IRONE

Product Name: IRONE
CAS No.: 79-69-6
Chemical Name: IRONE
Synonyms: IRONE;α-irone;IRON-ALPHA;alpha-Irone;methyl-alpha-inon;Methyl-alpha-ionone;IRONE alpha REFINED;IRONE ALPHA 6065003;ALPHA-N-METHYLIONONE;5-methyl-alpha-ionone
CBNumber: CB9184594
Molecular Formula: C14H22O
Formula Weight: 206.32
MOL File: 79-69-6.mol

More

Less

IRONE Property

Melting point:: <25 °C
Boiling point:: 285.19°C (rough estimate)
Density: 0.934 g/mL at 20 °C(lit.)
vapor pressure: 0.4Pa at 20℃
refractive index: n20/D 1.492
FEMA: 2597 | ALPHA-IRONE
form: Liquid
Odor: at 10.00 % in dipropylene glycol. orris floral berry violet woody powdery
Odor Type: floral
JECFA Number: 403
Merck: 13,5111
BRN: 1343498
LogP: 3.8-4 at 35℃ and pH7
EPA Substance Registry System: 3-Buten-2-one, 4-(2,5,6,6-tetramethyl-2-cyclohexen-1-yl)- (79-69-6)

More

Less

Safety

Safety Statements: 23-24/25
WGK Germany: 2
RTECS: EN0335000

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Hazard statements

H411Toxic to aquatic life with long lasting effects

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P501Dispose of contents/container to..…

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 58220
Product name: Irone
Purity: technical, mixture of isomers (mainly the α-isomer), ≥90% (GC)
Packaging: 5ml
Price: $275
Updated: 2024/03/01

American Custom Chemicals Corporation

Product number: FFG0000248
Product name: IRONE
Purity: 95.00%
Packaging: 250MG
Price: $762.83
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: FFG0000248
Product name: IRONE
Purity: 95.00%
Packaging: 5ML
Price: $944.21
Updated: 2021/12/16

Chem-Impex

Product number: 34401
Product name: Irone,95-100%(Assay,sumofisomers),meetsFGspecifications,KOSHER,FEMA2597
Purity: 95-100%(Assay,sumofisomers)
Packaging: 25KG
Price: $58523.1
Updated: 2021/12/16

Crysdot

Product number: CD13004268
Product name: 4-(2,5,6,6-Tetramethylcyclohex-2-en-1-yl)but-3-en-2-one
Purity: 95+%
Packaging: 250mg
Price: $713
Updated: 2021/12/16

More

Less

IRONE Chemical Properties,Usage,Production

Description

α-Irone has a characteristic orris and violet-like odor. The commercially prepared product corresponds generally to the α-isomer.

Chemical Properties

α- Irone has a rich, floral and natural character and constitutes an important element in orris and violet compositions as well as being useful when an exotic nuance is required. α-Irone is extremely diffusive, and it gives volume and tenacity to compositions. In combination with α-irisone (1:20, respectively) gives a natural orris effect.

Chemical Properties

Yellowish liquid; Soluble in alcohol. A mixture of three isomers (α-, βand γ-irone).

Occurrence

Reported found in orris root, raspberry and flowers of Pittosporum sp

Uses

Perfumery, violet odor. The α isomer is also used as a flavoring agent.

Definition

ChEBI: A methyl ketone that is alpha-ionone in which a hydrogen at position 5 of the cyclohex-2-en-1-yl ring is substituted by a methyl group.

Preparation

By intramolecular thermal H-ene reaction of an allysilane.

Taste threshold values

Taste characteristics at 10 ppm: woody, fruity, raspberry, orris, and berry with seedy nuances.

General Description

Irone is a bioactive compound that is produced by an endophytic fungus in the rhizomes of Iris germanica.

Synthesis

Alpha-n-Methy lionone is synthesized by condensation of Methylethyl ketone with Citral, and cyclization of the resulting Pseudomethylionone. Cyclization may be carried out with Boron trifluoride or other agent.

Purification Methods

If large amounts are available, then fractionate through a Podbielniak column (p 10) or an efficient spinning band column, but small amounts are distilled using a Kügelrohr apparatus. The 4-phenylsemicarbazone has m 174-175o (165-165.5o). [IR: Seidel & Ruzicka Helv Chim Acta 35 1826 1952, Naves Helv Chim Acta 31 1280 1948, Lecomte & Naves J Chim Phys 53 462 1956, Beilstein 7 IV 378.]

IRONE Preparation Products And Raw materials

Raw materials

1,3-Butadiene Citral

Preparation Products

METHYLIONONE

More

Less

IRONE Suppliers

China 57 Germany 1 India 1 Japan 1 Switzerland 1 United Kingdom 3 United States 24 Global 88

BOC Sciences

Tel: 1-631-485-4226; 16314854226
Email: info@bocsci.com
Country: United States
ProdList: 14055
Advantage: 65

Alfa Chemistry

Tel
Fax: 1-516-927-0118
Email: Info@alfa-chemistry.com
Country: United States
ProdList: 24072
Advantage: 58

TargetMol Chemicals Inc.

Tel
Email: support@targetmol.com
Country: United States
ProdList: 38632
Advantage: 58

Vigon International, Inc.

Tel: --
Fax: --
Email: jpassamonte@vigoninternational.com
Country: United States
ProdList: 1268
Advantage: 64

Ernesto Ventós S.A.

