(+)-B-METHOXYDIISOPINOCAMPHEYLBORANE

Product Name: (+)-B-METHOXYDIISOPINOCAMPHEYLBORANE
CAS No.: 85134-98-1
Chemical Name: (+)-B-METHOXYDIISOPINOCAMPHEYLBORANE
Synonyms: (-)-B-Methoxydiisopinocampheylborane;(+)-DIISOPINOCAMPHEYLMETHOXYBORANE;()-B-Methoxydiisopinocampheylborane;(+)-B-METHOXYDIISOPINOCAMPHEYLBORANE;)-B-Methoxydiisopinocampheylborane;()-B-Methoxydiisopinocampheylborane hydrate;(-)-B-Methoxydiisopinocampheylborane hydrate;Methoxybis((1R,2R,3S,5R)-2,6,6-trimethylbicyclo[3.1.1]Heptan-3-yl)borane;Methoxybis((1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl)borane;methoxy-bis[(1R,3S,4R,5R)-4,6,6-trimethyl-3-bicyclo[3.1.1]heptanyl]borane
CBNumber: CB9279292
Molecular Formula: C21H37BO
Formula Weight: 316.33
MOL File: 85134-98-1.mol

More

Less

(+)-B-METHOXYDIISOPINOCAMPHEYLBORANE Property

Melting point:: >110 °C
Boiling point:: 365.6±9.0 °C(Predicted)
Density: 0.95±0.1 g/cm3(Predicted)
Flash point:: >230 °F
storage temp.: 2-8°C
form: solid
color: white
optical activity: [α]20/D 72±3°, c = 1% in diethyl ether

More

Less

Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3
F: 10-21

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 317047
Product name: (?)-B-Methoxydiisopinocampheylborane
Packaging: 25g
Price: $426
Updated: 2024/03/01

Sigma-Aldrich

Product number: 317047
Product name: (?)-B-Methoxydiisopinocampheylborane
Packaging: 5g
Price: $200
Updated: 2023/06/20

Sigma-Aldrich

Product number: 317047
Product name: (?)-B-Methoxydiisopinocampheylborane
Packaging: 100g
Price: $391.8
Updated: 2024/03/01

TRC

Product number: M269740
Product name: (-)-B-Methoxydiisopinocampheylboranehydrate
Packaging: 100mg
Price: $40
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: BOR0004000
Product name: (-)-BETA-METHOXYDIISOPINOCAMPHEYLBORANE
Purity: 95.00%
Packaging: 5MG
Price: $499.94
Updated: 2021/12/16

More

Less

(+)-B-METHOXYDIISOPINOCAMPHEYLBORANE Chemical Properties,Usage,Production

Uses

Reactant involved in organic synthesis reactions such as:

Double allylboration for synthesis of fragments of tetrafibricin
Anticancer cytotoxic monorhizopodin synthesis
Annulation of cyclic allylsilanes
Asymmetric synthesis of β-amino-α-hydroxy acid taxol side chain analogs

Application

B-Methoxydiisopinocampheylborane is a intermediate for the synthesis of B-allyl- and B-crotyldiisopinocampheylboranes; reacts with potassium hydride to form an asymmetric reducing agent.

Preparation

B-Methoxydiisopinocampheylborane is prepared in two steps from either (+)- or (-)-α-pinene (eq 1).

General Description

B-Methoxydiisopinocampheylborane (Ipc₂BOMe) is an organoborane compound, which is prepared from excess α-pinene, borane dimethylsulfide, and methanol via the formation of an intermediate diisocampheylborane. Ipc₂BOMe is used as a versatile reagent for the construction of C-C bonds in asymmetric synthesis.

(+)-B-METHOXYDIISOPINOCAMPHEYLBORANE Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

(+)-B-METHOXYDIISOPINOCAMPHEYLBORANE Suppliers

China 25 Switzerland 1 United States 5 Global 31

Capot Chemical Co., Ltd

Tel: +86 (0) 571 85 58 67 18
Fax: 0086-571-85864795
Email: sales@capotchem.com
Country: China
ProdList: 18207
Advantage: 66

Shanghai Scientia Pharmaceutical Technology Co., Ltd.

