1-METHYL-4-NITRO-1H-IMIDAZOLE-2-CARBOXYLATE
- CAS No.
- 169770-25-6
- Chemical Name
- METHYL 1-METHYL-4-NITRO-1H-IMIDAZOLE-2-CARBOXYLATE
- Synonyms
- 3-BROMO-10-CHLOROPHENOL;Methyl 1-Methyl-4-nitroimidazole-2-carboxylate;Methyl 4-nitro-1-methylimidazole-2-carboxylate;Methyl 1-methyl-4-nitro-1H-imidazol-2-carboxylate;Methyl -methyl-4-nitro-1H-imidazole-2-carboxylate;METHYL 1-METHYL-4-NITRO-1H-IMIDAZOLE-2-CARBOXYLATE;Carbamicacid,N-[2-(2-bromoethoxy)ethyl]-,1,6-dimethylethylester;1H-Imidazole-2-carboxylic acid, 1-methyl-4-nitro-, methyl ester
- CBNumber
- CB9180798
- Molecular Formula
- C6H7N3O4
- Formula Weight
- 185.14
- MOL File
- 169770-25-6.mol
METHYL 1-METHYL-4-NITRO-1H-IMIDAZOLE-2-CARBOXYLATE Property
- Melting point:
- 157-158 °C
- Boiling point:
- 345.0±34.0 °C(Predicted)
- Density
- 1.49±0.1 g/cm3(Predicted)
- storage temp.
- 2-8°C
- pka
- -2.47±0.60(Predicted)
- Appearance
- White to off-white Solid
Safety
- HazardClass
- IRRITANT
- HS Code
- 2933299090
N-Bromosuccinimide Price
- Product number
- Z2323
- Product name
- 1-Methyl-4-nitro-1H-imidazole-2-carboxylicacidmethylester
- Packaging
- 100mg
- Price
- $103
- Updated
- 2021/12/16
- Product number
- 057542
- Product name
- Methyl -methyl-4-nitro-1H-imidazole-2-carboxylate
- Purity
- 98%
- Packaging
- 1g
- Price
- $142
- Updated
- 2021/12/16
- Product number
- Z2323
- Product name
- 1-Methyl-4-nitro-1H-imidazole-2-carboxylicacidmethylester
- Packaging
- 1g
- Price
- $207
- Updated
- 2021/12/16
- Product number
- Z2323
- Product name
- 1-Methyl-4-nitro-1H-imidazole-2-carboxylicacidmethylester
- Packaging
- 5g
- Price
- $489
- Updated
- 2021/12/16
- Product number
- 057542
- Product name
- Methyl -methyl-4-nitro-1H-imidazole-2-carboxylate
- Purity
- 98%
- Packaging
- 5g
- Price
- $489
- Updated
- 2021/12/16
METHYL 1-METHYL-4-NITRO-1H-IMIDAZOLE-2-CARBOXYLATE Chemical Properties,Usage,Production
Synthesis
67-56-1
120095-64-9
169770-25-6
The general procedure for the synthesis of methyl 1-methyl-4-nitro-1H-imidazole-2-carboxylate from methanol and 2,2,2-trichloro-1-(1-methyl-4-nitro-1H-imidazol-2-yl)ethanone was as follows: methanol (40 mL) was added to a reaction flask containing 2,2,2-trichloro-1-(1-methyl-4-nitro-1H-imidazol-2-yl)ethanone, heated to 40 °C and stirred for 10 minutes. Subsequently, a small amount of sodium hydride (100 mg) was added to the reaction mixture to ensure complete methanolysis. After continued stirring for 2 h, the reaction mixture was filtered to afford methyl 1-methyl-4-nitro-1H-imidazole-2-carboxylate in 94% yield. The product was confirmed by 1H-NMR (CDCl3): δ 7.84 (s, 1H, Im-CH), 4.18 (s, 3H, CH3), 3.93 (s, 3H, CH3).EI-HRMS analysis resulted in a m/z calculated value of 185.0437 for C6H7N3O4 and a measured value of 185.0476 (100%).
References
[1] Patent: WO2007/45096, 2007, A1. Location in patent: Page/Page column 45; 86
[2] Heterocycles, 1995, vol. 41, # 6, p. 1181 - 1196
[3] Synthetic Communications, 2004, vol. 34, # 9, p. 1609 - 1615
METHYL 1-METHYL-4-NITRO-1H-IMIDAZOLE-2-CARBOXYLATE Preparation Products And Raw materials
Raw materials
Preparation Products
METHYL 1-METHYL-4-NITRO-1H-IMIDAZOLE-2-CARBOXYLATE Suppliers
- Tel
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- Fax
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- sales@ajchem.in
- Country
- India
- ProdList
- 6100
- Advantage
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View Lastest Price from METHYL 1-METHYL-4-NITRO-1H-IMIDAZOLE-2-CARBOXYLATE manufacturers
- Product
- METHYL 1-METHYL-4-NITRO-1H-IMIDAZOLE-2-CARBOXYLATE 169770-25-6
- Price
- US $9.80/KG
- Min. Order
- 1g
- Purity
- ≥99%
- Supply Ability
- 100kg
- Release date
- 2020-01-13