ethyl 4-oxocyclohexaneacetate
- Product Name
- ethyl 4-oxocyclohexaneacetate
- CAS No.
- 58012-34-3
- Chemical Name
- ethyl 4-oxocyclohexaneacetate
- Synonyms
- ethyl 4-oxocyclohexaneacetate;ethyl 2-(4-oxocyclohexyl)acetate;ethyl 4-oxocyclohexaneacetate-26;Ethyl (4-oxocyclohex-1-yl)acetate;Ethyl (4-oxocyclohex-1-yl)acetate 95%;4-Oxocyclohexaneacetic acid ethyl ester;Ethyl 2-(4-Oxocyclohexyl)Acetate(WXC03040);(4-Oxo-cyclohexyl)-acetic acid ethyl ester;2-(4-Oxocyclohexyl)acetic Acid Ethyl Ester;4-oxo-Cyclohexaneacetic acid ethyl ester (6CI 9CI ACI)
- CBNumber
- CB92470848
- Molecular Formula
- C10H16O3
- Formula Weight
- 184.23
- MOL File
- 58012-34-3.mol
ethyl 4-oxocyclohexaneacetate Property
- Boiling point:
- 266℃
- Density
- 1.040
- refractive index
- 1.45
- Flash point:
- 112℃
- storage temp.
- Inert atmosphere,Store in freezer, under -20°C
- form
- clear liquid
- color
- Colorless to Light yellow to Light orange
- InChI
- InChI=1S/C10H16O3/c1-2-13-10(12)7-8-3-5-9(11)6-4-8/h8H,2-7H2,1H3
- InChIKey
- XHNJFNLTFMAPQB-UHFFFAOYSA-N
- SMILES
- C1(CC(OCC)=O)CCC(=O)CC1
Safety
- HS Code
- 2918300090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H304May be fatal if swallowed and enters airways
- Precautionary statements
-
P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P331Do NOT induce vomiting.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- E1375
- Product name
- Ethyl 2-(4-Oxocyclohexyl)acetate
- Packaging
- 1G
- Price
- $62
- Updated
- 2026/03/19
- Product number
- E1375
- Product name
- Ethyl 2-(4-Oxocyclohexyl)acetate
- Packaging
- 5G
- Price
- $244
- Updated
- 2026/03/19
- Product number
- E925378
- Product name
- Ethyl 2-(4-Oxocyclohexyl)acetate
- Packaging
- 250mg
- Price
- $55
- Updated
- 2021/12/16
- Product number
- E925378
- Product name
- Ethyl 2-(4-Oxocyclohexyl)acetate
- Packaging
- 1g
- Price
- $75
- Updated
- 2021/12/16
- Product number
- OR40563
- Product name
- Ethyl(4-oxocyclohex-1-yl)acetate
- Purity
- 95%
- Packaging
- 1g
- Price
- $63
- Updated
- 2021/12/16
ethyl 4-oxocyclohexaneacetate Chemical Properties,Usage,Production
Synthesis
62141-26-8
58012-34-3
To acetone (720 mL) was added 10 g (43.8 mmol, 1 eq.) of ethyl (1,4-dioxaspiro[4.5]dec-8-yl)acetate followed by 1 N hydrochloric acid (180 mL). The reaction mixture was heated to reflux for 2 hours. After completion of the reaction, it was cooled to room temperature, diluted with ethyl acetate (100 mL) and washed with deionized water (100 mL). The aqueous layer was back-extracted twice with ethyl acetate (100 mL), all the organic layers were combined, dried with anhydrous magnesium sulfate, filtered, and concentrated under reduced pressure to give 7.57 g (94% yield) of ethyl 4-oxocyclohexaneacetate as a clear oil. The product was characterized by 1H-NMR (CDCl3): δ 4.16 (q, 2H), 2.40 (m, 4H), 2.32 (m, 2H), 2.28 (m, 1H), 2.10 (m, 2H), 1.49 (m, 2H), 1.28 (t, 3H); TLC Rf = 0.32 (unfolding reagent ratio of ethyl acetate/hexanes 3:7).
References
[1] Patent: WO2005/10008, 2005, A1. Location in patent: Page/Page column 105-106
[2] Angewandte Chemie - International Edition, 2010, vol. 49, # 33, p. 5693 - 5697
[3] Patent: WO2006/44524, 2006, A1. Location in patent: Page/Page column 46-47
[4] Angewandte Chemie - International Edition, 2007, vol. 46, # 33, p. 6278 - 6283
[5] Tetrahedron, 1995, vol. 51, # 37, p. 10259 - 10280
ethyl 4-oxocyclohexaneacetate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from ethyl 4-oxocyclohexaneacetate manufacturers
- Product
- 4-Oxocyclohexaneacetic acid ethyl ester 58012-34-3
- Price
- US $3.00-9.00/KG
- Min. Order
- 0.1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2025-06-24
- Product
- ethyl 4-oxocyclohexaneacetate 58012-34-3
- Price
- US $0.00-0.00/KG
- Min. Order
- 1g
- Purity
- 99%
- Supply Ability
- 200KG/MONTH
- Release date
- 2020-11-23
- Product
- Ethyl 2-(4-oxocyclohexyl)acetate 58012-34-3
- Price
- US $5.50/KG
- Min. Order
- 1KG
- Purity
- 98%min
- Supply Ability
- 1kg,10kg,100kg
- Release date
- 2020-01-09