Chloro[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]gold(I)
Reaction- Product Name
- Chloro[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]gold(I)
- CAS No.
- 852445-81-9
- Chemical Name
- Chloro[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]gold(I)
- Synonyms
- IMesAuCl;oro[1,3-bis(2,4,6-trimethyL;Chloro[1,3-bis(mesityl)imidazole-2-ylidene]gold(I);Chloro(1,3-dimesityl-1H-imidazol-2(3H)-ylidene)aurate(I);1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]-chlorogold;Chemical Name：Chloro[1,3-bis(mesityl)imidazole-2-ylidene]gold(I);1,3-bis(2,4,6-trimethylphenyl)2H-imidazol-2-ylidene]gold(I)Chloro;CHLORO[1,3-BIS(2,4,6-TRIMETHYLPHENYL)2H-IMIDAZOL-2-YLIDENE]GOLD(I),98%;Chloro[1,3-bis(2,4,6-trimethylphenyl)2H-imidazol-2-ylidene]gold(I), 98%
- CBNumber
- CB92487411
- Molecular Formula
- C21H24AuClN2
- Formula Weight
- 536.84821
- MOL File
- 852445-81-9.mol
Chloro[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]gold(I) Property
- Melting point:
- >300 °C
- storage temp.
- 2-8°C
- form
- Powder
- color
- white
- Sensitive
- air sensitive
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H228Flammable solid
H315Causes skin irritation
H319Causes serious eye irritation
H413May cause long lasting harmful effects to aquatic life
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P240Ground/bond container and receiving equipment.
P241Use explosion-proof electrical/ventilating/lighting/…/equipment.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
P370+P378In case of fire: Use … for extinction.
N-Bromosuccinimide Price
- Product number
- 696501
- Product name
- Chloro[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]gold(I)
- Purity
- 95%
- Packaging
- 100MG
- Price
- $30.4
- Updated
- 2024/03/01
- Product number
- 696501
- Product name
- Chloro[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]gold(I)
- Purity
- 95%
- Packaging
- 500MG
- Price
- $156.6
- Updated
- 2024/03/01
- Product number
- 79-1200
- Product name
- Chloro[1,3-bis(2,4,6-trimethylphenyl)2H-imidazol-2-ylidene]gold(I), 98%
- Packaging
- 100mg
- Price
- $64
- Updated
- 2024/03/01
- Product number
- 79-1200
- Product name
- Chloro[1,3-bis(2,4,6-trimethylphenyl)2H-imidazol-2-ylidene]gold(I), 98%
- Packaging
- 500mg
- Price
- $250
- Updated
- 2024/03/01
- Product number
- 3213AC
- Product name
- Chloro(1,3-dimesityl-1H-imidazol-2(3H)-ylidene)aurate(I)
- Packaging
- 500mg
- Price
- $274
- Updated
- 2021/12/16
Chloro[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]gold(I) Chemical Properties,Usage,Production
Reaction
- Catalyst for the rearrangement of alkynyl sulfoxides to benzothiepinones
- Catalyst for the rearrangement of homopropargylic ethers to α,β-unsaturated carbonyl compounds
- Catalyst for oxidative cyclopropanation of N-Allylynamides to 3-aza-bicyclo[3.1.0]-hexan-2-one derivatives
- Catalyst for oxidative rearrangement of homopropargylic ethers to cyclobutanones
Description
Chloro[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]gold(I), also known as [(IMes)AuCl], is an useful organometallic catalyst. Organometallics are useful reagents, catalysts, and precursor materials with applications in thin film deposition, industrial chemistry, pharmaceuticals, LED manufacturing, and others.
Chemical Properties
White powder
Uses
Gold Catalysts — 21st Century ′Gold Rush′
Preparation
Ag2O (0.5 mmol) was added to the CH2Cl2 solution of 1,3-bis(mesityl)imidazolium chloride (1mmol). After stirring at room temperature for 3 hours, the suspension becomes clear. Then drop 1mmol of Me2SAuCl solution into CH2Cl2 and stir for 4 hours. After the mixture is filtered through Celite, the solvent is evaporated. Hexane is added to the remaining mixture and filtered to obtain Chloro[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]gold(I).