ChemicalBook > CAS DataBase List > (chlorodifluoroMethyl)triMethylsilane
(chlorodifluoroMethyl)triMethylsilane
- Product Name
- (chlorodifluoroMethyl)triMethylsilane
- CAS No.
- 115262-00-5
- Chemical Name
- (chlorodifluoroMethyl)triMethylsilane
- Synonyms
- Chlordifluormethyltrimethylsilan;(chlorodifluoroMethyl)triMethylsilane;Silane, (chlorodifluoromethyl)trimethyl-
- CBNumber
- CB92644986
- Molecular Formula
- C4H9ClF2Si
- Formula Weight
- 158.65
- MOL File
- 115262-00-5.mol
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(chlorodifluoroMethyl)triMethylsilane Property
- Boiling point:
- 90.0±40.0 °C(Predicted)
- Density
- 1.039±0.06 g/cm3(Predicted)
- storage temp.
- Storage temp. 2-8°C
- form
- liquid
- color
- colorless
- InChI
- InChI=1S/C4H9ClF2Si/c1-8(2,3)4(5,6)7/h1-3H3
- InChIKey
- DGLFKUGPLIRHCC-UHFFFAOYSA-N
- SMILES
- [Si](C(Cl)(F)F)(C)(C)C
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N-Bromosuccinimide Price
Frontier Specialty Chemicals
- Product number
- JK1578319
- Product name
- (Chlorodifluoromethyl)trimethylsilane
- Purity
- 98%
- Packaging
- 250mg
- Price
- $75
- Updated
- 2021/12/16
Biosynth Carbosynth
- Product number
- FC45667
- Product name
- (Chlorodifluoromethyl)trimethylsilane
- Packaging
- 50mg
- Price
- $80
- Updated
- 2021/12/16
ChemSupplyAustralia
- Product number
- 300936
- Product name
- (Chlorodifluoromethyl)trimethylsilane, 97%
- Packaging
- 1g
- Price
- $104.5
- Updated
- 2021/12/16
Biosynth Carbosynth
- Product number
- FC45667
- Product name
- (Chlorodifluoromethyl)trimethylsilane
- Packaging
- 100mg
- Price
- $125
- Updated
- 2021/12/16
Biosynth Carbosynth
- Product number
- FC45667
- Product name
- (Chlorodifluoromethyl)trimethylsilane
- Packaging
- 250mg
- Price
- $200
- Updated
- 2021/12/16
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(chlorodifluoroMethyl)triMethylsilane Chemical Properties,Usage,Production
Uses
(Chlorodifluoromethyl)trimethylsilane, is one of the partially fluorinated compounds, which are often used for diverse applications in materials science, agrochemistry, and the pharmaceutical industry.
Uses
(chlorodifluoroMethyl)triMethylsilane，also known as Hu reagent，it can be used to generate difluorocarbene at higher temperatures catalyzed by chloride ion.
Reactions
(1) Difluoromethylenation of alkenes.
Refs. 1) Angew. Chem. Int. Ed. 2011, 50, 7153 –7157; 2) Chem. Commun. 2011, 47, 2411–2413.
(2) Difluoromethylenation of alkynes.
Refs. 1) Angew. Chem. Int. Ed. 2011, 50, 7153 –7157; 2) Chem. Commun. 2011, 47, 2411–2413.
(3) Difluoromethylenation of TMSCN.
Ref. J. Org. Chem. 2012, 77, 5850?5855.
(4) Difluoromethylenation of benzyl and alkylzinc halides.
Ref. Org. Lett. 2013, 15, 917 – 919.
(5) Fluorination aminocarbonylation of aldehydes
Ref. Angew. Chem. Int. Ed. 2022, e202115467
References
[1]Angewandte Chemie International Edition.DOI :10.1002/anie.202283811
[2]The Journal of Organic Chemistry.DOI :10.1021/acs.orglett.2c02899
(chlorodifluoroMethyl)triMethylsilane Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from (chlorodifluoroMethyl)triMethylsilane manufacturers
Henan Aochuang Chemical Co.,Ltd.
- Product
- (chlorodifluoroMethyl)triMethylsilane 115262-00-5
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-10-09
Zibo Hangyu Biotechnology Development Co., Ltd
- Product
- (chlorodifluoroMethyl)triMethylsilane 115262-00-5
- Price
- US $0.10/kg
- Min. Order
- 0.004999999888241291kg
- Purity
- 99.99%
- Supply Ability
- 20 tons
- Release date
- 2024-04-15
Career Henan Chemical Co
- Product
- [Chloro(difluoro)methyl](trimethyl)silane 115262-00-5
- Price
- US $9.80/KG
- Min. Order
- 1KG
- Purity
- ＞98%HPLC
- Supply Ability
- 20 tons
- Release date
- 2020-02-06