1,3-Dimethyl-1,3-diphenylurea

ChemicalBook > CAS DataBase List > 1,3-Dimethyl-1,3-diphenylurea

1,3-Dimethyl-1,3-diphenylurea

Product Name: 1,3-Dimethyl-1,3-diphenylurea
CAS No.: 611-92-7
Chemical Name: 1,3-Dimethyl-1,3-diphenylurea
Synonyms: Centralite II;Zentralin;Zentralit I;Centralite-2;Centralit II;Zentralit II;Centralite ll;METHYL CENTRALITE;Dimethyldiphenylurea;N,N'-DIMETHYLCARBANILIDE
CBNumber: CB9218833
Molecular Formula: C15H16N2O
Formula Weight: 240.3
MOL File: 611-92-7.mol

Less

1,3-Dimethyl-1,3-diphenylurea Property

Melting point:: 120-122 °C(lit.)
Boiling point:: 383.02°C (rough estimate)
Density: 1.0611 (rough estimate)
vapor pressure: 0.001Pa at 25℃
refractive index: 1.6390 (estimate)
storage temp.: 2-8°C
solubility: Dichloromethane (Slightly), DMSO (Slightly), Methanol (Very Slightly)
form: Solid
pka: 0.68±0.50(Predicted)
color: White to Pale Green
Water Solubility: 76.42mg/L at 20℃
InChI: InChI=1S/C15H16N2O/c1-16(13-9-5-3-6-10-13)15(18)17(2)14-11-7-4-8-12-14/h3-12H,1-2H3
InChIKey: ADCBKYIHQQCFHE-UHFFFAOYSA-N
SMILES: N(C)(C1=CC=CC=C1)C(N(C)C1=CC=CC=C1)=O
LogP: 2.82 at 25℃
CAS DataBase Reference: 611-92-7(CAS DataBase Reference)
EPA Substance Registry System: Urea, N,N'-dimethyl-N,N'-diphenyl- (611-92-7)

Less

Safety

Safety Statements: 22-24/25
WGK Germany: 2
RTECS: FE0600000

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Less

N-Bromosuccinimide Price

TRC

Product number: C256618
Product name: CentraliteII
Packaging: 250mg
Price: $40
Updated: 2021/12/16

TRC

Product number: C256618
Product name: CentraliteII
Packaging: 5g
Price: $250
Updated: 2021/12/16

AK Scientific

Product number: 0570BA
Product name: 1,3-Dimethyl-1,3-diphenylurea
Packaging: 25g
Price: $517
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0115204
Product name: 1,3-DIMETHYL-1,3-DIPHENYLUREA
Purity: 95.00%
Packaging: 100G
Price: $2461.88
Updated: 2021/12/16

Alichem

Product number: 611927
Product name: 1,3-Dimethyl-1,3-diphenylurea
Packaging: 100g
Price: $742.5
Updated: 2021/12/16

Less

1,3-Dimethyl-1,3-diphenylurea Chemical Properties,Usage,Production

Chemical Properties

Centralite II, also known as 1,3-Dimethyl-1,3-diphenylurea, is a white to grey crystalline powder that is soluble in water, alcohol, acetone, and chloroform. This substance is commonly used as a burning rate moderator and stabilizer for smokeless powder, as well as a plasticizer for celluloid.

Uses

Detection of Methyl Centralite (MC) as gunshot residues (GSR) has been developed.

Description

1,3-Dimethyl-1,3-diphenylurea for Stabilizer and propellant, and production of intermediates of organic chemicals.

Application

Centralite II can be used as a stabilizer for smokeless powder, explosives, nitrates and smokeless fuels, as well as intermediates for fine chemicals.

Uses

1,3-Dimethyl-1,3-diphenylurea (methyl centralite) is a stabilizer in different types of ammunition. This compound is organic gunshot residue. It is the characteristic compound for which forensic analysts test determining if a person has discharged a firearm[1-2].

Flammability and Explosibility

Not classified

Synthesis

To a 10 mL Schlenk tube equipped with a magnetic stirring bar was charged with arylcarbamoyl chlorides (0.2 mmol, 1.0 equiv), and KHCO3 (40 mg, 0.4 mmol), and then Pd(PPh3)4 (0.01 mmol, 11.56 mg) were added. Finally, 1,4-dioxane (1.0 mL) was added to the mixture via syringe at room temperature under N2. The tube was sealed and put into a preheated oil bath a 100 °C for 48 h. The mixture was cooled to room temperature, quenched with water (5 mL), and diluted with ethyl acetate (5 mL). The layers were separated, and the aqueous layer was extracted with 2 × 5 mL of ethyl acetate. The combined organic extracts were dried over anhydrous sodium sulfate, filtered, and concentrated in vacuo. The crude product of 1,3-dimethyl-1,3-diphenylurea was purified by flash chromatography on silica gel (H), using 30-35% ethyl acetate/petroleum ether as the eluent.

