ChemicalBook > CAS DataBase List > 3-METHYL-3-(TOLUENESULFONYLOXYMETHYL)OXETANE

3-METHYL-3-(TOLUENESULFONYLOXYMETHYL)OXETANE

Product Name
3-METHYL-3-(TOLUENESULFONYLOXYMETHYL)OXETANE
CAS No.
99314-44-0
Chemical Name
3-METHYL-3-(TOLUENESULFONYLOXYMETHYL)OXETANE
Synonyms
(3-Methyloxetan-3-yl);(3-Methyloxetan-3-yl)Methyl p-tosylate;(3-Methyl-3-oxetanyl)methyl p-tosylate;3-Hydroxymethyl-3-methyloxetane p-tosylate;3-METHYL-3-(TOLUENESULFONYLOXYMETHYL)OXETANE;3-METHYL-3-OXETANEMETHANOL P-TOLUENESULFONATE;3-Methyl-3-(p-toluenesulfonyloxymethyl)oxetane,98%;3-Methyl-3-(p-toluenesulfonyloxyMethyl)oxetane, 98%;(3-Methyloxetan-3-yl)Methyl 4-Methylbenzenesulfonate;(3-methyl-3-oxetanyl)methyl 4-methylbenzenesulfonate
CBNumber
CB9393624
Molecular Formula
C12H16O4S
Formula Weight
256.32
MOL File
99314-44-0.mol
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3-METHYL-3-(TOLUENESULFONYLOXYMETHYL)OXETANE Property

Melting point:
50-51°
Boiling point:
381.1±15.0 °C(Predicted)
Density 
1.218±0.06 g/cm3(Predicted)
storage temp. 
2-8°C
form 
Solid
color 
Off-white
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Safety

HazardClass 
IRRITANT
HS Code 
2904100090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TRC
Product number
M324468
Product name
(3-Methyloxetan-3-yl)methyl4-Methylbenzenesulfonate
Packaging
100mg
Price
$75
Updated
2021/12/16
Matrix Scientific
Product number
047397
Product name
(3-Methyl-3-oxetanyl)methyl4-methylbenzenesulfonate
Purity
97%
Packaging
500mg
Price
$61
Updated
2021/12/16
Matrix Scientific
Product number
047397
Product name
(3-Methyl-3-oxetanyl)methyl4-methylbenzenesulfonate
Purity
97%
Packaging
1g
Price
$87
Updated
2021/12/16
AK Scientific
Product number
J95846
Product name
(3-Methyloxetan-3-yl)methyl4-methylbenzenesulfonate
Packaging
5g
Price
$120
Updated
2021/12/16
Matrix Scientific
Product number
047397
Product name
(3-Methyl-3-oxetanyl)methyl4-methylbenzenesulfonate
Purity
97%
Packaging
5g
Price
$265
Updated
2021/12/16
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3-METHYL-3-(TOLUENESULFONYLOXYMETHYL)OXETANE Chemical Properties,Usage,Production

Definition

ChEBI: (3-Methyl-3-oxetanyl)methyl 4-methylbenzenesulfonate is a benzenesulfonate ester.

Synthesis

3143-02-0

98-59-9

99314-44-0

General procedure for the synthesis of (3-methyloxetan-3-yl)methyl 4-methylbenzenesulfonate from 3-methyl-3-hydroxymethoxetane and p-toluenesulfonyl chloride: Step 1: To a solution of (3-methyloxetan-3-yl)methanol (1 g, 9.79 mmol) in dichloromethane (15 ml) was added triethylamine (2.71 ml, 19.58 mmol) followed by p-toluenesulphonyl chloride (1.867 g, 9.79 mmol) at 0 °C. The reaction mixture was stirred at room temperature for 3 to 5 hours. Upon completion of the reaction, the reaction mixture was quenched with water, the organic layer was extracted with ethyl acetate and purified by column chromatography to afford the title compound (3-methyloxetan-3-yl)methyl 4-methylbenzenesulfonate (1.875 g) as a white solid in 74.7% yield. Product characterization data: 1H NMR (DMSO-d6, 300 MHz): δ 7.82 (d, J = 8.1 Hz, 2H), 7.51 (d, J = 8.1 Hz, 2H), 4.25 (d, J = 5.7 Hz, 2H), 4.19 (d, J = 6.0 Hz, 2H), 4.11 (s, 2H), 2.43 (s, 3H), 1.18 (s, 3H); MS (ESI): m/z 279.0 (M + Na).

References

[1] Chemistry of Materials, 2016, vol. 28, # 18, p. 6628 - 6636
[2] Organic Syntheses, 2002, vol. 79, p. 216 - 216
[3] Patent: WO2018/75698, 2018, A1. Location in patent: Paragraph 00272
[4] Journal of Organic Chemistry, 1998, vol. 63, # 11, p. 3631 - 3646
[5] Tetrahedron, 2001, vol. 57, # 8, p. 1497 - 1507

3-METHYL-3-(TOLUENESULFONYLOXYMETHYL)OXETANE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 3-METHYL-3-(TOLUENESULFONYLOXYMETHYL)OXETANE manufacturers

Henan Fengda Chemical Co., Ltd
Product
3-METHYL-3-(TOLUENESULFONYLOXYMETHYL)OXETANE 99314-44-0
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-26
Career Henan Chemical Co
Product
3-METHYL-3-(TOLUENESULFONYLOXYMETHYL)OXETANE 99314-44-0
Price
US $2.00/KG
Min. Order
1g
Purity
98%min
Supply Ability
ask
Release date
2020-01-08

99314-44-0, 3-METHYL-3-(TOLUENESULFONYLOXYMETHYL)OXETANERelated Search:

3,3-DIMETHYLOXETANE BENZENESULFONIC ACID NEOPENTYL ESTER 3-Methyl-3-oxetanemethanol 3-METHYL-3-(TOLUENESULFONYLOXYMETHYL)OXETANE

  • 3-METHYL-3-OXETANEMETHANOL P-TOLUENESULFONATE
  • 3-METHYL-3-(TOLUENESULFONYLOXYMETHYL)OXETANE
  • (3-methyl-3-oxetanyl)methyl 4-methylbenzenesulfonate
  • 3-Methyl-3-(p-toluenesulfonyloxyMethyl)oxetane, 98%
  • (3-Methyloxetan-3-yl)Methyl 4-Methylbenzenesulfonate
  • (3-Methyloxetan-3-yl)
  • (3-Methyloxetan-3-yl)Methyl p-tosylate
  • (3-methyloxetan-3-yl)methyl 4-methylbenzene-1-sulfonate
  • 3-Methyl-3-(p-toluenesulfonyloxymethyl)oxetane,98%
  • 3-Hydroxymethyl-3-methyloxetane p-tosylate
  • (3-Methyl-3-oxetanyl)methyl p-tosylate
  • 3-Oxetanemethanol, 3-methyl-, 3-(4-methylbenzenesulfonate)
  • 99314-44-0