9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-oxide
- Product Name
- 9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-oxide
- CAS No.
- 35948-25-5
- Chemical Name
- 9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-oxide
- Synonyms
- DOP;DOPO;FR-DOPO;Flame Retardant DOPO;10H-9-Oxa-10-phosphaphenanthrene 10-oxide;10-Dihydro-9-oxa-10-phosphaphenanthrene-10-oxide;PD-3710;DOPO, 99.5%;C6H4P(O)(H)OC6H4;9,10-Dihydro-9-oxa
- CBNumber
- CB9228371
- Molecular Formula
- C12H9O2P
- Formula Weight
- 216.17
- MOL File
- 35948-25-5.mol
9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-oxide Property
- Melting point:
- 119°C
- Boiling point:
- 399.7±25.0 °C(Predicted)
- vapor pressure
- 0.004Pa at 25℃
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- Chloroform (Slightly), Methanol (Slightly)
- form
- Solid
- color
- White to Off-White
- Water Solubility
- 3.574g/L at 25℃
- InChI
- InChI=1S/C12H9O2P/c13-15-12-8-4-2-6-10(12)9-5-1-3-7-11(9)14-15/h1-8,15H
- InChIKey
- VBQRUYIOTHNGOP-UHFFFAOYSA-N
- SMILES
- O1C2=CC=CC=C2C2=CC=CC=C2P1=O
- LogP
- 1.87
- CAS DataBase Reference
- 35948-25-5(CAS DataBase Reference)
- EPA Substance Registry System
- 6H-Dibenz[c,e][1,2]oxaphosphorin, 6-oxide (35948-25-5)
Safety
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39
- HS Code
- 2934999090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
N-Bromosuccinimide Price
- Product number
- D1874
- Product name
- 9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-Oxide
- Purity
- >97.0%(T)
- Packaging
- 25g
- Price
- $33
- Updated
- 2025/07/31
- Product number
- D1874
- Product name
- 9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-Oxide
- Purity
- >97.0%(T)
- Packaging
- 100g
- Price
- $72
- Updated
- 2025/07/31
- Product number
- D1874
- Product name
- 9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-Oxide
- Purity
- >97.0%(T)
- Packaging
- 500g
- Price
- $151
- Updated
- 2025/07/31
- Product number
- D679033
- Product name
- 9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-Oxide
- Packaging
- 500mg
- Price
- $70
- Updated
- 2021/12/16
- Product number
- 273133
- Product name
- 9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-Oxide
- Packaging
- 100g
- Price
- $345
- Updated
- 2021/12/16
9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-oxide Chemical Properties,Usage,Production
Uses
9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-Oxide is an high effective componant of flame retardant epoxy resins.
Flammability and Explosibility
Non flammable
Synthesis
22749-43-5
35948-25-5
General procedure for the synthesis of 9,10-dihydro-9-oxa-10-phosphaphenanthrene from 10-chloro-9,10-dihydro-9-oxa-10-phosphaphenanthrene: 10 g of 6-chloro-6H-dibenzo[c,e][1,2]oxaphosphorine (0.0426 mol), 1.2 g of hydrochloric acid (0.0335 mol), and 2.1 g of water were added to a reactor and stirred for 5 minutes to form a homogeneous solution. The reaction mixture was heated at 80 °C for 1 h. Upon completion of the reaction, the system was divided into an organic layer and an aqueous layer. The temperature of the organic layer was maintained at 80 °C, and the organic layer was separated and transferred to another reactor. Reduced pressure distillation was carried out at 165 °C and 0.3 mbar to give 9.03 g of the white solid product 9,10-dihydro-9-oxa-10-phospha-phenanthrene-10-oxide [Yield: 98%; Color: 8 Hazen; Purity: 99.25% (major component: minor component = 99.25%: 0.75%); Melting point: 122.13 °C (DSC peak)] .
References
[1] Patent: US2011/34717, 2011, A1. Location in patent: Page/Page column 3
[2] Patent: US2007/173659, 2007, A1. Location in patent: Page/Page column 5
[3] J. Gen. Chem. USSR (Engl. Transl.), 1972, vol. 42, p. 88 - 90
[4] Zhurnal Obshchei Khimii, 1972, vol. 42, p. 93 - 96
[5] Heterocycles, 2011, vol. 83, # 4, p. 743 - 753
9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-oxide Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-oxide manufacturers
- Product
- Polyglyceryl-2 dipolyhydroxystearate 35948-25-5
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98.0%
- Supply Ability
- 1000kg/month
- Release date
- 2023-08-31
- Product
- 9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-oxide 35948-25-5
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100 mt
- Release date
- 2024-11-21
- Product
- Polyglyceryl-2 dipolyhydroxystearate 35948-25-5
- Price
- US $70.00/kg
- Min. Order
- 1kg
- Purity
- 99
- Supply Ability
- 5000
- Release date
- 2024-06-05