TERT-BUTYL 3-(BROMOMETHYL)PHENYLCARBAMATE

Product Name: TERT-BUTYL 3-(BROMOMETHYL)PHENYLCARBAMATE
CAS No.: 118684-32-5
Chemical Name: TERT-BUTYL 3-(BROMOMETHYL)PHENYLCARBAMATE
Synonyms: N-Boc-3-(bromomethyl)aniline;3-(Bromomethyl)aniline, N-BOC protected;TERT-BUTYL 3-(BROMOMETHYL)PHENYLCARBAMATE;Ter-Butyl-3-(bromomethyl)phenyl carbamate;3-[(tert-Butoxycarbonyl)amino]benzyl bromide;tert-butyl N-[3-(bromomethyl)phenyl]carbamate;3-(bromethyl)phenylaminomacetic acidtertbutyl ester;2-Methyl-2-propanyl [3-(bromomethyl)phenyl]carbamate;1,1-Dimethylethyl N-[3-(bromomethyl)phenyl]carbamate;Carbamic acid, N-[3-(bromomethyl)phenyl]-,1,1-dimethylethyl ...
CBNumber: CB92467561
Molecular Formula: C12H16BrNO2
Formula Weight: 286.16
MOL File: 118684-32-5.mol

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TERT-BUTYL 3-(BROMOMETHYL)PHENYLCARBAMATE Property

Melting point:: 122 °C
Boiling point:: 309.0±25.0 °C(Predicted)
Density: 1.376±0.06 g/cm3(Predicted)
storage temp.: Inert atmosphere,Store in freezer, under -20°C
form: solid
pka: 13.58±0.70(Predicted)
color: White to off white

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Safety

HS Code: 2921490090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

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N-Bromosuccinimide Price

Apolloscientific

Product number: OR55617
Product name: 3-(Bromomethyl)aniline, N-BOC protected
Packaging: 1g
Price: $98
Updated: 2021/12/16

AK Scientific

Product number: Z7939
Product name: tert-Butyl3-(bromomethyl)phenylcarbamate
Packaging: 1g
Price: $132
Updated: 2021/12/16

Apolloscientific

Product number: OR55617
Product name: 3-(Bromomethyl)aniline, N-BOC protected
Packaging: 5g
Price: $345
Updated: 2021/12/16

Crysdot

Product number: CD12175140
Product name: tert-Butyl(3-(bromomethyl)phenyl)carbamate
Purity: 95%
Packaging: 5g
Price: $239
Updated: 2021/12/16

Alichem

Product number: 118684325
Product name: tert-Butyl(3-(bromomethyl)phenyl)carbamate
Packaging: 5g
Price: $331.24
Updated: 2021/12/16

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TERT-BUTYL 3-(BROMOMETHYL)PHENYLCARBAMATE Chemical Properties,Usage,Production

Synthesis

118684-31-4

118684-32-5

At -20 °C, tert-butyl (3-(hydroxymethyl)phenylcarbamate (120 g, 484 mmol) was dissolved in tetrahydrofuran (50 mL) and triphenylphosphine (254 g, 967 mmol) and N-bromosuccinimide (103 g, 580 mmol) were added sequentially. The reaction mixture was stirred at this temperature for 3 hours. After completion of the reaction, the solvent was removed by distillation under reduced pressure. The crude product was purified by silica gel column chromatography with the eluent being petroleum ether: ethyl acetate (100:1, v/v) to afford tert-butyl 3-(bromomethyl)phenylcarbamate (125 g, 437 mmol, 90% yield) as a white solid. It was analyzed by liquid chromatography-mass spectrometry (LCMS, Method 1, Table 7) with a retention time (R t) of 2.10 min; mass spectrometry (MS) showed m/z = 230,232 [M-t-Bu + H+].

References

[1] Patent: WO2017/210471, 2017, A1. Location in patent: Paragraph 001137; 001138
[2] Bioorganic and Medicinal Chemistry, 2000, vol. 8, # 1, p. 73 - 93
[3] ChemBioChem, 2010, vol. 11, # 18, p. 2517 - 2520
[4] Patent: US2008/21032, 2008, A1. Location in patent: Page/Page column 56
[5] Journal of Medicinal Chemistry, 1989, vol. 32, # 4, p. 811 - 826

TERT-BUTYL 3-(BROMOMETHYL)PHENYLCARBAMATE Preparation Products And Raw materials

Raw materials

Preparation Products

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TERT-BUTYL 3-(BROMOMETHYL)PHENYLCARBAMATE Suppliers

China 71 India 4 United States 3 Global 78

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View Lastest Price from TERT-BUTYL 3-(BROMOMETHYL)PHENYLCARBAMATE manufacturers

Shanghai Rlavie Technology Co ltd

Product: N-Boc-3-(bromomethyl)aniline 118684-32-5
Price: US $0.00-0.00/KG
Min. Order: 1g
Purity: 98%min
Supply Ability: 2Tons/month
Release date: 2021-11-21

118684-32-5, TERT-BUTYL 3-(BROMOMETHYL)PHENYLCARBAMATERelated Search:

N-Boc-3-(bromomethyl)aniline

Ter-Butyl-3-(bromomethyl)phenyl carbamate

TERT-BUTYL 3-(BROMOMETHYL)PHENYLCARBAMATE

Carbamic acid, N-[3-(bromomethyl)phenyl]-, 1,1-dimethylethyl ester

2-Methyl-2-propanyl [3-(bromomethyl)phenyl]carbamate

Carbamic acid, N-[3-(bromomethyl)phenyl]-,1,1-dimethylethyl ...

3-[(tert-Butoxycarbonyl)amino]benzyl bromide

1,1-Dimethylethyl N-[3-(bromomethyl)phenyl]carbamate

tert-butyl N-[3-(bromomethyl)phenyl]carbamate

3-(Bromomethyl)aniline, N-BOC protected

3-(bromethyl)phenylaminomacetic acidtertbutyl ester

118684-32-5