METHYL 2-(4-FLUORO-3-NITROPHENYL)ACETATE

Product Name: METHYL 2-(4-FLUORO-3-NITROPHENYL)ACETATE
CAS No.: 226888-37-5
Chemical Name: METHYL 2-(4-FLUORO-3-NITROPHENYL)ACETATE
Synonyms: Methyl 3-nitro-4-fluorophenylacetate;Methyl (4-fluoro-3-nitrophenyl)acetate;METHYL 2-(4-FLUORO-3-NITROPHENYL)ACETATE;4-fluoro-3-nitrophenylacetic acid methyl ester;Benzeneacetic acid, 4-fluoro-3-nitro-, methyl ester
CBNumber: CB92452745
Molecular Formula: C9H8FNO4
Formula Weight: 213.16
MOL File: 226888-37-5.mol

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METHYL 2-(4-FLUORO-3-NITROPHENYL)ACETATE Property

Boiling point:: 320.5±27.0 °C(Predicted)
Density: 1.346±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
Appearance: Light yellow to yellow Solid-liquid mixture

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H360May damage fertility or the unborn child

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P308+P313IF exposed or concerned: Get medical advice/attention.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC

Product number: M706758
Product name: Methyl2-(4-fluoro-3-nitrophenyl)acetate
Packaging: 50mg
Price: $175
Updated: 2021/12/16

AK Scientific

Product number: CS-0042132
Product name: Methyl2-(4-fluoro-3-nitrophenyl)acetate
Packaging: 1g
Price: $90
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0360279
Product name: METHYL-2-(4-FLUORO-3-NITROPHENYL)ACETATE
Purity: 95.00%
Packaging: 5MG
Price: $502.5
Updated: 2021/12/16

Ambeed

Product number: A131024
Product name: Methyl2-(4-fluoro-3-nitrophenyl)acetate
Purity: 95%
Packaging: 100mg
Price: $18
Updated: 2021/12/16

Ambeed

Product number: A131024
Product name: Methyl2-(4-fluoro-3-nitrophenyl)acetate
Purity: 95%
Packaging: 250mg
Price: $31
Updated: 2021/12/16

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METHYL 2-(4-FLUORO-3-NITROPHENYL)ACETATE Chemical Properties,Usage,Production

Synthesis

67-56-1

192508-36-4

226888-37-5

General procedure for the synthesis of methyl 3-nitro-4-fluorophenylacetate from methanol and 3-nitro-4-fluorophenylacetic acid: 2-(4-fluoro-3-nitrophenyl)acetic acid (28.8 g, 0.14 mol) was mixed with a solution of methanol (30 mL) with concentrated sulfuric acid (10 mL), and the reaction was stirred at 80 °C overnight. Upon completion of the reaction, the mixture was quenched with ice water and extracted with ethyl acetate (EtOAc). The organic layer was washed sequentially with saturated aqueous sodium bicarbonate (NaHCO3) and brine, dried over anhydrous sodium sulfate (Na2SO4), filtered and concentrated to afford methyl 3-nitro-4-fluorophenylacetate (30 g, 97% yield) as a yellow oil.LC-MS (ESI) m/z calculated value C9H8FNO4: 213.04; measured value: 214.26 ( [M+H]+).

References

[1] Patent: WO2018/116107, 2018, A1. Location in patent: Page/Page column 26
[2] Patent: WO2004/89912, 2004, A1. Location in patent: Page 25
[3] Patent: US2003/207926, 2003, A1. Location in patent: Page/Page column 42
[4] Patent: WO2013/131408, 2013, A1. Location in patent: Page/Page column 83

METHYL 2-(4-FLUORO-3-NITROPHENYL)ACETATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL 2-(4-FLUORO-3-NITROPHENYL)ACETATE Suppliers

China 26 India 1 United States 4 Global 31

SynAsst Chemical.

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Allfluoro pharmaceutical co. ltd.

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226888-37-5, METHYL 2-(4-FLUORO-3-NITROPHENYL)ACETATERelated Search:

2-(4-FLUORO-3-NITROPHENYL)ETHANOL (4-FLUORO-3-NITROPHENYL)ACETIC ACID (3-NITROPHENYL)ACETIC ACID METHYL ESTER METHYL 2-(4-FLUORO-3-NITROPHENYL)ACETATE 3-nitro-4-bromobenzoic acid

Methyl (4-fluoro-3-nitrophenyl)acetate

METHYL 2-(4-FLUORO-3-NITROPHENYL)ACETATE

4-fluoro-3-nitrophenylacetic acid methyl ester

Benzeneacetic acid, 4-fluoro-3-nitro-, methyl ester

Methyl 3-nitro-4-fluorophenylacetate

226888-37-5