References

[1] Ricardo J. González. “Detection of organic gunshot residues from human hands using direct sample analysis-time of flight-mass spectrometry.” Journal of Mass Spectrometry 57 5 (2022).
[2] Patrick W. Fedick , Ryan M. Bain. “Swab touch spray mass spectrometry for rapid analysis of organic gunshot residue from human hand and various surfaces using commercial and fieldable mass spectrometry systems.” Forensic Chemistry 5 (2017): Pages 53-57.

1,3-Dimethyl-1,3-diphenylurea Preparation Products And Raw materials

Raw materials

Preparation Products

Less

1,3-Dimethyl-1,3-diphenylurea Suppliers

China 82 Czech Republic 1 Germany 2 India 1 Japan 1 Switzerland 1 United Kingdom 5 United States 9 Global 102

Shaanxi DIDU pharmaceutical and Chemical Co., Ltd

Tel: 15229059051
Email: 1027@dideu.com
Country: China
ProdList: 9941
Advantage: 58

Hubei Tuobang Chemical Co., Ltd.

Tel: 027-59106185 13986181695
Email: 1466039@qq.com
Country: China
ProdList: 9995
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 94838
Advantage: 76

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44751
Advantage: 61

ZhengZhou HuaWen Chemical Co.Ltd

Tel: 0370-2785118 15343847665
Fax: QQ：3470079902
Email: huawenchem@163.com
Country: China
ProdList: 3206
Advantage: 55

T&W GROUP

Tel: 021-61551611 13296011611
Fax: ＋86 21-50676805
Email: contact@trustwe.com
Country: China
ProdList: 9900
Advantage: 58

Bide Pharmatech Ltd.

Tel: 400-1647117 15221909166
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 41438
Advantage: 60

Zhengzhou HongSheng Pharmaceutical Co., Ltd.

Tel: 1352-6885213 15637198702
Fax: 0371-63709726
Email: xpkchem@163.com
Country: China
ProdList: 3998
Advantage: 58

HUBEI RISON CHEMICAL CO.,LTD

Tel: 027 83642615 13995607107
Fax: 027 83660699
Email: market@risonchem.com
Country: China
ProdList: 280
Advantage: 58

Zhengzhou Gecko Scientific Inc.

Tel: 0371-63336364 17344886665
Fax: 0371-65511872
Email: 209932355@qq.com
Country: China
ProdList: 407
Advantage: 55

Amadis Chemical Company Limited

Tel: 571-89925085
Fax: 0086-571-89925065
Email: sales@amadischem.com
Country: China
ProdList: 131981
Advantage: 58

Henan Kangqian Medical Technology Co., Ltd.

Tel: +86-0371-69197788
Fax: +86-371-86568877
Email: kangmedicine@hotmail.com
Country: China
ProdList: 76
Advantage: 58

Aikon International Limited

Tel: 025-66113011 18112977050
Fax: 02557626880
Email: sales01@aikonchem.com
Country: China
ProdList: 16028
Advantage: 58

Tianjin heowns Biochemical Technology Co., Ltd.

Tel: 400-6387771-6038 18902104717
Email: sales@heowns.com
Country: China
ProdList: 20512
Advantage: 60

Zhengzhou Acme Chemical Co., Ltd.

Tel: 0371-0371-63315541 13323832564
Fax: QQ:3001332135
Email: 3001332135@qq.com
Country: China
ProdList: 8922
Advantage: 58

Shenzhen Polymeri Biochemical Technology Co., Ltd.

Tel: +86-400-002-6226 13028896684
Email: sales@rrkchem.com
Country: China
ProdList: 55827
Advantage: 58

Henan Alpha Chemical Co., Ltd.

Tel: 0371-55055611 18137792234
Fax: QQ：3002694073
Email: 3002694073@qq.com
Country: China
ProdList: 10162
Advantage: 58

ANHUI WITOP BIOTECH CO., LTD

Tel: +8615255079626
Email: eric@witopchemical.com
Country: China
ProdList: 23556
Advantage: 58

Henan Alfa Chemical Co., Ltd

Tel: +8618339805032
Email: alfa4@alfachem.cn
Country: China
ProdList: 12755
Advantage: 58

Hefei TNJ Chemical Industry Co.,Ltd.

Tel: 0551-65418671
Fax: 0551-65418697
Email: sales@tnjchem.com
Country: China
ProdList: 34572
Advantage: 58

CD Chemical Group Limited

Tel: +8615986615575
Fax: 0086-13651442114
Email: info@codchem.com
Country: China
ProdList: 20356
Advantage: 58

Dayang Chem (Hangzhou) Co.,Ltd.

