(chlorodifluoroMethyl)triMethylsilane

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(chlorodifluoroMethyl)triMethylsilane

Product Name: (chlorodifluoroMethyl)triMethylsilane
CAS No.: 115262-00-5
Chemical Name: (chlorodifluoroMethyl)triMethylsilane
Synonyms: Chlordifluormethyltrimethylsilan;(chlorodifluoroMethyl)triMethylsilane;Silane, (chlorodifluoromethyl)trimethyl-
CBNumber: CB92644986
Molecular Formula: C4H9ClF2Si
Formula Weight: 158.65
MOL File: 115262-00-5.mol

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(chlorodifluoroMethyl)triMethylsilane Property

Boiling point:: 90.0±40.0 °C(Predicted)
Density: 1.039±0.06 g/cm3(Predicted)
form: liquid
color: colorless

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Safety

Risk Statements: 11
Safety Statements: 24/25
TSCA: No
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word: Danger
Hazard statements: H225Highly Flammable liquid and vapour
Precautionary statements: P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

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N-Bromosuccinimide Price

Frontier Specialty Chemicals

Product number: JK1578319
Product name: (Chlorodifluoromethyl)trimethylsilane
Purity: 98%
Packaging: 250mg
Price: $75
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FC45667
Product name: (Chlorodifluoromethyl)trimethylsilane
Packaging: 50mg
Price: $80
Updated: 2021/12/16

ChemSupplyAustralia

Product number: 300936
Product name: (Chlorodifluoromethyl)trimethylsilane, 97%
Packaging: 1g
Price: $104.5
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FC45667
Product name: (Chlorodifluoromethyl)trimethylsilane
Packaging: 100mg
Price: $125
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FC45667
Product name: (Chlorodifluoromethyl)trimethylsilane
Packaging: 250mg
Price: $200
Updated: 2021/12/16

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(chlorodifluoroMethyl)triMethylsilane Chemical Properties,Usage,Production

Uses

(Chlorodifluoromethyl)trimethylsilane, is one of the partially fluorinated compounds, which are often used for diverse applications in materials science, agrochemistry, and the pharmaceutical industry.

Uses

(chlorodifluoroMethyl)triMethylsilane，also known as Hu reagent，it can be used to generate difluorocarbene at higher temperatures catalyzed by chloride ion.

Reactions

(1) Difluoromethylenation of alkenes.

Refs. 1) Angew. Chem. Int. Ed. 2011, 50, 7153 –7157; 2) Chem. Commun. 2011, 47, 2411–2413.
(2) Difluoromethylenation of alkynes.

Refs. 1) Angew. Chem. Int. Ed. 2011, 50, 7153 –7157; 2) Chem. Commun. 2011, 47, 2411–2413.
(3) Difluoromethylenation of TMSCN.

Ref. J. Org. Chem. 2012, 77, 5850?5855.
(4) Difluoromethylenation of benzyl and alkylzinc halides.

Ref. Org. Lett. 2013, 15, 917 – 919.
(5) Fluorination aminocarbonylation of aldehydes

Ref. Angew. Chem. Int. Ed. 2022, e202115467

References

[1]Angewandte Chemie International Edition.DOI :10.1002/anie.202283811
[2]The Journal of Organic Chemistry.DOI :10.1021/acs.orglett.2c02899

(chlorodifluoroMethyl)triMethylsilane Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from (chlorodifluoroMethyl)triMethylsilane manufacturers

Zibo Hangyu Biotechnology Development Co., Ltd

Product: (chlorodifluoroMethyl)triMethylsilane 115262-00-5
Price: US $0.10-0.10/kg
Min. Order: 0.004999999888241291kg
Purity: 99.99%
Supply Ability: 20 tons
Release date: 2024-04-15

Henan Aochuang Chemical Co.,Ltd.

Product: (chlorodifluoroMethyl)triMethylsilane 115262-00-5
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-10-09

Career Henan Chemical Co

Product: [Chloro(difluoro)methyl](trimethyl)silane 115262-00-5
Price: US $9.80/KG
Min. Order: 1KG
Purity: ＞98%HPLC
Supply Ability: 20 tons
Release date: 2020-02-06

115262-00-5, (chlorodifluoroMethyl)triMethylsilaneRelated Search:

(chlorodifluoroMethyl)triMethylsilane

Chlordifluormethyltrimethylsilan

Silane, (chlorodifluoromethyl)trimethyl-

115262-00-5

C4H9ClF2Si

Aliphatics, Miscellaneous Reagents, Sulfur & Selenium Compounds