2,6-Dimethyl-2,5-heptadien-4-one

ChemicalBook > CAS DataBase List > 2,6-Dimethyl-2,5-heptadien-4-one

2,6-Dimethyl-2,5-heptadien-4-one

Product Name: 2,6-Dimethyl-2,5-heptadien-4-one
CAS No.: 504-20-1
Chemical Name: 2,6-Dimethyl-2,5-heptadien-4-one
Synonyms: PHORONE;Foron;5-Heptadien-4-one;s-Diisopropylidene acetone;Phoron;SYM-DIISOP;Phorone,98+%;diisobutenylketone;Diisobutenyl ketone;diisopropylidineacetone
CBNumber: CB9351608
Molecular Formula: C9H14O
Formula Weight: 138.21
MOL File: 504-20-1.mol

Less

2,6-Dimethyl-2,5-heptadien-4-one Property

Melting point:: 23-26 °C(lit.)
Boiling point:: 198-199 °C(lit.)
Density: 0.885 g/mL at 25 °C(lit.)
vapor density: 4.8 (vs air)
vapor pressure: 0.38 mm Hg ( 20 °C)
refractive index: n20/D 1.497(lit.)
Flash point:: 175 °F
storage temp.: 2-8°C
solubility: Chloroform (Slightly), Methanol (Slightly)
form: Solid
color: Light Yellow to Yellow
Merck: 7333
InChI: InChI=1S/C9H14O/c1-7(2)5-9(10)6-8(3)4/h5-6H,1-4H3
InChIKey: MTZWHHIREPJPTG-UHFFFAOYSA-N
SMILES: C/C(/C)=C\C(=O)/C=C(\C)/C
CAS DataBase Reference: 504-20-1(CAS DataBase Reference)
EPA Substance Registry System: Phorone (504-20-1)

Less

Safety

WGK Germany: 3
RTECS: MI5500000
HS Code: 2914199090

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 149233
Product name: 2,6-Dimethyl-2,5-heptadien-4-one
Purity: 95%
Packaging: 10G
Price: $25.5
Updated: 2023/06/20

Sigma-Aldrich

Product number: 149233
Product name: 2,6-Dimethyl-2,5-heptadien-4-one
Purity: 95%
Packaging: 100G
Price: $113
Updated: 2023/06/20

TRC

Product number: D473415
Product name: DiisopropylideneAcetone
Packaging: 5G
Price: $90
Updated: 2021/12/16

Oakwood

Product number: 075754
Product name: 2,6-Dimethyl-2,5-heptadien-4-one
Packaging: 250mg
Price: $10
Updated: 2021/12/16

Matrix Scientific

Product number: 074268
Product name: 2,6-Dimethyl-2,5-heptadien-4-one
Purity: 95+%
Packaging: 5g
Price: $38
Updated: 2021/12/16

Less

2,6-Dimethyl-2,5-heptadien-4-one Chemical Properties,Usage,Production

Description

2,6-Dimethyl-2,5-heptadien-4-one (DMHD4O) is an industrially important diene molecule chemically known as phorone or diisopropylidene acetone, available in the form of yellow to green liquid and yellowish green prisms. It is a self-condensation product of acetone and can also be obtained from camphor. In particular, it is used as a solvent for nitrocellulose, synthetic resins, fibers, coating compositions, stains, lubricant additives, odor-resistant agent production, and intermediate for organic and pharmaceutical synthesis[1]. This compound possesses the property of increasing the reactivity of enzymes involved in glutathione metabolism.

Chemical Properties

Yellow liquid or yellow green prismatic crystal

Uses

Diisopropylidene Acetone is a reagent used in the preparation of biaryls by Suzuki-Miyaura cross coupling reaction.

Definition

ChEBI: Phorone is a dialkenyl ketone.

General Description

A yellowish liquid with a solvent-like odor. Density 7.3 lb / gal. Very low vapor pressure (0.38 mm Hg at 68°F). Flash point 185°F. Combustible but difficult to ignite. Used as a solvent for lacquers and coatings.

Air & Water Reactions

Slightly soluble in water.

Reactivity Profile

Ketones, such as 2,6-DIMETHYL-2,5-HEPTADIEN-4-ONE, are reactive with many acids and bases liberating heat and flammable gases (e.g., H2). The amount of heat may be sufficient to start a fire in the unreacted portion of the ketone. Ketones react with reducing agents such as hydrides, alkali metals, and nitrides to produce flammable gas (H2) and heat. Ketones are incompatible with isocyanates, aldehydes, cyanides, peroxides, and anhydrides. They react violently with aldehydes, HNO3, HNO3 + H2O2, and HClO4.

