ChemicalBook > CAS DataBase List > 6-broMo-1-Methyl-1H-pyrrolo[3,2-b]pyridine6-broMo-1-Methyl-1H-pyrrolo[3,2-b]pyridine

6-broMo-1-Methyl-1H-pyrrolo[3,2-b]pyridine6-broMo-1-Methyl-1H-pyrrolo[3,2-b]pyridine

Product Name
6-broMo-1-Methyl-1H-pyrrolo[3,2-b]pyridine6-broMo-1-Methyl-1H-pyrrolo[3,2-b]pyridine
CAS No.
1086064-46-1
Chemical Name
6-broMo-1-Methyl-1H-pyrrolo[3,2-b]pyridine6-broMo-1-Methyl-1H-pyrrolo[3,2-b]pyridine
Synonyms
6-Bromo-1-methyl-4-azaindole;1H-Pyrrolo[3,2-b]pyridine, 6-bromo-1-methyl-;6-broMo-1-Methyl-1H-pyrrolo[3,2-b]pyridine6-broMo-1-Methyl-1H-pyrrolo[3,2-b]pyridine
CBNumber
CB92655214
Molecular Formula
C8H7BrN2
Formula Weight
211.06
MOL File
1086064-46-1.mol
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6-broMo-1-Methyl-1H-pyrrolo[3,2-b]pyridine6-broMo-1-Methyl-1H-pyrrolo[3,2-b]pyridine Property

storage temp. 
2-8°C
Appearance
White to yellow Solid
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Safety

HS Code 
2933399990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

SynQuest Laboratories
Product number
3H32-9-8B
Product name
6-Bromo-1-methyl-1H-pyrrolo[3,2-b]pyridine
Purity
95.0%
Packaging
250mg
Price
$117
Updated
2021/12/16
Apolloscientific
Product number
OR301261
Product name
6-Bromo-1-methyl-1H-pyrrolo[3,2-b]pyridine
Packaging
250mg
Price
$99
Updated
2021/12/16
Chemenu
Product number
CM149588
Product name
6-bromo-1-methyl-1H-pyrrolo[3,2-b]pyridine
Purity
95%+
Packaging
100mg
Price
$113
Updated
2021/12/16
Ambeed
Product number
A312440
Product name
6-Bromo-1-methyl-1H-pyrrolo[3,2-b]pyridine
Purity
95%
Packaging
100mg
Price
$66
Updated
2021/12/16
Ambeed
Product number
A312440
Product name
6-Bromo-1-methyl-1H-pyrrolo[3,2-b]pyridine
Purity
95%
Packaging
250mg
Price
$88
Updated
2021/12/16
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6-broMo-1-Methyl-1H-pyrrolo[3,2-b]pyridine6-broMo-1-Methyl-1H-pyrrolo[3,2-b]pyridine Chemical Properties,Usage,Production

Synthesis

944937-53-5

74-88-4

1086064-46-1

Step 2: 6-Bromo-4-azaindole (1.0 g, 5 mmol) was dissolved in N,N-dimethylformamide (10 mL) and cooled in an ice bath. Sodium hydride (400 mg, 10 mmol, 60% dispersed in mineral oil) was added slowly with stirring. The ice bath temperature was maintained and stirring was continued for 1 hour. Subsequently, iodomethane (852 mg, 6 mmol) was added dropwise and the reaction mixture was warmed to 25 °C and stirred for 2 hours. Upon completion of the reaction, the reaction was quenched with methanol. The mixture was concentrated to dryness under reduced pressure. The residue was purified by column chromatography (silica gel, 100-200 mesh, eluent: hexane solution of 20% ethyl acetate) to afford 6-bromo-1-methyl-1H-pyrrolo[3,2-b]pyridine (1 g, 95% yield).1H NMR (400 MHz, chloroform-d) δ 8.47 (d, J=2 Hz, 1H), 7.75-7.74 (m, 1H) , 7.25-7.23 (m, 1H), 6.65-6.63 (m, 1H), 3.76 (s, 3H).

References

[1] Patent: WO2016/142310, 2016, A1. Location in patent: Page/Page column 78
[2] Patent: WO2014/11568, 2014, A1. Location in patent: Paragraph 0180; 0181; 0182
[3] Patent: WO2011/110575, 2011, A1. Location in patent: Page/Page column 66

6-broMo-1-Methyl-1H-pyrrolo[3,2-b]pyridine6-broMo-1-Methyl-1H-pyrrolo[3,2-b]pyridine Preparation Products And Raw materials

Raw materials

Preparation Products

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6-broMo-1-Methyl-1H-pyrrolo[3,2-b]pyridine6-broMo-1-Methyl-1H-pyrrolo[3,2-b]pyridine Suppliers

Aladdin Scientific
Tel
Email
tp@aladdinsci.com
Country
United States
ProdList
57505
Advantage
58
Synthonix Inc
Tel
--
Fax
--
Email
info@synthonix.com
Country
United States
ProdList
6872
Advantage
58

1086064-46-1, 6-broMo-1-Methyl-1H-pyrrolo[3,2-b]pyridine6-broMo-1-Methyl-1H-pyrrolo[3,2-b]pyridineRelated Search:


  • 6-broMo-1-Methyl-1H-pyrrolo[3,2-b]pyridine6-broMo-1-Methyl-1H-pyrrolo[3,2-b]pyridine
  • 1H-Pyrrolo[3,2-b]pyridine, 6-bromo-1-methyl-
  • 6-Bromo-1-methyl-4-azaindole
  • 1086064-46-1