Reaction
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[Ru(bpz)3][PF6]2

Reaction
Product Name
[Ru(bpz)3][PF6]2
CAS No.
80907-56-8
Chemical Name
[Ru(bpz)3][PF6]2
Synonyms
[Ru(bpz)?][PF?]?;[Ru(bpz)3][PF6]2;[Ru(bpz)3][PF6]2 95%;[Ru(bpz)3][PF6]2 AldrichCPR;2'-bipyrazine) ruthenium hexafluoroborate;Tris (2,2'-bipyrazine) ruthenium hexafluoroborate;Tris (2,2'-bipyrazine) ruthenium hexafluoroborate;Tris(2,2'-bipyrazine)ruthenium(II) hexafluorophosphate;Tris(2,2′-bipyrazine)ruthenium bis(hexafluorophosphate);TRIS(2,2'-BIPYRAZINE)RUTHENIUM(II)HEXAFLUOROPHOSPHATE,95%
CBNumber
CB92751008
Molecular Formula
C24H18F6N12PRu+
Formula Weight
720.53
MOL File
80907-56-8.mol
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[Ru(bpz)3][PF6]2 Property

Melting point:
162-210°C (The MP data is a DECOMP) (lit.)
storage temp. 
Inert atmosphere,Room Temperature
form 
Powder
color 
red
Sensitive 
air sensitive
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Safety

Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
TSCA 
No
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
747777
Product name
[Ru(bpz)3][PF6]2
Purity
95%
Packaging
50mg
Price
$86.4
Updated
2024/03/01
Sigma-Aldrich
Product number
747777
Product name
[Ru(bpz)3][PF6]2
Purity
95%
Packaging
100mg
Price
$160
Updated
2024/03/01
Strem Chemicals
Product number
44-7910
Product name
Tris(2,2'-bipyrazine)ruthenium(II) hexafluorophosphate, 95%
Packaging
50mg
Price
$67
Updated
2024/03/01
Strem Chemicals
Product number
44-7910
Product name
Tris(2,2'-bipyrazine)ruthenium(II) hexafluorophosphate, 95%
Packaging
250mg
Price
$269
Updated
2024/03/01
ChemSupplyAustralia
Product number
300892
Product name
Tris(2,?2'-?Bipyrazine)ruthenium(II) hexafluorophosphate, 95%
Packaging
50mg
Price
$65
Updated
2021/12/16
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[Ru(bpz)3][PF6]2 Chemical Properties,Usage,Production

Reaction

  1. Endoperoxide synthesis by photocatalytic aerobic [2+2+2] cycloadditions.
  2. Aerobic oxidation of a tertiary aliphatic amine under visible-light photocatalysis. Facile synthesis of methylenebridged bis-1,3-dicarbonyl compounds.
  3. Hydrophosphinylation of unactivated alkenes with secondary phosphine oxides under visible-light photocatalysis.
  4. Photooxygenation of aryl cyclopropanes via visible light photocatalysis.

Uses

[Ru(bpz)3][PF6]2 may be employed as a photocatalyst during the preparation of cyclopentylamine derivatives, via visible light-assisted cycloaddition reaction of N-arylcyclopropylamines with styrene derivatives. It may also be employed for the photocatalytic synthesis of trans-substituted cyclohexene derivative.

General Description

[Ru(bpz)3][PF6]2 can be prepared from 2-iodopyrazine.

[Ru(bpz)3][PF6]2 Preparation Products And Raw materials

Raw materials

Preparation Products

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[Ru(bpz)3][PF6]2 Suppliers

Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
8418
Advantage
55
Daicel Chiral Technologies (China)CO.,LTD
Tel
021-50460086-9 15921403865
Fax
+86-21-50462321
Email
han_yajun@dctc.daicel.com
Country
China
ProdList
7191
Advantage
65
ShangHai YuanYe Biotechnology Co., Ltd.
Tel
021-61312847 13636370518
Fax
021-55068248
Email
shyysw007@163.com
Country
China
ProdList
4940
Advantage
60
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
41462
Advantage
60
Suzhou Laing Biological Technology Co., LTD
Tel
0512-62968256 18550502935
Fax
0512-62968256
Email
export@laingbiotec.com
Country
China
ProdList
1106
Advantage
58
Shanghai Macklin Biochemical Co.,Ltd.
Tel
15221275939 15221275939
Fax
021-50706099
Email
shenlinxing@macklin.cn
Country
China
ProdList
16166
Advantage
55
Cool Pharm, Ltd
Tel
021-60455363 18019463053
Fax
50966098
Email
sales@coolpharm.com
Country
China
ProdList
12346
Advantage
58
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51456
Advantage
80
Dalian Idery Biotechnology Co., Ltd.
Tel
0411-62696576 15141125520
Fax
0411-66160116
Email
dlidery@yeah.net
Country
China
ProdList
198
Advantage
58
Alfa Chemistry
Tel
1-516-6625404
Fax
1-516-927-0118
Email
support@alfa-chemistry.com
Country
United States
ProdList
9171
Advantage
60
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View Lastest Price from [Ru(bpz)3][PF6]2 manufacturers

Zhejiang Free Trade Zone Violet Trade Co., Ltd.
Product
[Ru (bpz)3] [PF6]2 80907-56-8
Price
US $0.00/g
Min. Order
1g
Purity
99.90%
Supply Ability
100kgs
Release date
2021-09-16
Xian confluore Biological Technology Co., Ltd.
Product
Ru(bpz)3(PF6)2 80907-56-8
Price
US $0.00/g
Min. Order
1g
Purity
>95.00%
Supply Ability
1g
Release date
2024-03-30

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