Health Hazard

Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Safety Profile

Moderately toxic by subcutaneous route. Combustible when exposed to heat or flame; can react with oxidizing materials. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ISOPHORON

Purification Methods

Crystallise phorone repeatedly from EtOH. [Beilstein 1 IV 3564.]

References

[1] V. Arjunan. “Electronic structure simulations of 2,6-dimethyl-2,5-heptadien-4-one by FTIR, FT-Raman, NMR, UV–vis, NBO and density functional theory.” Molecular Simulation 39 1 (2013): 185–198.

2,6-Dimethyl-2,5-heptadien-4-one Preparation Products And Raw materials

Raw materials

Preparation Products

2,6-Dimethyl-4-heptanone

Less

2,6-Dimethyl-2,5-heptadien-4-one Suppliers

China 133 France 2 Germany 2 India 1 Japan 1 Switzerland 1 United Kingdom 5 United States 14 Global 159

Xi'an Manareco New Materials Co., Ltd.

Tel: 029-02968669089-8816
Fax: +86-29-68669073
Email: market@xarlm.com
Country: China
ProdList: 453
Advantage: 55

Xi 'an billiton biological technology co., LTD

Tel: 029-88764766; 18191268030
Fax: 029 88764766
Email: wang.yali@xatuochao.com
Country: China
ProdList: 1042
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44751
Advantage: 61

Jia Xing Isenchem Co.,Ltd

Tel: 0573-85285100 18627885956
Fax: 0573-85285100
Email: isenchem@163.com
Country: China
ProdList: 9551
Advantage: 66

Accela ChemBio Co.,Ltd.

Tel: 021-50795510 4000665055
Fax: 021-50795055
Email: sales@accelachem.com
Country: China
ProdList: 11660
Advantage: 64

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696;
Email: info@hanhongsci.com
Country: China
ProdList: 42982
Advantage: 64

XiaoGan ShenYuan ChemPharm co,ltd

Tel: 15527768850
Email: 1791901229@qq.com
Country: China
ProdList: 8849
Advantage: 52

Sinopharm Chemical Reagent Co,Ltd.

Tel: 86-21-63210123
Fax: 86-21-63290778 86-21-63218885
Email: sj_scrc@sinopharm.com
Country: China
ProdList: 9823
Advantage: 79

Tongchuang Pharma(Suzhou). Co., Ltd.

Tel: 0512-63263366 18912765016
Fax: 0512-6326 3366
Email: tongtf110@sina.com
Country: China
ProdList: 1003
Advantage: 62

Hangzhou Sage Chemical Co., Ltd.

Tel: +86057186818502 13588463833
Fax: Pls mail us for more information!
Email: info@sagechem.com
Country: China
ProdList: 10269
Advantage: 58

Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.

Tel: 025-66099280 17798518460
Fax: (1)02557626880
Email: cfzhang@aikonchem.com
Country: China
ProdList: 19918
Advantage: 55

Shanghai Yolne Chemical Co., Ltd.

Tel: 021-62960152
Fax: 021-52212593
Email: 934678158@qq.com
Country: China
ProdList: 9906
Advantage: 55

Shanghai Raise Chemical Technology Co.,Ltd

Tel: +86-021-50935922
Fax: +86-021-33847795
Country: China
ProdList: 7876
Advantage: 55

Nanjing Sunlida Biological Technology Co., Ltd.

Tel: 025-57798810
Fax: 025-57019371
Email: sales@sunlidabio.com
Country: China
ProdList: 3750
Advantage: 55

Bide Pharmatech Ltd.

Tel: 400-1647117 15221909166
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 41438
Advantage: 60

ChemStrong Scientific Co.,Ltd

Tel: 0755-0755-66853366 13670046396
Fax: 0755-28363542
Email: sales@chem-strong.com
Country: China
ProdList: 17981
Advantage: 56

Hangzhou Dechem Tech Co.，Ltd

Tel: 86-0571-87649320
Fax: 86-0571-87649320
Email: dechem@aliyun.com
Country: China
ProdList: 163
Advantage: 58

Hunan HuaTeng Pharmaceutical Co., Ltd.,

Tel: 400-8592883 15367835770
Fax: 0731-82251112
Email: viola@huatengsci.com
Country: China
ProdList: 5877
Advantage: 58

Shanghai Macklin Biochemical Co.,Ltd.

Tel: 15221275939 15221275939
Fax: 021-50706099
Email: shenlinxing@macklin.cn
Country: China
ProdList: 15878
Advantage: 55

Shanghai Kewel Chemical Co., Ltd.

