ChemicalBook > CAS DataBase List > Tetrakis(acetonitrile)copper(I) tetrafluoroborate

Tetrakis(acetonitrile)copper(I) tetrafluoroborate

Product Name
Tetrakis(acetonitrile)copper(I) tetrafluoroborate
CAS No.
15418-29-8
Chemical Name
Tetrakis(acetonitrile)copper(I) tetrafluoroborate
Synonyms
Cu(MeCN)4BF4;e)copper(I) TetrafL;Tetrakis(acetonitriL;Tetra(acetonitrile)copper(1+) tetraflu;Copper(I) tetra(acetonitrile) tetrafluoroborate;Tetra(acetonitrile)copper(1+) tetrafluoroborate;Tetra(acetonitrile) Copper(I) tetrafluoroborate;TETRAKIS(ACETONITRILE)COPPER(1)TETRAFLUORO BORATE;Copper(1+) tetrafluoroborate acetonitrile (1:1:4);Tetrakis(acetonitrile)copper(I) tetrafluoroborate
CBNumber
CB92093324
Molecular Formula
C8H12BCuF4N4
Formula Weight
314.56
MOL File
15418-29-8.mol
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Tetrakis(acetonitrile)copper(I) tetrafluoroborate Property

Melting point:
164 °C(dec.)
Density 
1.466 g cm-3
storage temp. 
Inert atmosphere,Room Temperature
solubility 
soluble in toluene, CH2Cl2, MeCN.
form 
powder to crystal
color 
White to Almost white
Decomposition 
270 °C (161-171 °C, sealed tube; 167-169 °C with decomposition)
InChI
InChI=1S/4C2H3N.BF4.Cu/c4*1-2-3;2-1(3,4)5;/h4*1H3;;/q;;;;-1;+1
InChIKey
YZGSKMIIVMCEFE-UHFFFAOYSA-N
SMILES
[B+3]([F-])([F-])([F-])[F-].[Cu+](N#CC)(N#CC)(N#CC)N#CC
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 1759 8/PG 2
WGK Germany 
3
HazardClass 
8
PackingGroup 
III
HS Code 
29269090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
677892
Product name
Tetrakis(acetonitrile)copper(I) tetrafluoroborate
Purity
97%
Packaging
1g
Price
$31.4
Updated
2025/07/31
Sigma-Aldrich
Product number
677892
Product name
Tetrakis(acetonitrile)copper(I) tetrafluoroborate
Purity
97%
Packaging
5g
Price
$94.5
Updated
2025/07/31
TCI Chemical
Product number
T2666
Product name
Tetrakis(acetonitrile)copper(I) Tetrafluoroborate
Purity
>98.0%(T)
Packaging
1g
Price
$24
Updated
2025/07/31
TCI Chemical
Product number
T2666
Product name
Tetrakis(acetonitrile)copper(I) Tetrafluoroborate
Purity
>98.0%(T)
Packaging
5g
Price
$63
Updated
2025/07/31
TCI Chemical
Product number
T2666
Product name
Tetrakis(acetonitrile)copper(I) Tetrafluoroborate
Purity
>98.0%(T)
Packaging
25g
Price
$225
Updated
2025/07/31
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Tetrakis(acetonitrile)copper(I) tetrafluoroborate Chemical Properties,Usage,Production

Chemical Properties

White crystalline powder

Uses

Catalyst in Diels-Alder and Ullmann reactions, intramolecular aromatic annulations, ring expansions in steroids, asymmetric aziridination of alkenes, substitution of allylic halides and mesylates, the Kharasch-Sosnovsky reaction.

General Description

This product has been enhanced for catalytic efficiency.

reaction suitability

core: copper
reagent type: catalyst

Synthesis

The Preparative Method of Tetrakis(acetonitrile)copper(I) Tetrafluoroborate: Several available, e.g. modification of the known hexafluorophosphate procedure, addition of Acetonitrile to the CuBF4-toluene complex, and treatment of Copper(I) Oxide with Boron Trifluoride Etherate in MeCN.

Precautions

Irritant; moisture sensitive; handle under inert atmosphere. Use in a fume hood.

Tetrakis(acetonitrile)copper(I) tetrafluoroborate Preparation Products And Raw materials

Raw materials

Preparation Products

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Tetrakis(acetonitrile)copper(I) tetrafluoroborate Suppliers

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View Lastest Price from Tetrakis(acetonitrile)copper(I) tetrafluoroborate manufacturers

Career Henan Chemical Co
Product
Copper(1+) tetrafluoroborate acetonitrile (1:1:4) 15418-29-8
Price
US $3.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
1kg,5kg,50kg
Release date
2020-01-18

15418-29-8, Tetrakis(acetonitrile)copper(I) tetrafluoroborateRelated Search:

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