ChemicalBook > CAS DataBase List > 3-(4-chloro-3-fluorophenyl)propanoic acid

3-(4-chloro-3-fluorophenyl)propanoic acid

Product Name
3-(4-chloro-3-fluorophenyl)propanoic acid
CAS No.
881189-65-7
Chemical Name
3-(4-chloro-3-fluorophenyl)propanoic acid
Synonyms
3-(4-Chloro-3-fluorophenyl);4-chloro-3-fluoroBenzenepropanoic acid;Benzenepropanoic acid, 4-chloro-3-fluoro-;3-(4-chloro-3-fluorophenyl)propanoic acid;3-(4-Chloro-3-fluorophenyl)propionicacid,96%
CBNumber
CB92500321
Molecular Formula
C9H8ClFO2
Formula Weight
202.61
MOL File
881189-65-7.mol
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3-(4-chloro-3-fluorophenyl)propanoic acid Property

Melting point:
80-84℃
storage temp. 
Store at room temperature
Appearance
White to off-white Solid
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Safety

HS Code 
2916399090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TRC
Product number
C584715
Product name
3-(4-Chloro-3-fluorophenyl)propionicacid
Packaging
1g
Price
$115
Updated
2021/12/16
AK Scientific
Product number
W9037
Product name
3-(4-Chloro-3-fluorophenyl)propionicacid
Packaging
5g
Price
$237
Updated
2021/12/16
Apolloscientific
Product number
PC302035
Product name
3-(4-Chloro-3-fluorophenyl)propionicacid
Purity
97%
Packaging
5g
Price
$156
Updated
2021/12/16
SynQuest Laboratories
Product number
2621-7-38
Product name
3-(4-Chloro-3-fluorophenyl)propionic acid
Packaging
1g
Price
$112
Updated
2021/12/16
Apolloscientific
Product number
PC302035
Product name
3-(4-Chloro-3-fluorophenyl)propionicacid
Purity
97%
Packaging
1g
Price
$38
Updated
2021/12/16
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3-(4-chloro-3-fluorophenyl)propanoic acid Chemical Properties,Usage,Production

Synthesis

202982-66-9

881189-65-7

General procedure for the synthesis of 3-(4-chloro-3-fluorophenyl)propionic acid from 4-chloro-3-fluorocinnamic acid: 3-(4-chloro-3-fluorophenyl)acrylic acid (6.000 g, 29.91 mmol, 1.0 eq.), ZnBr2 (1.346 g, 5.98 mmol, 0.2 eq.), and 10% Pd/C (600 mg, 10 mass%) were The mixture was placed under nitrogen atmosphere followed by addition of methanol (500 ml). The resulting black suspension was evacuated and then charged with hydrogen (1 atm) and this operation was repeated three times. The reaction mixture was stirred vigorously at room temperature for 14 hours. Upon completion of the reaction, it was filtered through a diatomaceous earth pad and the filtrate was concentrated to dryness under reduced pressure and subsequently dried under high vacuum to afford 3-(4-chloro-3-fluorophenyl)propionic acid as a white solid (6.010 g, 99% yield).LC-MS analysis: retention time tR = 0.91 min; [M + H]+: no ionization peak was observed.

References

[1] Patent: US2011/105514, 2011, A1. Location in patent: Page/Page column 18
[2] Patent: WO2009/156951, 2009, A2. Location in patent: Page/Page column 37-38

3-(4-chloro-3-fluorophenyl)propanoic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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3-(4-chloro-3-fluorophenyl)propanoic acid Suppliers

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881189-65-7, 3-(4-chloro-3-fluorophenyl)propanoic acidRelated Search:


  • 3-(4-chloro-3-fluorophenyl)propanoic acid
  • Benzenepropanoic acid, 4-chloro-3-fluoro-
  • 4-chloro-3-fluoroBenzenepropanoic acid
  • 3-(4-Chloro-3-fluorophenyl)
  • 3-(4-Chloro-3-fluorophenyl)propionicacid,96%
  • 881189-65-7