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BENZYL TIGLATE

Aroma
Product Name
BENZYL TIGLATE
CAS No.
37526-88-8
Chemical Name
BENZYL TIGLATE
Synonyms
FEMA 3330;BENZYL TIGLATE;(E)-benzyl tiglate;Benzyl Tiglate >Benzyl-2-methylcrotonat;TIGLIC ACID BENZYL ESTER;benzyl 2-methylcrotonate;Benzyl Tiglate USP/EP/BP;BENZYL 2-METHYL-2-BUTENOATE;-Benzyl 2-methylbut-2-enoate
CBNumber
CB9308682
Molecular Formula
C12H14O2
Formula Weight
190.24
MOL File
37526-88-8.mol
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BENZYL TIGLATE Property

Boiling point:
139 °C9 mm Hg(lit.)
Density 
1.031 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.522(lit.)
FEMA 
3330 | BENZYL TRANS-2-METHYL-2-BUTENOATE
Flash point:
>230 °F
form 
clear liquid
color 
Colorless to Almost colorless
Odor
at 100.00 %. balsamic earthy mushroom vegetable plastic cortex almond nutty
Odor Type
balsamic
JECFA Number
846
BRN 
2556119
LogP
3.35
CAS DataBase Reference
37526-88-8(CAS DataBase Reference)
EPA Substance Registry System
2-Butenoic acid, 2-methyl-, phenylmethyl ester, (2E)- (37526-88-8)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
2
TSCA 
Yes
HS Code 
29161900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B3348
Product name
Benzyl Tiglate
Purity
>97.0%(GC)
Packaging
25g
Price
$55
Updated
2024/03/01
TRC
Product number
T440055
Product name
TiglicAcidBenzylEster
Packaging
50g
Price
$305
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
FFG0000041
Product name
BENZYL TIGLATE
Purity
95.00%
Packaging
5MG
Price
$503.86
Updated
2021/12/16
Medical Isotopes, Inc.
Product number
62146
Product name
TiglicAcidBenzylEster
Packaging
10g
Price
$610
Updated
2021/12/16
Medical Isotopes, Inc.
Product number
62146
Product name
TiglicAcidBenzylEster
Packaging
50g
Price
$775
Updated
2021/12/16
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BENZYL TIGLATE Chemical Properties,Usage,Production

Aroma

Peculiar fungus-like, mushroom-type odor with a rosy undertone.

Chemical Properties

Colorless liquid. Insoluble in water, soluble in alcohol and oils.

Occurrence

Reported found in clove bud and rose apple (Syz. jambos Alston).

Uses

Tiglic Acid Benzyl Ester is found as one of the Geranium essential oils, and essential oil and solvent extracts of Iris planifolia (Mill) from Algeria, possessing antibacterial activity. It is also the starting material in the synthesis of (S)-α-Acetolactic Acid (A163805).

Definition

ChEBI: Benzyl trans-2-methyl-2-butenoate is a carboxylic ester. It is functionally related to a benzyl alcohol.

Preparation

By direct esterification of tiglic acid with benzyl alcohol under azeotropic conditions.

Application

Benzyl tiglate has been suggested for use in Rose fragrances, where this particularly deep-earthy, almost musty undertone can be desirable, e.g. in combination with spicy undertones. This ester also introduces a certain naturalness of herbaceous character, and blends well with Vetiver oil, Oakmoss, etc. in Reseda and similar fragrance types. Suggested for use in Rose type fragrances. mainly as a background note and fixative.

Taste threshold values

Taste characteristics at 100 ppm: sweet, balsamic, spice-like with a nutty almond note.

BENZYL TIGLATE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from BENZYL TIGLATE manufacturers

Career Henan Chemical Co
Product
BENZYL TIGLATE 37526-88-8
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kg
Release date
2020-01-08

37526-88-8, BENZYL TIGLATERelated Search:


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  • 2-Butenoicacid,2-methyl-,phenylmethylester,(E)-
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  • trans-2-Butenoic acid, 2-methyl-, phenylmethyl ester
  • trans-2-Butenoicacid,2-methyl-,phenylmethylester
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