Tel: 571-88938639 +8617705817739
Fax: +86-571-88938652，+86-571- 88492614
Email: info@dycnchem.com
Country: CHINA
ProdList: 52867
Advantage: 58

SIMAGCHEM CORP

Tel: +86-13806087780
Email: sale@simagchem.com
Country: China
ProdList: 17367
Advantage: 58

Chemwill Asia Co.,Ltd.

Tel: 86-21-51086038
Fax: 86-21-51861608
Email: chemwill_asia@126.com
Country: CHINA
ProdList: 23931
Advantage: 58

Hubei Jusheng Technology Co.,Ltd.

Tel: 18871490254
Fax: 027-59599243
Email: linda@hubeijusheng.com
Country: CHINA
ProdList: 28180
Advantage: 58

Shanghai Taijilin Industrial Co., Ltd.

Tel: 021-021-50630626 18964684208
Fax: 021-50563898
Email: kate@tajilin.com
Country: China
ProdList: 1212
Advantage: 58

Shandong chuangyingchemical Co., Ltd.

Tel: 18853181302
Email: sale@chuangyingchem.com
Country: CHINA
ProdList: 5909
Advantage: 58

Shanghai Longyu Biotechnology Co., Ltd.

Tel: +8615821988213
Fax: +86 15821988213
Email: info@longyupharma.com
Country: China
ProdList: 2531
Advantage: 58

Henan Huawen Chemical Co., Ltd

Tel: 0370-0370-2059268 17550075363
Fax: QQ:2712427897
Email: 1124977392@qq.com
Country: China
ProdList: 1987
Advantage: 58

Wuhan Rongcan Biotechnology Co., Ltd

Tel: 18327024450
Fax: 183-27024450
Email: 2130026275@qq.com
Country: China
ProdList: 4590
Advantage: 58

Shanghai Kaiwei Chemical Technology Co., Ltd.

Tel: 021-58461859 15821823057
Email: service@aiviche.com
Country: China
ProdList: 49323
Advantage: 58

Beijing Haite lesk Technology Co., Ltd

Tel: 15210893940; 15116916250
Fax: QQ: 237008221
Email: chemistryliu@163.com
Country: China
ProdList: 7327
Advantage: 58

ShangHai Anpel Co, Ltd.

Tel: 18501792038; 18501792038
Email: shanpel@anpel.com.cn
Country: China
ProdList: 9614
Advantage: 58

Fuxin Pharmaceutical

Tel: +86-021-021-50872116 +8613122107989
Email: contact@fuxinpharm.com
Country: China
ProdList: 10297
Advantage: 58

Henan qinpeng technology co., ltd

Tel: 18839185240 18839185240
Email: 2148319152@qq.com
Country: China
ProdList: 404
Advantage: 58

Atomic chemistry

Tel: 0370-2785705 19339619972
Fax: QQ：3564171929
Email: 2234585634@qq.com
Country: China
ProdList: 4176
Advantage: 58

Energy Chemical

Tel: 021-58432009 400-005-6266
Fax: 021-58436166
Email: marketing@energy-chemical.com
Country: China
ProdList: 44941
Advantage: 58

Mainchem Co., Ltd.

Tel: --
Fax: --
Email: sarah@mainchem.com
Country: China
ProdList: 6572
Advantage: 58

Hubei yongkuo Technology Co., Ltd

Tel: 027-59223108 15972152991
Fax: 027-59223108
Email: 1248580099@qq.com
Country: China
ProdList: 10007
Advantage: 58

Hubei Shishun Biotechnology Co. Ltd

Tel: 027-59223025 15107168801
Fax: 027-59223025
Email: 1718480011@qq.com
Country: China
ProdList: 9990
Advantage: 58

Tianmen Hengchang Chemical Co., Ltd

Tel: 027-59322316 15172518801
Fax: 027-59322316
Email: 1208480077@qq.com
Country: China
ProdList: 9944
Advantage: 58

Hubei Qifei Pharmaceutical Chemical Co., Ltd

Tel: 027-027-59322506 18071128681
Fax: 027-59322506
Email: 1438082200@qq.com
Country: China
ProdList: 9995
Advantage: 58

Shanghai Haohong Pharmaceutical Co., Ltd.

Tel: 400-8210725 4008210725
Email: malulu@leyan.com
Country: China
ProdList: 39997
Advantage: 58

Hubei Nordina Biotechnology Co., Ltd.

