ChemicalBook > CAS DataBase List > 1,5-DIHYDROXYANTHRAQUINONE

1,5-DIHYDROXYANTHRAQUINONE

Product Name: 1,5-DIHYDROXYANTHRAQUINONE
CAS No.: 117-12-4
Chemical Name: 1,5-DIHYDROXYANTHRAQUINONE
Synonyms: ANTHRARUFIN;NSC 7211;NSC 646570;Anthrarufin,80%;Anthrarufin 85%;Anthrarufin >1,5 DIHYDROXY AQ;RARECHEM AQ BD AN24;LABOTEST-BB LT00160027;ANTHRARUFIN, TECH., 85%
CBNumber: CB9317976
Molecular Formula: C14H8O4
Formula Weight: 240.21
MOL File: 117-12-4.mol

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1,5-DIHYDROXYANTHRAQUINONE Property

Melting point:: 279 °C (dec.)(lit.)
Boiling point:: 342.92°C (rough estimate)
Density: 1.56 g/cm³
vapor density: 8.3 (vs air)
refractive index: 1.5430 (estimate)
storage temp.: -20°C Freezer
solubility: Poor solubility in all solvents tested.DMSO (Sparingly)
form: Solid
pka: 6.42±0.20(Predicted)
color: Yellow to Green
Merck: 14,689
BRN: 1881718
InChI: InChI=1S/C14H8O4/c15-9-5-1-3-7-11(9)14(18)8-4-2-6-10(16)12(8)13(7)17/h1-6,15-16H
InChIKey: JPICKYUTICNNNJ-UHFFFAOYSA-N
SMILES: C1(O)=C2C(C(=O)C3=C(C2=O)C=CC=C3O)=CC=C1
CAS DataBase Reference: 117-12-4(CAS DataBase Reference)
EPA Substance Registry System: Anthrarufin (117-12-4)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-37/39-36/37
WGK Germany: 3
RTECS: CB6630000
TSCA: Yes
HS Code: 29146990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 340014
Product name: Anthrarufin
Purity: technical grade, 85%
Packaging: 100g
Price: $158
Updated: 2025/07/31

TCI Chemical

Product number: D0562
Product name: Anthrarufin
Purity: >85.0%(HPLC)
Packaging: 25g
Price: $43
Updated: 2025/07/31

TCI Chemical

Product number: D0562
Product name: Anthrarufin
Purity: >85.0%(HPLC)
Packaging: 500g
Price: $161
Updated: 2022/04/27

TRC

Product number: A679300
Product name: Anthrarufin85%
Packaging: 2.5g
Price: $130
Updated: 2021/12/16

Usbiological

Product number: 002784
Product name: Anthrarufin
Packaging: 2.5g
Price: $460
Updated: 2021/12/16

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1,5-DIHYDROXYANTHRAQUINONE Chemical Properties,Usage,Production

Chemical Properties

Yellow to Green Solid

Uses

1,5-Dihydroxyanthraquinone (anthrarufin) is an important intermediate for manufacturing disperse blue dyes. It is the key intermediates for manufacturing disperse blue dyes via dinitrodihydroxyanthraquinone and vat dyes via diaminoanthraquinones.

Uses

1,5-Dihydroxyanthraquinone is an anthraquinone derivative with suppressive effects against nitric oxide (NO) synthase. Potential antimalarial agent. Used in studies as a potential competitive non-peptidic inhibitor of HIV-1 protei nase.

Uses

Important intermediate in the manufacture of alizarin and indanthrene dyestuffs. Forms insoluble Ba and Ca lakes; has been proposed as analytical reagent for the detection of Ca.

Definition

ChEBI: A dihydroxyanthraquinone that is anthracene-9,10-dione substituted by hydroxy groups at positions 1 and 5.

Synthesis

1,5-Dihydroxyanthraquinone is prepared from 1,5-anthraquinonedisulfonic acid by replacing the SO3H groups, and from 1,5-dinitroanthraquinone by directly replacing the nitro groups, e.g., in sulfolane with calcium oxide or, more effectively, via 1,5- dimethoxyanthraquinone and subsequent hydrolysis of the ether linkage.

