Reaction
ChemicalBook > CAS DataBase List > (11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine

(11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine

Reaction
Product Name
(11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
CAS No.
736158-72-8
Chemical Name
(11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
Synonyms
(11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d;(11bR)-N,N-bis[(1R)-1-(2-methoxyphenyl)ethyl]-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine;(11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine;(11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine;(11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1'',2''-f][1,3,2]dioxaphosphepin-4-amine;Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N,N-bis[(1R)-1-(2-methoxyphenyl)ethyl]-, (11bR)-;(11BR)-N,N-BIS[(R)-(-)-1-(2-METHOXYPHENYL)ETHYL]DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE,MIN.98%;(11bR)-N,N-Bis[(R)-(-)-1-(2-Methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-aMine, Min. 98%
CBNumber
CB92527553
Molecular Formula
C38H34NO4P
Formula Weight
599.65
MOL File
736158-72-8.mol
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(11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine Property

Boiling point:
760.0±70.0 °C(Predicted)
pka
-0.37±0.20(Predicted)
form 
Powder
color 
white
Sensitive 
moisture sensitive
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Strem Chemicals
Product number
15-0522
Product name
(11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, min. 98%
Packaging
100mg
Price
$162
Updated
2024/03/01
Strem Chemicals
Product number
15-0522
Product name
(11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, min. 98%
Packaging
500mg
Price
$588
Updated
2024/03/01
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(11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine Chemical Properties,Usage,Production

Reaction

  1. Ligand for the copper catalyzed, highly regioselective substitution reactions of a wide variety of aromatic and aliphatic substituted allylic halides to form branched chiral products from diverse Grignard and dialkyl zinc reagents.
  2. Ligand for the iridium catalyzed, highly regioselective, substitution reactions of a wide variety of aromatic and aliphatic substituted allylic carboxylates to form branched chiral products from amines, stabilized carbanions, and aryl zinc reagents.
  3. Ligand for the iridium catalyzed, highly regioselective, substitution reactions of a wide variety of aromatic and aliphatic substituted allylic carboxylates to form branched chiral products from alcohol.
  4. Ligand for the iridium catalyzed, highly regioselective, substitution reactions of a wide variety of aromatic and aliphatic substituted allylic carboxylates to form branched chiral products from thiolate.
  5. Ligand for the copper catalyzed, highly regioselective substitution reactions of a wide variety of aromatic and aliphatic substituted allylic halides to form branched chiral products from diverse organolithium compounds.

(11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine Preparation Products And Raw materials

Raw materials

Preparation Products

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(11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine Suppliers

China 15 United States 2 Global 17
Aladdin Scientific
Tel
+1-+1(833)-552-7181
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sales@aladdinsci.com
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United States
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52925
Advantage
58
Strem Chemicals, Inc.
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Email
info@strem.com
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United States
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736158-72-8, (11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amineRelated Search:


  • (11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
  • (11bR)-N,N-Bis[(R)-(-)-1-(2-Methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-aMine, Min. 98%
  • (11BR)-N,N-BIS[(R)-(-)-1-(2-METHOXYPHENYL)ETHYL]DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE,MIN.98%
  • (11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d
  • Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N,N-bis[(1R)-1-(2-methoxyphenyl)ethyl]-, (11bR)-
  • (11bR)-N,N-bis[(1R)-1-(2-methoxyphenyl)ethyl]-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
  • (11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1'',2''-f][1,3,2]dioxaphosphepin-4-amine
  • (11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
  • 736158-72-8
  • C38H34NO4P
  • Chiral Phosphine
  • CPN