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ChemicalBook > CAS DataBase List > Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium (II)chloride [RuCl(p-cymene)((R)-H8-binap)]Cl

Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium (II)chloride [RuCl(p-cymene)((R)-H8-binap)]Cl

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Product Name
Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium (II)chloride [RuCl(p-cymene)((R)-H8-binap)]Cl
CAS No.
944451-26-7
Chemical Name
Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium (II)chloride [RuCl(p-cymene)((R)-H8-binap)]Cl
Synonyms
(R)-RuCL;[p-cymene)(H8-BINAP)]CL;RUCL(P-CYMENE)((R)-H8-BINAP)]CL;(R)-RuCl[p-cymene)(H8-BINAP)]Cl (R)-RuCl[p-cymene)(H8-BINAP)]Cl;Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)r;[(R)-(+)-2,2'-Bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) dichloride;Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride;Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium (II)chloride [RuCl(p-cymene)((R)-H8-binap)]Cl;Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride, [RuCl(p-cymene)((R)-H8-binap)]Cl
CBNumber
CB92512489
Molecular Formula
C54H52Cl2P2Ru
Formula Weight
934.93
MOL File
944451-26-7.mol
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Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium (II)chloride [RuCl(p-cymene)((R)-H8-binap)]Cl Property

Melting point:
>100°C
storage temp. 
2-8°C
form 
Powder
color 
pale yellow
Sensitive 
air sensitive
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Safety

WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
692514
Product name
(R)-RuCl[p-cymene)(H8-BINAP)]Cl
Packaging
50mg
Price
$94
Updated
2023/01/07
Sigma-Aldrich
Product number
692514
Product name
(R)-RuCl[p-cymene)(H8-BINAP)]Cl
Packaging
100mg
Price
$136
Updated
2023/01/07
Strem Chemicals
Product number
44-0094
Product name
Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-H8-binap)]Cl
Packaging
50mg
Price
$69
Updated
2024/03/01
Strem Chemicals
Product number
44-0094
Product name
Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-H8-binap)]Cl
Packaging
250mg
Price
$276
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
ING0013123
Product name
CHLORO-[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-5,5',6,6',7,7',8,8'-OCTAHYDRO-1,1'-BINAPHTHYL](PARA-CYMENE)RUTHENIUM-(II)-CHLORIDE
Purity
95.00%
Packaging
5MG
Price
$504.89
Updated
2021/12/16
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Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium (II)chloride [RuCl(p-cymene)((R)-H8-binap)]Cl Chemical Properties,Usage,Production

Reaction

  1. Biaryl bisphosphine ligand. The H8-BINAP ligand, as the ruthenium complex, catalyzes hydrogenation of unsaturated carboxylic acids to a higher ee than does BINAP.
  2. The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug Ibuprofen.

Uses

Takasago Ligands and Complexes for Asymmetric Reactions

Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium (II)chloride [RuCl(p-cymene)((R)-H8-binap)]Cl Preparation Products And Raw materials

Raw materials

Preparation Products

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Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium (II)chloride [RuCl(p-cymene)((R)-H8-binap)]Cl Suppliers

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944451-26-7, Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium (II)chloride [RuCl(p-cymene)((R)-H8-binap)]ClRelated Search:

Chloro(η2-P,C-tris(2,4-di-tert-butylphenyl)phosphite)(tricyclohexylphosphine)palladiuM(II), SaMCat Chloro[(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-2-(diphenylphosphino)-1,2-diphenylethanamine]ruthenium(II) tetrafluoroborate Chloro[(S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1S,2S)-2-(diphenylphosphino)-1,2-diphenylethanamine]ruthenium(II) tetrakis(pentafluorophenyl)borate, min. 97% Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-H8-binap)]Cl Chloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-xylbinap)]Cl CHLORO[(1,2,3-Η)-3-PHENYL-2-PROPENYL][1,3-BIS(2,6-DI-I-PROPYLPHENYL)-4,5-DIHYDROIMIDAZOL-2-YLIDENE]PALLADIUM(II) Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-xylbinap}]Cl Chloro[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride Chloro[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II)chloride[RuCl (p-cymene)((S)-segphos)]Cl　

  • (R)-RuCl[p-cymene)(H8-BINAP)]Cl (R)-RuCl[p-cymene)(H8-BINAP)]Cl
  • Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium (II)chloride [RuCl(p-cymene)((R)-H8-binap)]Cl
  • Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)r
  • [(R)-(+)-2,2'-Bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) dichloride
  • (R)-RuCL
  • [p-cymene)(H8-BINAP)]CL
  • RUCL(P-CYMENE)((R)-H8-BINAP)]CL
  • Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride
  • Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride, [RuCl(p-cymene)((R)-H8-binap)]Cl
  • 944451-26-7
  • C54H54Cl2P2Ru
  • Ru