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ChemicalBook > CAS DataBase List > (S)-VANOL

(S)-VANOL

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Product Name
(S)-VANOL
CAS No.
147702-14-5
Chemical Name
(S)-VANOL
Synonyms
(R)-VANOL;(S)-VANOL;(S)-VANOL 97%;(S)-VANOL,99%e.e.;(R)-3,3'-DIPHENYL-2,2'-BI-1-NAPHTHALOL;(S)-3,3'-DIPHENYL-2,2'-BI(1-NAPHTHALOL);(2S)-3,3'- diphenyl [2,2'- binaphthyl ]-1,1'- diol;(2S)-3,3'- diphenyl [2,2'- binaphthyl ]-1,1'- diol;(2S)-(-)-3,3'-DIPHENYL-[2,2'-BINAPHTHALENE]-1,1'-DIOL;(2R)-(+)-3,3'-DIPHENYL-[2,2'-BINAPHTHALENE]-1,1'-DIOL
CBNumber
CB9188800
Molecular Formula
C32H22O2
Formula Weight
438.52
MOL File
147702-14-5.mol
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(S)-VANOL Property

Melting point:
199-203 °C
alpha 
-372.3° (c 1.0, THF)
Boiling point:
580.1±50.0 °C(Predicted)
Density 
1.251±0.06 g/cm3(Predicted)
storage temp. 
2-8°C
form 
Powder
pka
7.71±0.50(Predicted)
color 
white to pale yellow
optical activity
[α]20/D -314°, c = 1 in chloroform
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Safety

Hazard Codes 
Xi
Risk Statements 
37/38-41
Safety Statements 
26-36/37/39
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
676098
Product name
(S)-VANOL
Purity
97%
Packaging
250mg
Price
$159
Updated
2024/03/01
Strem Chemicals
Product number
08-1702
Product name
(2S)-(-)-3,3'-Diphenyl-[2,2'-binaphthalene]-1,1'-diol, min. 98% (S)-VANOL
Packaging
100mg
Price
$212
Updated
2024/03/01
Strem Chemicals
Product number
08-1702
Product name
(2S)-(-)-3,3'-Diphenyl-[2,2'-binaphthalene]-1,1'-diol, min. 98% (S)-VANOL
Packaging
500mg
Price
$838
Updated
2024/03/01
AK Scientific
Product number
Z1960
Product name
(S)-Vanol
Packaging
250mg
Price
$274
Updated
2021/12/16
Ambeed
Product number
A238090
Product name
(2S)-3,3'-Diphenyl[2,2'-binaphthalene]-1,1'-diol
Purity
98%99%ee
Packaging
50mg
Price
$35
Updated
2021/12/16
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(S)-VANOL Chemical Properties,Usage,Production

Reactions

  1. Chiral ligand used in catalytic asymmetric aziridination.
  2. Chiral ligand used in catalytic asymmetric aminoallylation of aldehydes.
  3. Chiral ligand used in catalytic asymmetric Petasis reaction. 

Uses

VANOL has proven to be an excellent ligand in catalytic asymmetric Diels-Alder, imine aldol, and aziridination reactions.

(S)-VANOL Preparation Products And Raw materials

Raw materials

Preparation Products

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(S)-VANOL Suppliers

SIGMA-RBI
Tel
--
Fax
--
Country
Switzerland
ProdList
6896
Advantage
91
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View Lastest Price from (S)-VANOL manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
(S)-VANOL 147702-14-5
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27

147702-14-5, (S)-VANOLRelated Search:


  • (R)-3,3'-DIPHENYL-2,2'-BI-1-NAPHTHALOL
  • (S)-VANOL
  • (R)-VANOL
  • (S)-3,3'-DIPHENYL-2,2'-BI(1-NAPHTHALOL)
  • (2S)-(-)-3,3'-Diphenyl-[2,2'-binaphthalene]-1,1'-diol,min.98%(S)-VANOL
  • (2S)-(-)-3,3''-DIPHENYL-[2,2''-BINAPHTHALENE]-1,1''-DIOL (S)-VANOL
  • (S)-3,3μ-Diphenyl-2,2μ-bi(1-naphthalol), (S)-3,3μ-Diphenyl-2,2μ-bi-(1-naphthol)
  • (S)-VANOL 97%
  • (2R)-(+)-3,3'-DIPHENYL-[2,2'-BINAPHTHALENE]-1,1'-DIOL
  • (2S)-(-)-3,3'-DIPHENYL-[2,2'-BINAPHTHALENE]-1,1'-DIOL
  • (S)-VANOL,99%e.e.
  • [2,2'-Binaphthalene]-1,1'-diol, 3,3'-diphenyl-, (2S)-
  • (2S)-3,3'- diphenyl [2,2'- binaphthyl ]-1,1'- diol
  • (2s)-(-)-3,3'-diphenyl-[2,2'-binaphthalene]-1,1'-diol, min. 98% (s)-vanol
  • (2S)-(-)-3,3'-Diphenyl-[2,2'-binaphthalene]-1,1'-diol
  • (2S)-3,3'- diphenyl [2,2'- binaphthyl ]-1,1'- diol
  • 147702-14-5
  • BINOL Series
  • Chiral Oxygen