5,6,8,14-Tetradehydro-6-methoxy-17-methyl-2,3-[methylenebisoxy]morphinan-7β-ol

Product Name
5,6,8,14-Tetradehydro-6-methoxy-17-methyl-2,3-[methylenebisoxy]morphinan-7β-ol
CAS No.
4850-04-8
Chemical Name
5,6,8,14-Tetradehydro-6-methoxy-17-methyl-2,3-[methylenebisoxy]morphinan-7β-ol
Synonyms
Nudaurine;Amurinol I;5,6,8,14-Tetradehydro-6-methoxy-17-methyl-2,3-[methylenebisoxy]morphinan-7β-ol;Morphinan-7-ol, 5,6,8,14-tetradehydro-6-methoxy-17-methyl-2,3-[methylenebis(oxy)]-, (7β)- (9CI)
CBNumber
CB92398326
Molecular Formula
C19H21NO4
Formula Weight
327.37
MOL File
4850-04-8.mol
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5,6,8,14-Tetradehydro-6-methoxy-17-methyl-2,3-[methylenebisoxy]morphinan-7β-ol Property

Melting point:
201-2°C
Boiling point:
523.6±50.0 °C(Predicted)
Density 
1.38±0.1 g/cm3(Predicted)
pka
12.41±0.40(Predicted)
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Hazard and Precautionary Statements (GHS)

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5,6,8,14-Tetradehydro-6-methoxy-17-methyl-2,3-[methylenebisoxy]morphinan-7β-ol Chemical Properties,Usage,Production

Description

A morphine type alkaloid, this base is a minor constituent of the seeds of Papaver nudicaule var. amurense. It forms clusters of colourless crystals from Me2CO and has [α] 22 D - 52° (c 1.0, CHCI3). The salts are crystalline and include the hydriodide, m.p. 198°C (dec.); perchlorate, m.p. 188°C (dec.) and the picrate, m.p. 150°C (dec.). The structure given above has been determined on the basis of the infrared, NMR and mass spectra.

References

Boit, Flentje., Naturwiss., 47,180 (1960)
Flentje, Dopke, Jeffs., ibid, 52,259 (1965)
Dopke, Flentje, Jeffs., Tetrahedron, 24,4459 (1968)
Absolute configuration: Barton et ai., Chern. Ber., 100,2457 (1967)
Circular dichroism: Snatzke, Wollenberg.,!. Chern. Soc., C, 1581 (1966)

5,6,8,14-Tetradehydro-6-methoxy-17-methyl-2,3-[methylenebisoxy]morphinan-7β-ol Preparation Products And Raw materials

Raw materials

Preparation Products

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5,6,8,14-Tetradehydro-6-methoxy-17-methyl-2,3-[methylenebisoxy]morphinan-7β-ol Suppliers

4850-04-8, 5,6,8,14-Tetradehydro-6-methoxy-17-methyl-2,3-[methylenebisoxy]morphinan-7β-olRelated Search:


  • 5,6,8,14-Tetradehydro-6-methoxy-17-methyl-2,3-[methylenebisoxy]morphinan-7β-ol
  • Amurinol I
  • Nudaurine
  • Morphinan-7-ol, 5,6,8,14-tetradehydro-6-methoxy-17-methyl-2,3-[methylenebis(oxy)]-, (7β)- (9CI)
  • 4850-04-8