methyl 2-ethynylbenzoate

Product Name: methyl 2-ethynylbenzoate
CAS No.: 33577-99-0
Chemical Name: methyl 2-ethynylbenzoate
Synonyms: NSC 649436;Methyl o-ethynylbenzoate;methyl 2-ethynylbenzoate;Methyl 2-ethynylbenzoate 95%;o-Methoxycarbonylphenylacetylene;OrthoMethoxycarbonylphenylacetylene;2-Ethynyl-benzoic acid Methyl ester;Methyl 2-ethynylbenzoate - [M53793];Benzoic acid, 2-ethynyl-, methyl ester
CBNumber: CB92514100
Molecular Formula: C10H8O2
Formula Weight: 160.17
MOL File: 33577-99-0.mol

More

Less

methyl 2-ethynylbenzoate Property

Boiling point:: 80-85 °C(Press: 1 Torr)
Density: 1.11±0.1 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
Appearance: Colorless to light yellow Solid-liquid mixture

More

Less

Safety

HS Code: 2916399090

More

Less

Hazard and Precautionary Statements (GHS)

More

Less

N-Bromosuccinimide Price

TRC

Product number: M339658
Product name: Methyl2-Ethynylbenzoate
Packaging: 50mg
Price: $45
Updated: 2021/12/16

TRC

Product number: M339658
Product name: Methyl2-Ethynylbenzoate
Packaging: 100mg
Price: $60
Updated: 2021/12/16

Synthonix

Product number: M53793
Product name: Methyl2-ethynylbenzoate
Purity: 96%
Packaging: 100mg
Price: $50
Updated: 2021/12/16

AK Scientific

Product number: J97449
Product name: Methyl2-ethynylbenzoate
Packaging: 250mg
Price: $54
Updated: 2021/12/16

Synthonix

Product number: M53793
Product name: Methyl2-ethynylbenzoate
Purity: 96%
Packaging: 250mg
Price: $70
Updated: 2021/12/16

More

Less

methyl 2-ethynylbenzoate Chemical Properties,Usage,Production

Synthesis

107793-07-7

33577-99-0

General procedure for the synthesis of methyl 2-[(trimethylsilyl)ethynyl]benzoate from methyl 2-alkynylbenzoate: 1. Preparation of reaction system: Cesium fluoride (1.41 g, 9.30 mmol) was added to an acetonitrile/water (20 mL/5 mL) solution of methyl 2-[(trimethylsilyl)ethynyl]benzoate (540 mg, 2.32 mmol). 2. Reaction conditions: the reaction mixture was stirred at room temperature for 4 hours. 3. Post-treatment: After completion of the reaction, the reaction mixture was concentrated and the residue was partitioned with ethyl acetate (100 mL) and 0.2 N hydrochloric acid (30 mL). The aqueous layer was extracted with ethyl acetate (100 mL), the combined organic layers were washed with brine, dried over anhydrous magnesium sulfate, filtered and concentrated. 4. Purification: The residue was purified by column chromatography using 0 to 5% ethyl acetate/hexane as eluent to afford methyl 2-alkynylbenzoate (358 mg, 96% yield). 5. Characterization: GC/MS analysis showed a molecular ion peak m/z of 160.

References

[1] Tetrahedron Letters, 2003, vol. 44, # 46, p. 8525 - 8527
[2] Tetrahedron, 2007, vol. 63, # 40, p. 9979 - 9990
[3] Patent: WO2007/140174, 2007, A2. Location in patent: Page/Page column 32
[4] Organic Letters, 2010, vol. 12, # 16, p. 3651 - 3653
[5] Tetrahedron Letters, 2010, vol. 51, # 15, p. 2007 - 2009

methyl 2-ethynylbenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

methyl 2-ethynylbenzoate Suppliers

China 51 India 4 United Kingdom 2 United States 7 Global 64

Jia Xing Isenchem Co.,Ltd

Tel: 0573-85285100 18627885956
Fax: 0573-85285100
Email: isenchem@163.com
Country: China
ProdList: 9309
Advantage: 66

Tetranov Biopharm

Tel: 13526569071
Email: sales@leadmedpharm.com
Country: China
ProdList: 7892
Advantage: 64

SynAsst Chemical.

Tel: 021-60343070
Fax: 021-35122006
Country: China
ProdList: 12740
Advantage: 55

Shanghai Run-Biotech Co., Ltd.

Tel: 021-57171705 13817537615
Fax: QQ3095748324
Email: sales@run-biotech.com
Country: China
ProdList: 2311
Advantage: 58

Amatek Scientific Co. Ltd.

Tel: 0512-56316828 4008675858
Fax: +86-512-56316826
Email: sales@amateksci.com
Country: China
ProdList: 9860
Advantage: 55

HBCChem, Inc.

Tel: +1-510-219-6317
Fax: +1-650-486-1361
Email: sales@hbcchem.com
Country: United States
ProdList: 10648
Advantage: 60

Bide Pharmatech Ltd.

Tel: 400-400-164-7117 18317119277
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 40000
Advantage: 60

Bellen Chemistry Co., Ltd.

Tel: 010-60400365-8001 15910885229
Fax: 010-60400361
Email: service@bellenchem.com
Country: China
ProdList: 4514
Advantage: 60

Shanghai YuanYe Biotechnology Co., Ltd.

Tel: 021-61312847; 18021002903
Fax: QQ:3008007432
Email: 3008007409@qq.com
Country: China
ProdList: 71826
Advantage: 60

Shanghai SuperLan Chemcial Technique Centre

Tel: 0-2022843681 15618226720
Fax: +86-21-51601218
Email: chaolaichem@foxmail.com
Country: China
ProdList: 10408
Advantage: 58

More

Less

View Lastest Price from methyl 2-ethynylbenzoate manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: methyl 2-ethynylbenzoate 33577-99-0
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20T
Release date: 2024-08-14

Career Henan Chemical Co

Product: methyl 2-ethynylbenzoate 33577-99-0
Price: US $5.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 100KG
Release date: 2020-01-12

33577-99-0, methyl 2-ethynylbenzoateRelated Search:

methyl 2-ethynylbenzoate

2-Ethynyl-benzoic acid Methyl ester

OrthoMethoxycarbonylphenylacetylene

NSC 649436

o-Methoxycarbonylphenylacetylene

Methyl o-ethynylbenzoate

Methyl 2-ethynylbenzoate 95%

Benzoic acid, 2-ethynyl-, methyl ester

Methyl 2-ethynylbenzoate - [M53793]

33577-99-0

33577-90-0