ChemicalBook > CAS DataBase List > Isobornyl methacrylate

Isobornyl methacrylate

Product Name
Isobornyl methacrylate
CAS No.
7534-94-3
Chemical Name
Isobornyl methacrylate
Synonyms
IBOMA;IBXMA;Acryester IBX;exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl methacrylate;Photomer 2012;Ageflex IBOMA;Light Ester IB;Isoice methacrylate;Isobornyl Methacrylat;ISOBOMYL METHACRYLATE
CBNumber
CB9196470
Molecular Formula
C14H22O2
Formula Weight
222.33
MOL File
7534-94-3.mol
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Isobornyl methacrylate Property

Melting point:
-60 °C
Boiling point:
127-129 °C15 mm Hg(lit.)
Density 
0.983 g/mL at 25 °C(lit.)
vapor pressure 
7.5Pa at 20℃
refractive index 
n20/D 1.477(lit.)
Flash point:
225 °F
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
form 
Liquid
Specific Gravity
0.985
color 
Clear colorless to yellow
Water Solubility 
negligible
InChIKey
HHHKSPVBHWRWNA-QOZQQMKHSA-N
LogP
5.09
CAS DataBase Reference
7534-94-3(CAS DataBase Reference)
EPA Substance Registry System
Isobornyl methacrylate (7534-94-3)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
2
TSCA 
TSCA listed
HS Code 
29161400
Hazardous Substances Data
7534-94-3(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
392111
Product name
Isobornyl methacrylate
Purity
technical grade
Packaging
100ml
Price
$58.8
Updated
2024/03/01
Sigma-Aldrich
Product number
392111
Product name
Isobornyl methacrylate
Purity
technical grade
Packaging
1l
Price
$248
Updated
2024/03/01
TCI Chemical
Product number
I0617
Product name
Isobornyl Methacrylate (stabilized with MEHQ)
Purity
>85.0%(GC)
Packaging
25g
Price
$31
Updated
2024/03/01
TCI Chemical
Product number
I0617
Product name
Isobornyl Methacrylate (stabilized with MEHQ)
Purity
>85.0%(GC)
Packaging
500g
Price
$128
Updated
2024/03/01
scipoly
Product number
M-118
Product name
Isobornyl methacrylate
Packaging
200g
Price
$45
Updated
2024/07/03
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Isobornyl methacrylate Chemical Properties,Usage,Production

Description

Isobornyl methacrylate (IBOMA) is an acrylate monomer with a bridging ring structure. It can be used in polymerisation reactions to make other coatings or plastic products. Advantages of IBOMA and its polymers include: high viscosity, good compatibility, low volatility, low toxicity, UV resistance, water resistance, chemical resistance, and low adverse biological effects.

Chemical Properties

CLEAR COLORLESS TO YELLOW LIQUID

Characteristics

Isobornyl methacrylate is a colorless transparent liquid. It is a monomer that unifies hardness and flexibility. Due to its molecular structure, its polymer has excellent high gloss, sharp image, scratch resistance, medium resistance and weather resistance, and Its hygroscopicity is significantly lower than that of MMA (methyl methacrylate). In addition, IBOMA-added acrylic resin has good compatibility with polyester, alkyd and many volatile paint film-forming substances.

Uses

Isobornyl methacrylate is a versatile hydrophobic monomer with a good combination of hardness and flexibility that can improve the chemical and water resistance of polymer systems.

Application

Suitable for manufacturing acrylic resins with high glass transition temperatures (Tg).
Used as a thickening agent, base material, reactive diluent, and curing agent in printing ink formulations, solvent-based high-solid content transparent coatings, and curing coatings.
Suitable for producing decorative protective coatings for PET, PE, and PP soft plastic films, as well as engineering plastic components such as PE, PP, and PC.
Used as a plasticizer in the plastics industry.
Used as a viscosity improver in dental resin.

Preparation

Isobornyl methacrylate was synthesized by direct esterification of camphene and methacrylic acid.

General Description

Isobornyl methacrylate is a reactive solvent with low vapor pressure. It facilitates the free radical polymerization by forming a polymer with high glass transition temperature (Tg).

Flammability and Explosibility

Not classified

Synthesis

Isobornyl methacrylate is obtained by reacting (1S,2S,4S)-(+)-isoborneol and 4-methoxyphenol.Dissolve5g (1S,2S,4S)-(+)-isoborneol in 15 mL toluene. Add 4 mg (0.032 mmol) 4-methoxyphenol to the solution. After the addition of 0.4 g (3.24 mmol)4-dimethylamino pyridine, add a solution of 10 g (64.8 mmol) methacrylic anhydride (MAA) in 10 mL toluene dropwise to the mixture. Heat the reaction mixture to 80 °C. Stir the reaction mixture for 16 hours. After cooling down to room temperature, wash the mixture with 50 mL 1M sodium bicarbonate solution four times. Wash the organic phase with 50 mL brine two times. Separate the organic phase. Remove the toluene by rotary evaporation followed by a fractional distillation under reduced pressure.
1H NMR (CDCl3, 300 MHz): δ(ppm) = 6.06 (dq, 1H, 1); 5.51 (dq, 1H, 2); 4.71 (m ,1H, 4); 1.93 (dd, 3H, 3); 1.87-1.5 (m, 5H, 6,7,8); 1.23-1.04 (m, 2H, 5); 1.012 (s, 3H, 9);0.86 (s, 3H, 10); 0.85 (s, 3H, 11). IR (film): ν(cm-1) = 2954 (CH2), 2879 (CH2), 1715 (C=O) 1454 (CH2), 1157 and 1053 (C=O).


Fig The synthetic method of Isobornyl methacrylate

Isobornyl methacrylate Preparation Products And Raw materials

Raw materials

Preparation Products

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Isobornyl methacrylate Suppliers

Americas 1 Belgium 2 China 317 Europe 2 France 1 Germany 5 India 8 Japan 8 Russia 1 Slovakia 1 South Korea 1 Switzerland 2 The Netherlands 2 United Kingdom 3 United States 33 Global 387
Yancheng Green Chemicals Co.,Ltd.
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Anhui Royal Chemical Co., Ltd.
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Suzhou Senfeida Chemical Material Co., Ltd.
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IGM RESINS
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View Lastest Price from Isobornyl methacrylate manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Isobornyl methacrylate 7534-94-3
Price
US $99.00-35.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-14
Hebei Mujin Biotechnology Co.,Ltd
Product
Isobornyl methacrylate 7534-94-3
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-07-28
Jinan Finer Chemical Co., Ltd
Product
Isobornyl methacrylate 7534-94-3
Price
US $0.00/Kg/Drum
Min. Order
1KG
Purity
99%
Supply Ability
1000mt
Release date
2021-12-07

7534-94-3, Isobornyl methacrylateRelated Search:

PHENYL METHACRYLATE Butyl methacrylate Dimethyl succinate tetradecyl methacrylate Dodecyl 2-methylacrylate Methyl propiolate Isobornyl acrylate Octadecyl methacrylate 2-Methyl-2-propenoic acid cyclohexyl ester Methyl acrylate Tris(trimethylsilyl)phosphate 2-Isocyanatoethyl methacrylate Ethylene dimethacrylate Methacrylic acid Poly(methyl methacrylate) Diethyl phthalate METHYLTHYMOL BLUE 2-Hydroxypropyl methacrylate

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  • 7534-94-3
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  • 7534-94-3