ChemicalBook > CAS DataBase List > 2-BROMOMETHYL-4-CHLORO-BENZOIC ACID METHYL ESTER

2-BROMOMETHYL-4-CHLORO-BENZOIC ACID METHYL ESTER

Product Name
2-BROMOMETHYL-4-CHLORO-BENZOIC ACID METHYL ESTER
CAS No.
145908-29-8
Chemical Name
2-BROMOMETHYL-4-CHLORO-BENZOIC ACID METHYL ESTER
Synonyms
Methyl 2-(broMoMethyl)-4-chlorobenzoate;2-BROMOMETHYL-4-CHLORO-BENZOIC ACID METHYL ESTER;Benzoic acid, 2-(broMoMethyl)-4-chloro-, Methyl ester
CBNumber
CB92457629
Molecular Formula
C9H8BrClO2
Formula Weight
263.52
MOL File
145908-29-8.mol
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2-BROMOMETHYL-4-CHLORO-BENZOIC ACID METHYL ESTER Property

storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
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Safety

RIDADR 
3261
HazardClass 
8
PackingGroup 
Ⅱ
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H317May cause an allergic skin reaction

H319Causes serious eye irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
M296178
Product name
Methyl2-(bromomethyl)-4-chlorobenzoate
Packaging
250mg
Price
$45
Updated
2021/12/16
AK Scientific
Product number
W3187
Product name
Methyl2-(bromomethyl)-4-chlorobenzoate
Packaging
1g
Price
$58
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB153931
Product name
2-(Bromomethyl)-4-chloro-benzoic acid methyl ester
Packaging
2g
Price
$151
Updated
2021/12/16
Matrix Scientific
Product number
075674
Product name
Methyl 2-bromomethyl-4-chlorobenzoate
Purity
95+%
Packaging
250mg
Price
$297
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB153931
Product name
2-(Bromomethyl)-4-chloro-benzoic acid methyl ester
Packaging
5G
Price
$302
Updated
2021/12/16
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2-BROMOMETHYL-4-CHLORO-BENZOIC ACID METHYL ESTER Chemical Properties,Usage,Production

Synthesis

99585-12-3

145908-29-8

Methyl 4-chloro-2-methylbenzoate (10.86 g, 58.8 mmol, 1.0 eq.) was used as the starting material and dissolved in carbon tetrachloride (100 mL). N-bromosuccinimide (15.7 g, 88.2 mmol, 1.5 eq.) and benzoyl peroxide (0.05 g) were added sequentially. The reaction mixture was heated to reflux overnight. After completion of the reaction, the reaction mixture was filtered and the solids were washed with dichloromethane. The organic filtrates were combined, concentrated and dried to afford the target product methyl 2-bromomethyl-4-chlorobenzoate (7.1 g, 45.8% yield). The structure of the product was confirmed by 1H NMR.

References

[1] Patent: US2005/143348, 2005, A1. Location in patent: Page/Page column 45; 49; 55
[2] Patent: US2005/239838, 2005, A1. Location in patent: Page/Page column 41
[3] Patent: WO2005/54176, 2005, A1. Location in patent: Page/Page column 136
[4] Bioorganic and Medicinal Chemistry Letters, 2008, vol. 18, # 5, p. 1628 - 1631
[5] Patent: US2009/270393, 2009, A1. Location in patent: Page/Page column 43-44

2-BROMOMETHYL-4-CHLORO-BENZOIC ACID METHYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

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2-BROMOMETHYL-4-CHLORO-BENZOIC ACID METHYL ESTER Suppliers

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145908-29-8, 2-BROMOMETHYL-4-CHLORO-BENZOIC ACID METHYL ESTERRelated Search:


  • 2-BROMOMETHYL-4-CHLORO-BENZOIC ACID METHYL ESTER
  • Methyl 2-(broMoMethyl)-4-chlorobenzoate
  • Benzoic acid, 2-(broMoMethyl)-4-chloro-, Methyl ester
  • 145908-29-8