TETRAETHYL PYROPHOSPHITE
- Product Name
- TETRAETHYL PYROPHOSPHITE
- CAS No.
- 21646-99-1
- Chemical Name
- TETRAETHYL PYROPHOSPHITE
- Synonyms
- TETRAETHYL PYROPHOSPHITE;Oxybis(diethoxyphosphine);Bis(diethoxyphosphino) ether;Tetraethyl pyrophosphite 96%;iethoxyphosphanyldiethylphosphite;Tetraethyl pyrophosphite,93%,tech.;Diphosphorous acid tetraethyl ester;TETRAETHYL PYROPHOSPHITE, TECH., 93%;Bis(phosphorous acid diethyl)anhydride;Oxybis(phosphonous acid diethyl) ester
- CBNumber
- CB9279595
- Molecular Formula
- C8H20O5P2
- Formula Weight
- 258.19
- MOL File
- 21646-99-1.mol
TETRAETHYL PYROPHOSPHITE Property
- Boiling point:
- 79-81 °C/1 mmHg (lit.)
- Density
- 1.057 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.434(lit.)
- Flash point:
- >230 °F
- solubility
- Chloroform (Slightly), DMSO (Sparingly), Methanol (Slightly)
- form
- Oil
- color
- Colourless
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 155411
- Product name
- Tetraethyl pyrophosphite
- Purity
- 96%
- Packaging
- 5g
- Price
- $183
- Updated
- 2024/03/01
- Product number
- T303765
- Product name
- Tetraethyl pyrophosphite
- Packaging
- 500mg
- Price
- $95
- Updated
- 2021/12/16
- Product number
- CHM0156978
- Product name
- TETRAETHYL PYROPHOSPHITE
- Purity
- 95.00%
- Packaging
- 5G
- Price
- $927.15
- Updated
- 2021/12/16
TETRAETHYL PYROPHOSPHITE Chemical Properties,Usage,Production
Chemical Properties
clear colorless liquid
Uses
Tetraethyl Pyrophosphite is used as a reagent in the preparation of peptides and in the phosphonylation of carbonyl compounds.
Uses
The product can be used as a reagent for peptide synthesis.
Application
Tetraethyl pyrophosphite can be used in peptide synthesis; phosphonylation of ketones, aldehydes, and perfluoroalkyl iodides.
Preparation
The most convenient method involves the reaction of diethyl phosphite with diethyl phosphorochloridite. Diethyl phosphorochloridite (223 g) is added rapidly to a solution of diethyl phosphite (138 g) and triethylamine (101 g) in benzene (200 ml). The mixture is filtered and the benzene removed by distillation at reduced pressure. The product is isolated by further distillation at reduced pressure (79-81 °C/0.15 mmHg) in 41% yield.
TETRAETHYL PYROPHOSPHITE Preparation Products And Raw materials
Raw materials
Preparation Products
TETRAETHYL PYROPHOSPHITE Suppliers
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View Lastest Price from TETRAETHYL PYROPHOSPHITE manufacturers
- Product
- Tetraethyl pyrophosphite 21646-99-1
- Price
- US $1.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 tons
- Release date
- 2020-01-16
- Product
- TETRAETHYL PYROPHOSPHITE 21646-99-1
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 97%-99.9%
- Supply Ability
- 100kg
- Release date
- 2019-12-21