Purification Methods

Purify anthrarufin by column chromatography on silica gel with CHCl3/Et2O as eluent, followed by recrystallisation from acetone. Alternatively recrystallise it from glacial acetic acid [Flom & Barbara J Phys Chem 89 4489 1985]. [Beilstein 7 III 2359, 8 IV 3268.]

1,5-DIHYDROXYANTHRAQUINONE Preparation Products And Raw materials

Raw materials

Anthracene MERCURY(II) SULFATE Aluminium chloride hexahydrate

Preparation Products

CI 63010 Disperse Blue BGL

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View Lastest Price from 1,5-DIHYDROXYANTHRAQUINONE manufacturers

Hebei Chuanghai Biotechnology Co., Ltd

Product: 1,5-DIHYDROXYANTHRAQUINONE 117-12-4
Price: US $20.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-10-24

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: 1,5-DIHYDROXYANTHRAQUINONE 117-12-4
Price: US $10.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20ton
Release date: 2024-06-03

Qingdao RENAS Polymer Material Co., Ltd.

Product: 1,5-dihydroxyanthraquinone 117-12-4
Price: US $0.00/kg
Min. Order: 20kg
Purity: 99%
Supply Ability: 20 tons
Release date: 2024-10-12

117-12-4, 1,5-DIHYDROXYANTHRAQUINONERelated Search:

1,5-DIHYDROXY-4,8-DINITROANTHRAQUINONE 4,8-diamino-1,5-dihydroxyanthraquinon Daunorubicin Menogaril DISPERSE BLUE 26 1,2,5,8-TETRAHYDROXYANTHRAQUINONE Adriamycin NOGALAMYCIN 1,4,5,8-TETRAHYDROXYANTHRAQUINONE Disperse Blue 56 1,5-DIHYDROXYANTHRAQUINONE 4,8-DIAMINO-1,5-DIHYDROXYANTHRAQUINONE-2,6-DISULFONIC ACID, DISODIUM SALT ALIZARIN SAFIROL SE 2,6-DIHYDROXYANTHRAQUINONE disodium 2,2-(5,8-dihydroxyanthraquinone-1,4-diyldiimino)bis(5-methylbenzenesulphonate) Anthracene-1,4,9,10-tetraol Alizarin 4,5-diamino-1,8-dihydroxyanthraquinon

1,5-dihydroxy-10-anthracenedione

1,5-Dihydroxy-9,10-anthracenedione

1,5-Dihydroxy-9,10-anthraquinone

1,5-Dihydroxyanthra-9,10-quinone

1,5-Dihydroxyanthrachinon

1,5-dihydroxy-anthraquinon

Anthraquinone, 1,5-dihydroxy-

LABOTEST-BB LT00160027

ANTHRARUFIN

1,5-DIHYDROXYANTHRAQUINONE

1,5 DIHYDROXY AQ

RARECHEM AQ BD AN24

1,5-dihydroxyanthracene-9,10-dione

ANTHRARUFIN, TECH., 85%

9,10-Anthracenedione, 1,5-dihydroxy-

Anthrarufin,80%

1,5-DIHYDROXYANTHRAQUINONE: TECH., 90%

Anthrarufin 85%

5-Dihydroxyanthraquinone

NSC 646570

NSC 7211

Anthrarufin technical grade, 85%

Anthrarufin &gt

Anthraquinone Impurity 1

117-12-4

HOC6H3CO2C6H3OH

C13 to C14

Carbonyl Compounds

Building Blocks

Organic Building Blocks

Ketones

Anthraquinones

Hydroxyanthraquinones

Aromatics

Intermediates & Fine Chemicals

Pharmaceuticals

Protein Kinase Inhibitors and Activators

Intermediates of Dyes and Pigments

Anthraquinones

Hydroxyanthraquinones