ChemicalBook > CAS DataBase List > Chloro(2-methylphenyl)[1,1'-bis(diphenylphosphino)ferrocene]nickel (II)
Chloro(2-methylphenyl)[1,1'-bis(diphenylphosphino)ferrocene]nickel (II)
- Product Name
- Chloro(2-methylphenyl)[1,1'-bis(diphenylphosphino)ferrocene]nickel (II)
- CAS No.
- 1501945-23-8
- Chemical Name
- Chloro(2-methylphenyl)[1,1'-bis(diphenylphosphino)ferrocene]nickel (II)
- Synonyms
- (dppf)Ni(o-tolyl)Cl;chloro(2-methylphenyl)[1,1`-bis(diphenylphosphino)ferrocene]nickel;Chloro(2-methylphenyl)[1,1'-bis(diphenylphosphino)ferrocene]nickel (II);CHLORO(2-METHYLPHENYL)[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]NICKEL(II),98%;(2-methylphenyl)[1,1'-bis(diphenylphosphino)ferrocene] Nickel (II) chloride;Chloro(2-methylphenyl)[1,1'-bis(diphenylphosphino)ferrocene]nickel (II), 98%
- CBNumber
- CB93357074
- Molecular Formula
- C41H29ClFeNiP2
- Formula Weight
- 733.62
- MOL File
- 1501945-23-8.mol
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Chloro(2-methylphenyl)[1,1'-bis(diphenylphosphino)ferrocene]nickel (II) Property
- Melting point:
- 173 °C
- storage temp.
- 2-8°C
- form
- Powder
- color
- yellow
- Sensitive
- air sensitive
- InChI
- InChI=1S/2C17H11P.C7H7.ClH.Fe.Ni/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;1-7-5-3-2-4-6-7;;;/h2*1-6,9-12,18H;2-5H,1H3;1H;;/q;;-1;;+2;/p-1
- InChIKey
- BNPFTYORGXHTBI-UHFFFAOYSA-M
- SMILES
- [Cl-][Ni+2]1([C-]2=CC=CC=C2C)P(C2C=CC=CC=2)(C2C=CC=CC=2)[C-]23C4=C5C6=C2[Fe+2]27893456C3C2=C7[C-]8(C9=3)P1(C1C=CC=CC=1)C1C=CC=CC=1
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H317May cause an allergic skin reaction
H334May cause allergy or asthma symptoms or breathing difficulties if inhaled
H341Suspected of causing genetic defects
H350May cause cancer
H360May damage fertility or the unborn child
H372Causes damage to organs through prolonged or repeated exposure
H410Very toxic to aquatic life with long lasting effects
- Precautionary statements
-
P201Obtain special instructions before use.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P308+P313IF exposed or concerned: Get medical advice/attention.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 802948
- Product name
- (dppf)Ni(o-tolyl)Cl
- Packaging
- 250mg
- Price
- $134
- Updated
- 2025/07/31
Sigma-Aldrich
- Product number
- 802948
- Product name
- (dppf)Ni(o-tolyl)Cl
- Packaging
- 1g
- Price
- $405
- Updated
- 2025/07/31
Ambeed
- Product number
- A1175359
- Product name
- Chloro(2-methylphenyl)[1,1'-bis(diphenylphosphino)ferrocene]nickel(II)
- Purity
- 97%
- Packaging
- 100mg
- Price
- $75
- Updated
- 2021/12/16
Ambeed
- Product number
- A1175359
- Product name
- Chloro(2-methylphenyl)[1,1'-bis(diphenylphosphino)ferrocene]nickel(II)
- Purity
- 97%
- Packaging
- 250mg
- Price
- $100
- Updated
- 2021/12/16
Ambeed
- Product number
- A1175359
- Product name
- Chloro(2-methylphenyl)[1,1'-bis(diphenylphosphino)ferrocene]nickel(II)
- Purity
- 97%
- Packaging
- 1g
- Price
- $295
- Updated
- 2021/12/16
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Chloro(2-methylphenyl)[1,1'-bis(diphenylphosphino)ferrocene]nickel (II) Chemical Properties,Usage,Production
General Description
(dppf)Ni(o-tolyl)Cl is an air stable reagent. Its crystal structure has been investigated by X-ray studies. (dppf)Ni(o-tolyl)Cl can be prepared from (Ph3P)2Ni(o-tolyl)Cl. It is widely employed as a precatalyst for various C-N bond formation reactions. Efficacy of (dppf)Ni(o-tolyl)Cl as a precatalyst for the amination of 4-n-butylchlorobenzene with morpholine under various optimized reaction conditions has been investigated.
reaction suitability
core: nickel
reaction type: Cross Couplings
reagent type: catalyst
Chloro(2-methylphenyl)[1,1'-bis(diphenylphosphino)ferrocene]nickel (II) Preparation Products And Raw materials
Raw materials
Preparation Products
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