Tel: 21-21-54301573 13917723525
Fax: (86)21-51861981
Email: sales@scientiapharm.com
Country: China
ProdList: 263
Advantage: 62

Tianjin heowns Biochemical Technology Co., Ltd.

Tel: 400 638 7771
Email: sales@heowns.com
Country: China
ProdList: 14435
Advantage: 57

Shanghai Aladdin Bio-Chem Technology Co.,LTD

Tel: 400-6206333 18021050169
Fax: 021-50323701
Email: market@aladdin-e.com
Country: China
ProdList: 25003
Advantage: 65

Sigma-Aldrich

Tel: 021-61415566 800-8193336
Email: orderCN@merckgroup.com
Country: China
ProdList: 51456
Advantage: 80

Alfa Chemistry

Tel: 1-516-6625404
Fax: 1-516-927-0118
Email: support@alfa-chemistry.com
Country: United States
ProdList: 9171
Advantage: 60

Shanghai Forxine Pharmaceutical Co., Ltd.

Tel: 21-21-64961388 18918697718
Fax: 6496-1388-8320
Email: service@forxine.com
Country: China
ProdList: 62
Advantage: 60

Chengdu Dianchun Technology Co., Ltd

Tel: 400-1166-196 18502815961
Fax: QQ：800101999
Email: cdhxsj@163.com
Country: China
ProdList: 14603
Advantage: 60

Capot Chemical Co.,Ltd.

Tel: +86-（0）57185586718 +86-13336195806
Fax: +86-571-85864795
Email: sales@capot.com
Country: China
ProdList: 29792
Advantage: 60

Aikon International Limited

Tel: 025-66113011 13155353615
Fax: (7)02557626880
Email: qzhang@aikonchem.com
Country: China
ProdList: 15394
Advantage: 58

More

Less

View Lastest Price from (+)-B-METHOXYDIISOPINOCAMPHEYLBORANE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: ()-B-Methoxydiisopinocampheylborane hydrate 85134-98-1
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

Career Henan Chemical Co

Product: (+)-B-METHOXYDIISOPINOCAMPHEYLBORANE 85134-98-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%-99.9%
Supply Ability: 200kg
Release date: 2020-01-12

85134-98-1, (+)-B-METHOXYDIISOPINOCAMPHEYLBORANERelated Search:

ISO-PROPYLCYCLOBUTANE Methoxydiethylborane (+)-B-METHOXYDIISOPINOCAMPHEYLBORANE (-)-B-METHOXYDIISOPINOCAMPHEYLBORANE Disiamylborane (1R)-(+)-CIS-PINANE (1R)-(+)-TRANS-PINANE 1-ETHYLCYCLOBUTANE

(+)-B-METHOXYDIISOPINOCAMPHEYLBORANE

(+)-DIISOPINOCAMPHEYLMETHOXYBORANE

(-)-B-Methoxydiisopinocampheylborane

)-<I>B</I>-Methoxydiisopinocampheylborane

methoxy-bis[(1R,3S,4R,5R)-4,6,6-trimethyl-3-bicyclo[3.1.1]heptanyl]borane

Borinic acid, B,B-bis[(1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]hept-3-yl]-, methyl ester

()-B-Methoxydiisopinocampheylborane

(-)-B-Methoxydiisopinocampheylborane hydrate

()-B-Methoxydiisopinocampheylborane hydrate

Methoxybis((1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl)borane

Methoxybis((1R,2R,3S,5R)-2,6,6-trimethylbicyclo[3.1.1]Heptan-3-yl)borane

85134-98-1

C21H37BOxH2O

C21H37BO

Reduction

Chiral Catalysts, Ligands, and Reagents

Asymmetric Synthesis