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AMBROX DL

Product Name
AMBROX DL
CAS No.
3738-00-9
Chemical Name
AMBROX DL
Synonyms
Cetalox;Ambermor;AMBERLYN;AMBROX DL;Ambraoxide;AMBERLYN 50;Iridium ether;CETALOX 922560;amber naphthofuran;AMBROX DL, FIRMENICH
CBNumber
CB9272233
Molecular Formula
C16H28O
Formula Weight
236.39
MOL File
3738-00-9.mol
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AMBROX DL Property

Melting point:
75-76 °C
Boiling point:
273.9±8.0 °C(Predicted)
Density 
0.939±0.06 g/cm3(Predicted)
FEMA 
3471 | 1,5,5,9-TETRAMETHYL-13-OXATRICYCLO(8.3.0.0(4,9))TRIDECANE
Odor
at 10.00 % in dipropylene glycol. dry woody amber ambergris musk sweet
Appearance
colourless to very pale yellow solid
Odor Type
amber
JECFA Number
1240
LogP
5.41
EPA Substance Registry System
Naphtho[2,1-b]furan, dodecahydro-3a,6,6,9a-tetramethyl- (3738-00-9)
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

American Custom Chemicals Corporation
Product number
FFG0002227
Product name
DODECAHYDRO-3ALPHA,6,6,9ALPHA-TETRAMETHYL-NAPHTHO[2,1-B]FURAN
Purity
95.00%
Packaging
5MG
Price
$501.47
Updated
2021/12/16
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AMBROX DL Chemical Properties,Usage,Production

Chemical Properties

3a,6,6,9a-Tetramethyldodecahydronaphtho[2,1-b]furan is a crystalline autoxidation product of ambrein with a typical ambergris odor. It is prepared from (?)-sclareol, a diterpene alcohol obtained from extraction of clary sage plants. Oxidative degradation to a lactone (“sclareolide”), hydrogenation of the latter to the corresponding diol, and dehydration yield the title compound.

Occurrence

Reported found in clary sage oil.

Uses

This ingredient provides warmth, richness and elegance to all areas of perfumery from sheer florals to modern ambers. Due to its power, best effects can be achieved at lower dosages, however, higher levels are often used to provide performance and substantivity.

Definition

ChEBI: Ambronide is a naphthofuran.

Preparation

Racemic sclareolide can be prepared by cyclization of homofarnesic acid in the presence of SnCl4 as a catalyst . Pure diastereomers are obtained by acid cyclization of (E)- and (Z)-4-methyl-6-(2,6,6-trimethylcyclohex-l(2)-enyl)-3- hexen-1-ol, prepared from 2-methyl-4-(2,6,6-trimethylcyclohex-l(2)-enyl)-2- butenal [394]. If the racemic sclareolide mixture is resolved into its enantiomers, the (–)-oxide may also be obtained by a totally synthetic route

Synthesis Reference(s)

Synthesis, p. 216, 1983 DOI: 10.1055/s-1983-30287

Trade name

Compound starting from natural sclareol: Ambermore, Ambermore-DL, Ambermore-EX (Aromor), Ambrox® Super (Firmenich), Ambroxide® (Kao), Ambroxide (Symrise); compound starting from homofarnesic acid derivatives: Ambrox® DL (Firmenich); compound starting from 2-methyl- 4-(2,6,6-trimethylcyclohex-l(2)enyl)-2-butenal: Cetalox® (Firmenich), Cetalor (Aromor).

AMBROX DL Preparation Products And Raw materials

Raw materials

Preparation Products

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AMBROX DL Suppliers

Alfa Chemistry
Tel
+1-5166625404;
Fax
1-516-927-0118
Email
Info@alfa-chemistry.com
Country
United States
ProdList
20405
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58
Vigon International, Inc.
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--
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Email
jpassamonte@vigoninternational.com
Country
United States
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64
Associate Allied Chemicals
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--
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aacipl@aacipl.com
Country
United States
ProdList
371
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58
Penta International Corporation
Tel
--
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--
Email
lisaa@pentamfg.com
Country
United States
ProdList
5042
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58
Ernesto Ventós S.A.
Tel
--
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Email
info@ventos.com
Country
United States
ProdList
2257
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Firmenich Inc.
Tel
--
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Email
Frederick.Keifer@firmenich.com
Country
United States
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Azelis UK Ltd.
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--
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fi@azelis.co.uk
Country
United States
ProdList
822
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Augustus Oils Ltd
Tel
--
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Email
essentials@augustus-oils.ltd.uk
Country
United States
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1404
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58
Vigon International
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sales@vigon.com
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Lluch Essence S.L.
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web@lluche.com
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The Lermond Company
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info@lermond.com
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United States
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Indukern, S.A. F&F Ingredients Division
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info@indukern.es
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Penta Manufacturing Company
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View Lastest Price from AMBROX DL manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
(?)-Ambroxide 3738-00-9
Price
US $1.10-9.90/kg
Min. Order
1kg
Purity
99%min
Supply Ability
100kg
Release date
2025-08-18

3738-00-9, AMBROX DLRelated Search:


  • Iridium ether
  • 1-b]furan,dodecahydro-3a,6,6,9a-tetramethyl-Naphtho[2
  • Dodecahydro-3a,6,6,9a-tetramethylnaphtho[2,1-b]furan
  • AMBROX DL
  • DODECAHYDRO-3A,6,6,9A-TETRAMETHYLNAPHTO-(2,1-B)-FURAN
  • Dodecahydro-3a,6,6,9a-tetramethylnaphtho[2,1-b]fur
  • Ambermor
  • Tetramethyl perhydronaphthofuran
  • Naphtho2,1-bfuran, dodecahydro-3a,6,6,9a-tetramethyl-
  • AMBROX DL, FIRMENICH
  • Dodecahydro-3a,6,6,9a-tetramethylnaphtol[2,1-b]furan
  • AMBERLYN 50
  • 3a,6,6,9a-Tetramethyldodecahydronaphtho[2,1-b]furan
  • 3a,6,6,9a-tetramethyl-2,4,5,5a,7,8,9,9b-octahydro-1H-benzo[e][1]benzofuran
  • 3a,6,6,9a-tetramethyl-2,4,5,5a,7,8,9,9b-octahydro-1H-benzo[e]benzofuran
  • AMBERLYN
  • Ambraoxide
  • Cetalox
  • 1-b]furan,dodecahydro-3a,6,6,9a-tetramethyl-naphtho[
  • (3aR,5aS,9aS,9bR)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furan
  • amber naphthofuran
  • Dodecahydro-3a,6,6,9a-tetramethylnaphthol[2,1-b]furan
  • CETALOX 922560
  • Cetalox,Ambrox DL,Ambrotech,Ambermor
  • Supernatural Ambergis Ether
  • 3738-00-9