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ALLYLTRICHLOROSILANE

Product Name
ALLYLTRICHLOROSILANE
CAS No.
107-37-9
Chemical Name
ALLYLTRICHLOROSILANE
Synonyms
DK034;NSC 20940;allylsilicone;allytrichlorosilane;allyltrichloro-silan;ALLYLTRICHLOROSILANE;TRICHLOROALLYLSILANE;trichloroallyl-silan;3-TRICHLOROSILYLPROPENE;Silane, trichloroallyl-
CBNumber
CB9294622
Molecular Formula
C3H5Cl3Si
Formula Weight
175.52
MOL File
107-37-9.mol
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ALLYLTRICHLOROSILANE Property

Melting point:
35℃
Boiling point:
116 °C750 mm Hg(lit.)
Density 
1.211 g/mL at 25 °C(lit.)
vapor density 
>1 (vs air)
vapor pressure 
10 mm Hg ( 16.1 °C)
refractive index 
n20/D 1.443(lit.)
Flash point:
88 °F
storage temp. 
Flammables area
solubility 
soluble in MeCN, THF, CH2Cl2, toluene, benzene, etc.; not compatible with protic solvents, acetone, and other ketones. Dipolar aprotic solvents (DMF, DMSO, HMPA, etc.) coordinate Si, thereby increasing the reactivity of C3H5SiCl3 with electrophiles.
form 
Liquid
Specific Gravity
1.211
color 
Clear colorless to slightly yellow
Water Solubility 
Soluble in THF, toluene, benzene. Reacts with water.
Hydrolytic Sensitivity
8: reacts rapidly with moisture, water, protic solvents
Sensitive 
Moisture Sensitive
BRN 
1743449
CAS DataBase Reference
107-37-9(CAS DataBase Reference)
EPA Substance Registry System
Silane, trichloro-2-propen-1-yl- (107-37-9)
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Safety

Hazard Codes 
F,C
Risk Statements 
11-34
Safety Statements 
16-26-33-36/37/39-43-45
RIDADR 
UN 1724 8/PG 2
WGK Germany 
1
RTECS 
VV1530000
10-21
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
29319090
Hazardous Substances Data
107-37-9(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
107778
Product name
Allyltrichlorosilane
Purity
95%
Packaging
5g
Price
$56.5
Updated
2024/03/01
Sigma-Aldrich
Product number
107778
Product name
Allyltrichlorosilane
Purity
95%
Packaging
25g
Price
$226
Updated
2024/03/01
Alfa Aesar
Product number
L03703
Product name
Allyltrichlorosilane, 95%
Packaging
5g
Price
$48
Updated
2024/03/01
Alfa Aesar
Product number
L03703
Product name
Allyltrichlorosilane, 95%
Packaging
25g
Price
$158
Updated
2024/03/01
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ALLYLTRICHLOROSILANE Chemical Properties,Usage,Production

Chemical Properties

Clear colorless to slightly yellow liquid

Chemical Properties

Allyl trichhlorosilane is a volatile, corrosive, flammable, colorless liquid. Irritating odor.

Physical properties

bp 116°C/750 Torr; nD 1.4450; d 1.211.

Uses

Intermediate for silicones, fiberous glass finishes.

Uses

Allyltrichlorosilane acts as a reagent that produces homoallylic alcohols upon reaction with aldehydes in DMF. It is used to make silicones and glass fiber fininshes.

Preparation

allyl trichlorosilane is conveniently prepared from allyl chloride, Cl3SiH, CuCl, and (i-Pr)2EtN (or Et3N) in ether at 20°C,or from allyl chloride and coppersilicon powder at 250°C.Other methods include the reaction of allyl chloride with SiCl4 in the presence of CuCl and Et3N7 or in the presence of Cp2Ni and HMPA at 90°C,the flash pyrolysis of allyl chloride with Si2Cl2 in PhCl at 500°C,the reaction of allylMgBr with SiCl4,coupling of allene with Cl3SiH, catalyzed by (Ph3P)4Pd (120°C, 5 h),11 and the elimination of HCl from Cl(CH2)3SiCl3 using, e.g., quinoline as base.The analogous (E)-crotyl trichlorosilane can be synthesized from (E)-crotyl chloride, Cl3SiH, CuCl, and (i-Pr)2EtN in ether at 20°C,or from (E)-crotyl chloride, SiCl4, and Cp2Ni in HMPA at 90°C.The reaction of (E)-crotyl chloride with Cl3SiH and Bu4PCl at 150°C has also been reported. (Z)-crotyl trichlorosilane, on the other hand, was prepared via the 1,4-addition of Cl3SiH to butadiene, catalyzed by (Ph4P)4Pd (at 20°Cor?78°C)or by (PhCN)2PdCl2;this hydrosilylation can also be catalyzed by Nior proceed uncatalyzed at 500–600°C.Analogous trifluoro and tribromo derivatives C3H5SiX3 (X = F and Br) have also been described.

