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BIS(3,5-DI(TRIFLUOROMETHYL)PHENYL)CHLOROPHOSPHINE

Product Name
BIS(3,5-DI(TRIFLUOROMETHYL)PHENYL)CHLOROPHOSPHINE
CAS No.
142421-57-6
Chemical Name
BIS(3,5-DI(TRIFLUOROMETHYL)PHENYL)CHLOROPHOSPHINE
Synonyms
BIS(3,5-DI(TRIFLUOROMETHYL)PHENYL)CHLOROPHOSPHINE;Bis(3,5-bis(trifluoromethyl)phenyl)chlorophosphine;BIS[BIS(3,5-TRIFLUOROMETHYL)PHENYL]CHLOROPHOSPHINE;Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine;Bis(3,5-Bis(Trifluoromethyl)Ohenyl)Chlorophosphane;bis[3,5-bis(trifluoromethyl)phenyl]-chlorophosphane;Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine, 98+%;Bis(3,5-di(trifluoroMethyl)phenyl)chlorophosphine,Min.98%;P,P-Bis[3,5-bis(trifluoromethyl)phenyl]phosphinous chloride;Phosphinous chloride, P,P-bis[3,5-bis(trifluoromethyl)phenyl]-
CBNumber
CB9217634
Molecular Formula
C16H6ClF12P
Formula Weight
492.63
MOL File
142421-57-6.mol
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BIS(3,5-DI(TRIFLUOROMETHYL)PHENYL)CHLOROPHOSPHINE Property

Melting point:
25-29 °C
Boiling point:
333.2±42.0 °C(Predicted)
form 
liquid
color 
colorless
Water Solubility 
Reacts with water.
Sensitive 
Moisture Sensitive
InChI
1S/C16H6ClF12P/c17-30(11-3-7(13(18,19)20)1-8(4-11)14(21,22)23)12-5-9(15(24,25)26)2-10(6-12)16(27,28)29/h1-6H
InChIKey
DFZQEHBNAJGDCT-UHFFFAOYSA-N
SMILES
FC(F)(F)c1cc(cc(c1)C(F)(F)F)P(Cl)c2cc(cc(c2)C(F)(F)F)C(F)(F)F
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Safety

Hazard Codes 
C
Risk Statements 
14-34
Safety Statements 
26-36/37/39-45
RIDADR 
UN3265
WGK Germany 
3
HazardClass 
8
PackingGroup 
II
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
Hazard Classifications
Skin Corr. 1B
Water-react 3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H261In contact with water releases flammable gas

H314Causes severe skin burns and eye damage

Precautionary statements

P231+P232Handle under inert gas. Protect from moisture.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

P422Store contents under …

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
694746
Product name
Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine
Packaging
500mg
Price
$75.81
Updated
2025/07/31
Sigma-Aldrich
Product number
694746
Product name
Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine
Packaging
100mg
Price
$49.9
Updated
2023/01/07
Strem Chemicals
Product number
15-0114
Product name
Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine, min. 98%
Packaging
500mg
Price
$53
Updated
2024/03/01
Strem Chemicals
Product number
15-0114
Product name
Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine, min. 98%
Packaging
2g
Price
$156
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
ING0005744
Product name
BIS(3,5-DI(TRIFLUOROMETHYL)PHENYL)CHLOROPHOSPHINE
Purity
95.00%
Packaging
25G
Price
$1695.75
Updated
2021/12/16
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BIS(3,5-DI(TRIFLUOROMETHYL)PHENYL)CHLOROPHOSPHINE Chemical Properties,Usage,Production

Uses

Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine is used as a reactant for the synthesis of chiral phosphine-aminophosphine ligands for rhodium-catalyzed asymmetric hydrogenation, ligands for palladium-catalyzed stereoselective allylation reactions, enantioselective hydrogenations, Josiphos analog as catalyst for asymmetric hydrogenation, ligands used in asymmetric hydrovinylation reactions.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

BIS(3,5-DI(TRIFLUOROMETHYL)PHENYL)CHLOROPHOSPHINE Preparation Products And Raw materials

Raw materials

Preparation Products

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BIS(3,5-DI(TRIFLUOROMETHYL)PHENYL)CHLOROPHOSPHINE Suppliers

J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
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96815
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Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
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Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
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China
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9401
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Energy Chemical
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021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
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Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
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China
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Shanghai Macklin Biochemical Co.,Ltd.
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15221275939
Fax
021-50706099
Email
shenlinxing@macklin.cn
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China
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15872
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Sigma-Aldrich
Tel
021-61415566 800-8193336
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orderCN@merckgroup.com
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China
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Panjin Infinity Scientific CO. LTD
Tel
400-1062016 18612996721
Fax
QQ25788917
Email
hao@infsci.com
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China
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Aikon International Limited
Tel
025-58859352 18068836627
Fax
02557626880
Email
sales01@aikonchem.com
Country
China
ProdList
16027
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58
Rhawn Reagent
Tel
400-400-1332688 18019345275
Fax
400-133-2688
Email
amy@rhawn.cn
Country
China
ProdList
14948
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58
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View Lastest Price from BIS(3,5-DI(TRIFLUOROMETHYL)PHENYL)CHLOROPHOSPHINE manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine 142421-57-6
Price
US $1.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 tons
Release date
2020-01-16

142421-57-6, BIS(3,5-DI(TRIFLUOROMETHYL)PHENYL)CHLOROPHOSPHINERelated Search:


  • BIS(3,5-DI(TRIFLUOROMETHYL)PHENYL)CHLOROPHOSPHINE
  • BIS[BIS(3,5-TRIFLUOROMETHYL)PHENYL]CHLOROPHOSPHINE
  • Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine, 98+%
  • Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine
  • Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine, 98+%, may contain suspended dimethylamine hydrochloride crystals
  • P,P-Bis[3,5-bis(trifluoromethyl)phenyl]phosphinous chloride
  • bis[3,5-bis(trifluoromethyl)phenyl]-chlorophosphane
  • Bis(3,5-di(trifluoroMethyl)phenyl)chlorophosphine,Min.98%
  • Phosphinous chloride, P,P-bis[3,5-bis(trifluoromethyl)phenyl]-
  • High purity CAS 142421-57-6 BIS(3,5-DI(TRIFLUOROMETHYL)PHENYL)CHLOROPHOSPHINE in stock
  • Bis(3,5-bis(trifluoromethyl)phenyl)chlorophosphine
  • Bis(3,5-Bis(Trifluoromethyl)Ohenyl)Chlorophosphane
  • 142421-57-6
  • C16H6ClF12P
  • Catalysis and Inorganic Chemistry
  • Phosphorus Compounds
  • Phosphorus Precursors
  • organophosphine ligand
  • Achiral Phosphine
  • Aryl Phosphine
  • P-Cl