ChemicalBook > CAS DataBase List > 4-AMINO-6-NITRO-QUINALDINE

4-AMINO-6-NITRO-QUINALDINE

Product Name
4-AMINO-6-NITRO-QUINALDINE
CAS No.
99185-71-4
Chemical Name
4-AMINO-6-NITRO-QUINALDINE
Synonyms
4-AMINO-6-NITRO-QUINALDINE;2-METHYL-6-NITROQUINOLIN-4-AMINE;4-amino-2-methyl-6-nitroquinoline;2-Methyl-4-aMino-6-nitroquinoline;4-Quinolinamine, 2-methyl-6-nitro-;2-Methyl-6-nitro-quinolin-4-ylaMine
CBNumber
CB92464500
Molecular Formula
C10H9N3O2
Formula Weight
203.2
MOL File
99185-71-4.mol
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4-AMINO-6-NITRO-QUINALDINE Property

storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
M350768
Product name
2-Methyl-6-nitroquinolin-4-amine
Packaging
50mg
Price
$90
Updated
2021/12/16
AK Scientific
Product number
0197CT
Product name
2-Methyl-6-nitroquinolin-4-amine
Packaging
100mg
Price
$132
Updated
2021/12/16
AK Scientific
Product number
0197CT
Product name
2-Methyl-6-nitroquinolin-4-amine
Packaging
1g
Price
$332
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0383370
Product name
4-QUINOLINAMINE, 2-METHYL-6-NITRO-
Purity
95.00%
Packaging
5MG
Price
$500.49
Updated
2021/12/16
Alichem
Product number
99185714
Product name
2-Methyl-6-nitroquinolin-4-amine
Packaging
1g
Price
$647.35
Updated
2021/12/16
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4-AMINO-6-NITRO-QUINALDINE Chemical Properties,Usage,Production

Synthesis

1528735-22-9

99185-71-4

4-Azido-2-methyl-6-nitroquinoline (CAS:1528735-22-9; 29.9 g, 130 mmol) was used as starting material and suspended in THF (450 mL). Subsequently, triphenylphosphine (41.1 g, 160 mmol) was added to the suspension and the resulting mixture was stirred at room temperature for 20 min. Next, water (45 mL) was added and the reaction solution was concentrated to about 200 mL. The concentrated solution was poured into 2.5 M aqueous HCl (1.5 L) and stirred vigorously until the solid was completely dissolved. The aqueous phase was extracted with ether (250 mL x 3), followed by adjusting the pH of the aqueous phase with 50% NaOH aqueous solution to 9. The resulting bright yellow crystalline solid was collected by filtration, washed with cold water (500 mL), and dried to give 2-methyl-6-nitroquinolin-4-amine (25.2 g, 95% yield) as a bright yellow crystalline solid: melting point >250 °C; TLC Rf 0.37 ( Spreading agent ratio 95:4.5:0.5 CHCl3:MeOH:aqueous solution, MeNH2); 1H-NMR (DMSO-d6) δ 9.22 (d, 1H), 8.25 (dd, 1H), 7.77 (d, 1H), 7.30 (s, br, 2H), 6.55 (s, 1H), 2.45 (s, 3H).

References

[1] Bioorganic and Medicinal Chemistry, 2014, vol. 22, # 1, p. 419 - 434

4-AMINO-6-NITRO-QUINALDINE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-AMINO-6-NITRO-QUINALDINE Suppliers

China 23 India 1 United States 2 Global 26
Shanghai Sphchem Co., Ltd.
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021-56491756 13512199871
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China
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Changzhou Renaissance Chem Co. Ltd
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86-519-86202821
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China
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Nanjing Chalf-Pharm Technology Co., Ltd.
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025-57018978 18251899859
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Wuhan Greatwall chemical Co,.LTD
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Changzhou Hopschain Chemical Co.,Ltd.
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Shanghai Chaolan Chemical Technology Center
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Amadis Chemical Company Limited
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Amatek Scientific Co. Ltd.
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Aikon International Limited
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Zhengzhou Ruke Biological Co., Ltd.
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99185-71-4, 4-AMINO-6-NITRO-QUINALDINERelated Search:

4-AMINO-6-NITRO-QUINALDINE METHYL 4-(N-BOC PIPERAZINE)-6-NITRO-QUINOLINE-2-CARBOXYLATE 4,6-DIAMINO-2-METHYL-QUINOLINE

  • 2-METHYL-6-NITROQUINOLIN-4-AMINE
  • 4-AMINO-6-NITRO-QUINALDINE
  • 4-Quinolinamine, 2-methyl-6-nitro-
  • 2-Methyl-4-aMino-6-nitroquinoline
  • 2-Methyl-6-nitro-quinolin-4-ylaMine
  • 4-amino-2-methyl-6-nitroquinoline
  • 99185-71-4