ChemicalBook > CAS DataBase List > 9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-oxide

9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-oxide

Product Name
9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-oxide
CAS No.
35948-25-5
Chemical Name
9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-oxide
Synonyms
DOP;DOPO;FR-DOPO;Flame Retardant DOPO;10H-9-Oxa-10-phosphaphenanthrene 10-oxide;10-Dihydro-9-oxa-10-phosphaphenanthrene-10-oxide;PD-3710;DOPO, 99.5%;C6H4P(O)(H)OC6H4;9,10-Dihydro-9-oxa
CBNumber
CB9228371
Molecular Formula
C12H9O2P
Formula Weight
216.17
MOL File
35948-25-5.mol
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9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-oxide Property

Melting point:
119°C
Boiling point:
399.7±25.0 °C(Predicted)
vapor pressure 
0.004Pa at 25℃
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Solid
color 
White to Off-White
Water Solubility 
3.574g/L at 25℃
InChI
InChI=1S/C12H9O2P/c13-15-12-8-4-2-6-10(12)9-5-1-3-7-11(9)14-15/h1-8,15H
InChIKey
VBQRUYIOTHNGOP-UHFFFAOYSA-N
SMILES
O1C2=CC=CC=C2C2=CC=CC=C2P1=O
LogP
1.87
CAS DataBase Reference
35948-25-5(CAS DataBase Reference)
EPA Substance Registry System
6H-Dibenz[c,e][1,2]oxaphosphorin, 6-oxide (35948-25-5)
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Safety

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
HS Code 
2934999090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TCI Chemical
Product number
D1874
Product name
9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-Oxide
Purity
>97.0%(T)
Packaging
25g
Price
$33
Updated
2025/07/31
TCI Chemical
Product number
D1874
Product name
9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-Oxide
Purity
>97.0%(T)
Packaging
100g
Price
$72
Updated
2025/07/31
TCI Chemical
Product number
D1874
Product name
9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-Oxide
Purity
>97.0%(T)
Packaging
500g
Price
$151
Updated
2025/07/31
TRC
Product number
D679033
Product name
9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-Oxide
Packaging
500mg
Price
$70
Updated
2021/12/16
Usbiological
Product number
273133
Product name
9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-Oxide
Packaging
100g
Price
$345
Updated
2021/12/16
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9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-oxide Chemical Properties,Usage,Production

Uses

9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-Oxide is an high effective componant of flame retardant epoxy resins.

Flammability and Explosibility

Non flammable

Synthesis

22749-43-5

35948-25-5

General procedure for the synthesis of 9,10-dihydro-9-oxa-10-phosphaphenanthrene from 10-chloro-9,10-dihydro-9-oxa-10-phosphaphenanthrene: 10 g of 6-chloro-6H-dibenzo[c,e][1,2]oxaphosphorine (0.0426 mol), 1.2 g of hydrochloric acid (0.0335 mol), and 2.1 g of water were added to a reactor and stirred for 5 minutes to form a homogeneous solution. The reaction mixture was heated at 80 °C for 1 h. Upon completion of the reaction, the system was divided into an organic layer and an aqueous layer. The temperature of the organic layer was maintained at 80 °C, and the organic layer was separated and transferred to another reactor. Reduced pressure distillation was carried out at 165 °C and 0.3 mbar to give 9.03 g of the white solid product 9,10-dihydro-9-oxa-10-phospha-phenanthrene-10-oxide [Yield: 98%; Color: 8 Hazen; Purity: 99.25% (major component: minor component = 99.25%: 0.75%); Melting point: 122.13 °C (DSC peak)] .

References

[1] Patent: US2011/34717, 2011, A1. Location in patent: Page/Page column 3
[2] Patent: US2007/173659, 2007, A1. Location in patent: Page/Page column 5
[3] J. Gen. Chem. USSR (Engl. Transl.), 1972, vol. 42, p. 88 - 90
[4] Zhurnal Obshchei Khimii, 1972, vol. 42, p. 93 - 96
[5] Heterocycles, 2011, vol. 83, # 4, p. 743 - 753

9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-oxide Preparation Products And Raw materials

Raw materials

Preparation Products

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9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-oxide Suppliers

Zhengzhou Alfachem Co.,Ltd.
Tel
0371-53778726 18003825608
Fax
QQ:2885354392
Email
liuxiaoyan@alfachem.cn
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China
ProdList
1986
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Changzhou Run-chem Biotech Co., ltd
Tel
15061933924
Email
3301839366@qq.com
Country
China
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930
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58
Guangzhou Shanghe Chemical Technology Co., Ltd
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13352869970; 13352869970
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272907493@qq.com
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China
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1140
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HEZE DIJADE CHEMCAL CORPORATION
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0530-7157019 18678572026
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3109950577@qq.com
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China
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J & K SCIENTIFIC LTD.
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18210857532; 18210857532
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86-10-82849933
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jkinfo@jkchemical.com
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China
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Meryer (Shanghai) Chemical Technology Co., Ltd.
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4006356688 18621169109
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86-21-61259102
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market03@meryer.com
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China
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40228
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TAIYUAN RHF CO.,LTD.
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+86 351 7031519
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+86 351 7031519
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sales@RHFChem.com
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China
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TCI (Shanghai) Development Co., Ltd.
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021-67121386
Fax
021-67121385
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Sales-CN@TCIchemicals.com
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China
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24529
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Beijing HwrkChemical Technology Co., Ltd
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18515581800 18501085097
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010-89508210
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sales.bj@hwrkchemical.com
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China
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Energy Chemical
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021-021-58432009 400-005-6266
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021-58436166
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sales8178@energy-chemical.com
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China
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View Lastest Price from 9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-oxide manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Polyglyceryl-2 dipolyhydroxystearate 35948-25-5
Price
US $0.00/KG
Min. Order
1KG
Purity
98.0%
Supply Ability
1000kg/month
Release date
2023-08-31
Hebei Chuanghai Biotechnology Co., Ltd
Product
9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-oxide 35948-25-5
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100 mt
Release date
2024-11-21
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Polyglyceryl-2 dipolyhydroxystearate 35948-25-5
Price
US $70.00/kg
Min. Order
1kg
Purity
99
Supply Ability
5000
Release date
2024-06-05

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