Tel: --
Fax: --
Email: info@ventos.com
Country: United States
ProdList: 2257
Advantage: 58

Vigon International

Tel: --
Fax: --
Email: sales@vigon.com
Country: United States
ProdList: 1776
Advantage: 58

Pell Wall Perfumes

Tel: --
Fax: --
Email: //pellwall.com/contact-us/
Country: United States
ProdList: 559
Advantage: 58

Firmenich Inc.

Tel: --
Fax: --
Email: Frederick.Keifer@firmenich.com
Country: United States
ProdList: 1017
Advantage: 58

Prodasynth

Tel: --
Fax: --
Email: info@prodasynth.com
Country: United States
ProdList: 423
Advantage: 58

Penta International Corporation

Tel: --
Fax: --
Email: lisaa@pentamfg.com
Country: United States
ProdList: 5042
Advantage: 58

Lluch Essence S.L.

Tel: --
Fax: --
Email: web@lluche.com
Country: United States
ProdList: 2352
Advantage: 58

M&U International LLC

Tel: --
Fax: --
Email: sales@mu-intel.com
Country: United States
ProdList: 2011
Advantage: 58

Jiangyin Healthway International Trade Co., Ltd

Tel: --
Fax: --
Email: info@healthwaychem.com
Country: United States
ProdList: 1006
Advantage: 58

PerfumersWorld Ltd.

Tel: --
Fax: --
Email: pwenquiries@perfumersworld.com
Country: United States
ProdList: 723
Advantage: 58

SRS Aromatics Ltd

Tel: --
Fax: --
Email: info@srsaromatics.co.uk
Country: United States
ProdList: 2315
Advantage: 46

Moellhausen S.P.A.

Tel: --
Fax: --
Country: United States
ProdList: 1676
Advantage: 58

Augustus Oils Ltd

Tel: --
Fax: --
Email: essentials@augustus-oils.ltd.uk
Country: United States
ProdList: 1404
Advantage: 58

Pyrazine Specialties, Inc.

Tel: --
Fax: --
Country: United States
ProdList: 1265
Advantage: 30

Indukern, S.A. F&F Ingredients Division

Tel: --
Fax: --
Email: info@indukern.es
Country: United States
ProdList: 1321
Advantage: 58

Robertet, Inc.

Tel: --
Fax: --
Email: info@robertetUSA.com
Country: United States
ProdList: 1026
Advantage: 58

Riedel-de Haen AG

Tel: --
Fax: --
Country: United States
ProdList: 6773
Advantage: 87

Penta Manufacturing Company

Tel: --
Fax: --
Email: sales@pentamfg.com
Country: United States
ProdList: 5076
Advantage: 65

2A PharmaChem USA

Tel: --
Fax: --
Email: sales@2apharmachem.com
Country: United States
ProdList: 6137
Advantage: 39

3B Scientific Corporation

Tel: --
Fax: --
Email: sales@3bsc.com
Country: United States
ProdList: 6718
Advantage: 47

More

Less

View Lastest Price from IRONE manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: Irone 79-69-6
Price: US $0.00-0.00/KG
Min. Order: 100g
Purity: 99.0%+
Supply Ability: 100 tons
Release date: 2020-01-19

Career Henan Chemical Co

Product: IRONE 79-69-6
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1
Release date: 2018-08-06

79-69-6, IRONERelated Search:

ZEARALANONE Cedryl acetate Ionone alpha-Ionone METHYLIONONE ORRIS CONCRETE 8% IRONE,ORRIS CONCRETE 15% IRONE IRONE ALPHA gamma-irone cis-(+)-α-Irone (2R,6S)-irone trans-(+)-γ-Irone beta-irone

(3E)-4-(2,5,6,6-Tetramethyl-2-cyclohexen-1-yl)-3-buten-2-one

3-Buten-2-one, 4-(2,5,6,6-tetramethyl-2-cyclohexen-1-yl)-

3-Buten-2-one, 4-(2,5,6,6-tetramethyl-2-cyclohexen-1-yl)-, cis-

4-(2,5,6,6-tetramethyl-2-cyclohexen-1-yl)-3-buten-2-on

4-(2,5,6,6-tetramethyl-2-cyclo-hexen-1-yl)-3-buten-2-one

4-(2,5,6,6-tetramethyl-2-cyclohexen-1-yl)-3-Buten-2-one

alpha-Ionone, 6-methyl-

alpha-Irone

irone,mixtureofisomers(mainlythealpha-isomer)

methyl-alpha-inon

Methyl-alpha-ionone

4-(2,5,6,6-tetramethylcyclohex-2-enyl)but-3-en-2-one

5-methyl-alpha-ionone

ALPHA-N-METHYLIONONE

4-(2,5,6,6-Tetramethylcyclohex-2-enyl)but-3-en-2-on

IRON-ALPHA

IRONE alpha REFINED

IRONE

(3E)-4-[(5R)-2,5β,6,6-Tetramethyl-1-cyclohexen-1-yl]-3-buten-2-one

4-(2,5,6,6-TetraMethylcyclohex-2-en-1-yl)but-3-en-2-one

Irone technical, mixture of isomers (mainly the alpha-isomer), >=90% (GC)

Irone (mixture of isomers)

α-irone

(e)-4-(2,5,6,6-Tetramethylcyclohex-2-en-1-yl)but-3-en-2-one

IRONE ALPHA 6065003

79-69-6

Organic Building Blocks

Ketones

Asymmetric Synthesis

Chiral Building Blocks

Ketones

Organic Building Blocks

ketone Flavor