General Description

A colorless liquid with a pungent odor. Flash point of 95°F. Corrosive to metals and tissue.

Reactivity Profile

Chlorosilanes, such as ALLYLTRICHLOROSILANE, are compounds in which silicon is bonded to from one to four chlorine atoms with other bonds to hydrogen and/or alkyl groups. Chlorosilanes react with water, moist air, or steam to produce heat and toxic, corrosive fumes of hydrogen chloride. They may also produce flammable gaseous H2. They can serve as chlorination agents. Chlorosilanes react vigorously with both organic and inorganic acids and with bases to generate toxic or flammable gases.

Health Hazard

Inhalation of vapor irritates mucous membranes. Liquid causes severe burns of eyes and skin and severe internal burns if ingested.

Safety Profile

Poison by intravenous route. Corrosive. See ALLYL COMPOUNDS. When heated to decomposition it emits toxic Cl-. A dangerous fire hazard. To fight fire, use foam, mist, spray, dry chemical.

Potential Exposure

Used to make silicones and glass fiber finishes.

Shipping

UN1724 Allyltrichlorosilane, stabilized, Hazard class: 8; Labels: 8-Corrosive material, 3-Flammable liquid

Incompatibilities

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Chlorosilanes react vigorously with bases and both organic and inorganic acids generating toxic and/or flammable gases. Chlorosilanes react with water, moist air, or steam to produce heat and toxic, corrosive fumes of hydrogen chloride gas. They may also produce flammable gaseous hydrogen. Attacks metals in the presence of moisture. Avoid all sources of ignition.

ALLYLTRICHLOROSILANE Preparation Products And Raw materials

Raw materials

Preparation Products

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ALLYLTRICHLOROSILANE Suppliers

Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696;
Email
info@hanhongsci.com
Country
China
ProdList
42982
Advantage
64
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18736
Advantage
57
Syntechem Co.,Ltd
Tel
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
12990
Advantage
57
BEST-REAGENT
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11726
Advantage
57
Novel Chemical
Tel
+86-21-64855560, 4008207808
Fax
+86-21-64855560-8021
Email
sales@novelglobal.com
Country
China
ProdList
124
Advantage
62
Thermo Fisher Scientific
Tel
800-810-5118
Fax
+86-10-84193589
Email
cnchemical@thermofisher.com
Country
China
ProdList
17779
Advantage
75
Shanghai Worldyang Chemical Co.,Ltd.
Tel
021-021-56795766
Fax
+86-21-56795266
Email
sales@worldyachem.com
Country
China
ProdList
9353
Advantage
58
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View Lastest Price from ALLYLTRICHLOROSILANE manufacturers

Career Henan Chemical Co
Product
allyltrichlorosilane 107-37-9
Price
US $1.00/KG
Min. Order
1KG
Purity
Min98% HPLC
Supply Ability
g/kg/ton
Release date
2019-12-25

107-37-9, ALLYLTRICHLOROSILANERelated Search:


  • 3-TRICHLOROSILYLPROPENE
  • ALLYLTRICHLOROSILANE
  • Allyl trichlorosilane, stabilized
  • allylsilicone
  • allylsiliconetrichloride
  • allyltrichloro-silan
  • allyltrichlorosilane,stabilized
  • Propen-3-yltrichlorosilane
  • Silane, allyltrichloro-
  • Silane, trichloroallyl-
  • trichloro-2-propenyl-silan
  • trichloro-2-propenyl-silane
  • TRICHLOROALLYLSILANE
  • Silane,trichloro-2-propen-1-yl-
  • trichloroallyl-silan
  • NSC 20940
  • Allyltrichlorosilane,95%
  • allytrichlorosilane
  • trichloro(prop-2-enyl)silane
  • DK034
  • 107-37-9
  • C3H5Cl3Si
  • H2CCHCH2SiCl3
  • CH2CHCH2SiCl3
  • Protecting and Derivatizing Reagents
  • Protection and Derivatization
  • Synthetic Reagents
  • Silicon-Based
  • Trichlorosilanes
  • Silane Coupling Agents
  • Si (Classes of Silicon Compounds)
  • Si-Cl Compounds
  • Vinylsilanes, Allylsilanes
  • Vinyl Silanes (Silane Coupling Agents)
  • Protection and Derivatization
  • Functional Materials
  • Si (Classes of Silicon Compounds)
  • Si-Cl Compounds
  • Silane Coupling Agents
  • Trichlorosilanes
  • Vinyl Silanes (Silane Coupling Agents)
  • Vinylsilanes, Allylsilanes
  • Protecting and Derivatizing Reagents
  • Self Assembly&Contact Printing
  • Self-Assembly Materials
  • SilanesProtection and Derivatization
  • Silicon-Based