Tel: 021-64609169 18901607656
Fax: 021-64609160
Email: greensnown@163.com
Country: China
ProdList: 9911
Advantage: 50

Shanghai HuanChuan Industry Co.,Ltd.

Tel: 021-61478794
Fax: 021-61478794
Email: sales@hcshhai.com
Country: China
ProdList: 9798
Advantage: 50

Shanghai Yongye Biotechnology Co., Ltd.

Tel: 86-021-61559134 15921386130
Fax: 021-55068248
Email: 3423497944@qq.com
Country: China
ProdList: 8147
Advantage: 55

Nanjing Chalf-Pharm Technology Co., Ltd.

Tel: 025-57018978 18251899859
Fax: 025-57018008
Email: sales@chalf-pharm.com
Country: China
ProdList: 5945
Advantage: 50

Cool Pharm, Ltd

Tel: 021-60455363 18019463053
Fax: 50966098
Email: sales@coolpharm.com
Country: China
ProdList: 12357
Advantage: 58

Hubei Jusheng Technology Co.,Ltd

Tel: 027-59599241 18871490274
Fax: 027-59599241
Email: 1400878000@qq.com
Country: China
ProdList: 9972
Advantage: 58

shanghai sinofluoro chemicals co., ltd.

Tel: 15800445152
Fax: 021-64278603
Email: sales@sinofluoro.com
Country: China
ProdList: 299
Advantage: 59

ShangHai Siyan Biological Technology Co., Ltd.

Tel: 021-50908862，442785678，326799392 18721037013
Fax: 021-50908862
Email: siyansales@126.com
Country: China
ProdList: 9638
Advantage: 58

Shijiazhuang Sdyano Fine Chemical Co., Ltd.

Tel: 0311-89250318 031166536426
Fax: 4000311741
Email: master@sjzsdyn.com
Country: China
ProdList: 3496
Advantage: 58

Shanghai QianYan Bio-technology Co., Ltd

Tel: 02781293128
Email: orders@biochemsafebuy.com
Country: China
ProdList: 9934
Advantage: 55

Amadis Chemical Company Limited

Tel: 571-89925085
Fax: 0086-571-89925065
Email: sales@amadischem.com
Country: China
ProdList: 131981
Advantage: 58

Shanghai Qiandu Biological Technology Co., Ltd.

Tel: 021-61535850
Email: 2911799694@qq.com
Country: China
ProdList: 208
Advantage: 58

Shanghai Kangman Biological Technology Co., Ltd.

Tel: 18800375331
Fax: 021-50908862
Email: kangmansales@163.com
Country: China
ProdList: 7580
Advantage: 55

Zhengzhou Huiju Chemical Co., Ltd.

Tel: 0371-55900031 18137872243
Fax: QQ：2853979815
Email: 2853979815@qq.com
Country: China
ProdList: 10004
Advantage: 55

Amatek Scientific Co. Ltd.

Tel: 0512-56316828
Fax: 0512-56316826
Email: info@amateksci.com
Country: China
ProdList: 28821
Advantage: 58

Jiaxing Deyi Chemical Co., Ltd.

Tel: 86-0573-85866609 13325730825
Fax: 0573-85866609
Email: 945717149@qq.com
Country: China
ProdList: 7959
Advantage: 58

Capot Chemical Co.,Ltd.

Tel: 571-85586718 +8613336195806
Fax: +86-571-85864795
Email: sales@capotchem.com
Country: China
ProdList: 29797
Advantage: 60

Wuhan FengyaoTonghui Chemical Products Co., Ltd.

Tel: 027-87466105 15377573527
Email: 2678564200@qq.com
Country: China
ProdList: 17997
Advantage: 58

Shanghai Haohong Pharmaceutical Co., Ltd.

Tel: 400-8210725 18016230971
Fax: 021-58955996
Email: malulu@leyan.com
Country: China
ProdList: 24971
Advantage: 58

3A Chemicals

Tel: 400-668-9898
Fax: 010-51582189
Email: service@3achem.com
Country: China
ProdList: 20569
Advantage: 58

Zhengzhou Acme Chemical Co., Ltd.

Tel: 0371-0371-63315541 13323832564
Fax: QQ:3001332135
Email: 3001332135@qq.com
Country: China
ProdList: 8770
Advantage: 58

Shanghai Jizhi Biochemical Technology Co. Ltd.

Tel: 400-400-400-9004166 18616739031
Email: 3007523370@qq.com
Country: China
ProdList: 52712
Advantage: 58

Beijing Minruida Technology Co., Ltd.

Tel: 010-82387566 18001021521;
Fax: 82387566-801
Email: sales@mreda.com.cn
Country: China
ProdList: 21450
Advantage: 58

Shaanxi Jiandu Pharmaceutical Chemical Co. Ltd.