Tel: 18171027221; 18171027221
Fax: 18162687220
Email: nuodinashengwu@163.com
Country: China
ProdList: 2589
Advantage: 58

Henan yingchuang

Tel: 0370-3678455 16650708709
Fax: qq:778660296
Email: hnyingchuang@163.com
Country: China
ProdList: 3961
Advantage: 58

Guangdong wengjiang Chemical Reagent Co., Ltd.

Tel: 0751-2815987 13927875076
Fax: 0751-2828607
Email: 3007432263@qq.com
Country: China
ProdList: 9984
Advantage: 58

Shangqiu Ladybug Network Technology Co., LTD

Tel: 0370-2070160 19837086283
Fax: 18736733639
Email: 298644986@qq.com
Country: China
ProdList: 2968
Advantage: 58

Bide Pharmatech Ltd.

Tel: 400-6005915
Email: sales@picasso-e.com
Country: China
ProdList: 39668
Advantage: 58

Henan Evonik Biotechnology Co. LTD

Tel: 16650615803
Email: hnyingchuang@163.com
Country: China
ProdList: 3970
Advantage: 58

Shanghai Maclean Biochemical Technology Co., LTD

Tel: 021-50706066 15221275939
Email: shenlinxing@macklin.cn
Country: China
ProdList: 29803
Advantage: 58

Less

View Lastest Price from 1,3-Dimethyl-1,3-diphenylurea manufacturers

Shandong Juchuang Chemical Co., LTD

Product: 1,3-Dimethyl-1,3-diphenylurea 611-92-7
Price: US $30.00-10.00/kg
Min. Order: 500kg
Purity: 99.9
Supply Ability: 200tons
Release date: 2024-03-12

Chongqing Hesheng Longgang Technology Co. Ltd.

Product: Centralite?II 611-92-7
Price: US $29.80-11.80/kg
Min. Order: 3000kg
Purity: 99%
Supply Ability: 1500000
Release date: 2023-02-04

Chongqing Hesheng Longgang Technology Co. Ltd.

Product: Centralite ll 611-92-7
Price: US $11.90-11.30/KG
Min. Order: 1000KG
Purity: 99%
Supply Ability: 200000
Release date: 2023-05-09

611-92-7, 1,3-Dimethyl-1,3-diphenylureaRelated Search:

1,3-Dimethyl-1,3-diphenylurea 1,3-Diethyl-1,3-diphenylurea N,N'-Diphenylurea Phenylurea AKOS B028777 1,3-BIS(4-METHYLPHENYL)-5-((4-CHLOROPHENYL)METHYLENE)-1,3-DIAZAPERHYDROINE-2,4,6-TRIONE 6-CHLORO-1,3-DIPHENYL-1,2,3,4-TETRAHYDROPYRIMIDINE-2,4-DIONE AURORA KA-3830 1,3-DIPHENYLPARABANIC ACID AURORA KA-3840 1,3-BIS(4-METHYLPHENYL)-5-((4-METHOXYPHENYL)METHYLENE)-1,3-DIAZAPERHYDROINE-2,4,6-TRIONE AURORA KA-6376 1,3-DIPHENYL-6-[(1,1,1-TRIPHENYL-LAMBDA5-PHOSPHANYLIDENE)AMINO]-1,2,3,4-TETRAHYDROPYRIMIDINE-2,4-DIONE AURORA KA-4968 AURORA KA-3223 AURORA KA-4914 AURORA KA-3218 5-((3,4-DIMETHOXYPHENYL)METHYLENE)-1,3-BIS(4-METHYLPHENYL)-1,3-DIAZAPERHYDROINE-2,4,6-TRIONE

N,N-DIMETHYL CARBANILIDE

N,N'-DIMETHYLCARBANILIDE

N,N'-DIMETHYL-N,N'-DIPHENYLUREA

1,3-DIMETHYL-1,3-DIPHENYLUREA

METHYL CENTRALITE

N,N'-Dimethyl-N,N'-diphenylharnstoff

sym-Dimethyldiphenylurea

Carbanilide, N,N'-dimethyl-

Centralit II

Centralite II

Centralite-2

Zentralin

Zentralit I

Zentralit II

N,N'-Dimethyldiphenylurea (Methyl Centralite)

Methylcentralite@100 μg/mL in Acetonitrile:Methanol (50:50)

1,3-Dimethyl-1,3-diphenylure

Centralite ll

N,N-DIMETHYLDIPHENYLUREA

Dimethyldiphenylurea

N,N'-Dimethyl-N,N'-diphenylurea

611-92-7

C6H5NCH32CO

Carbonyl Compounds

Building Blocks

Organic Building Blocks

Ureas

Industrial/Fine Chemicals

Carbonyl Compounds

Organic Building Blocks

Ureas