Tel: 029-87576359 17691182729
Fax: 029-88380327
Email: 1018@dideu.com
Country: China
ProdList: 1983
Advantage: 58

Shenzhen Polymeri Biochemical Technology Co., Ltd.

Tel: +86-400-002-6226 13028896684
Email: sales@rrkchem.com
Country: China
ProdList: 55827
Advantage: 58

Hangzhou Xinbaisi Biomedical Co., Ltd.

Tel: 13325818654
Fax: 057188737015
Email: sales@synbestech.com
Country: China
ProdList: 232
Advantage: 58

Henan Alfa Chemical Co., Ltd

Tel: +8618339805032
Email: alfa4@alfachem.cn
Country: China
ProdList: 12755
Advantage: 58

Shanghai UCHEM Inc.

Tel: +862156762820 +86-13564624040
Email: sales@myuchem.com
Country: China
ProdList: 6709
Advantage: 58

Nanjing Hengbei Chemicals Co., Ltd.

Tel: +86-25-58393656
Fax: +86-25-58393656
Email: sales@hengbeichem.cn
Country: China
ProdList: 6856
Advantage: 58

Hefei TNJ Chemical Industry Co.,Ltd.

Tel: 0551-65418671
Fax: 0551-65418697
Email: sales@tnjchem.com
Country: China
ProdList: 34572
Advantage: 58

Less

View Lastest Price from 2,6-Dimethyl-2,5-heptadien-4-one manufacturers

Hong Kong Tiansheng New Material Trading Co., Ltd

Product: Phorone 504-20-1
Price: US $1.23/KG
Min. Order: 500g
Purity: 99%
Supply Ability: 20TONS
Release date: 2021-12-16

Career Henan Chemical Co

Product: 2,6-DIMETHYL-2,5-HEPTADIEN-4-ONE 504-20-1
Price: US $1.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: Customized
Release date: 2018-12-17

504-20-1, 2,6-Dimethyl-2,5-heptadien-4-oneRelated Search:

2,6-Dimethyl-2,5-heptadien-4-one Leucodin hydroxyachillin 3,5-Dibromo-2,6-dimethyl-2,5-heptadien-4-one (3S,3AR,4S,9AS,9BR)-4-HYDROXY-3,6,9-TRIMETHYL-3,3A,4,5,9A,9B-HEXAHYDRO-AZULENO[4,5-B]FURAN-2,7-DIONE 7-[(tert-Butyloxycarbonyl)amino]-2,6-dimethyl-2,5-heptadien-4-one PHORONE, (2,6-DIMETHYL-2,5-HEPTADIEN-4-ONE) 3-Heptyl-6,6-dimethyl-3,4-heptadien-2-one 2,6-Dimethyl-2,5-heptadien-4-one(Phorone) 4,6-Dimethyl-3,5-heptadien-2-one SALOR-INT L160083-1EA molephantinin (3S)-4β-Acetoxy-3,3aβ,4,5,9aβ,9bα-hexahydro-3β,6,9-trimethylazuleno[4,5-b]furan-2,7-dione 2,5-BIS(CYCLOPENTYLLIDENE)CYCLOPENTANONE-1 AURORA KA-491 molephantin AKOS NCG-0033

diisopropylidineacetone

Foron

Phoron

s-Diisopropylidene acetone

DIISOPROPYLIDENEACETONE

2,6-DIMETHYL-2,5-HEPTADIEN-4-ONE

2,6-DIMETHYL-2,5-HEPTADIENE-4-ONE

SYM-DIISOPROPYLIDENEACETONE

PHORONE

Diisopropyllideneacetone

Phorone,98+%

diiosopropylideneacetone

2,5-HEPTADIEN-4-ONE,2,6-DIMET

3,6-dimethyl-2,5-hexadien-4-one

Bis(2-methyl-1-propenyl) ketone

Diisopropylydeneacetone

Phorone, sym-Diisopropylideneacetone

5-Heptadien-4-one,2,6-dimethyl-2

Diisobutenyl ketone

diisobutenylketone

5-Heptadien-4-one

SYM-DIISOP

2,5-Heptadien-4-one,2,6-dimethyl-

2,6-dimethyl-5-heptadien-4-one

2,6-dimethyl-hepta-2,5-dien-4-one

Metamfepramone Impurity 4 (Diisopropylidene Acetone)

504-20-1

CH32CCH2CO

UCH32CCH22CO

CH32CCHCOCHCCH32

COCHCH322

Building Blocks

Carbonyl Compounds

Ketones

Organic Building Blocks