TERT-BUTYL-D9-AMINE
- Product Name
- TERT-BUTYL-D9-AMINE
- CAS No.
- 6045-08-5
- Chemical Name
- TERT-BUTYL-D9-AMINE
- Synonyms
- Tert-Butylamine-D9;tert-Butyl-d?-amine;TERT-BUTYL-D9-AMINE;2-Amino-2-Methyl-D3-P;[2H9]-tert-Butyl-amine;tert-Butyl-d9-amine DCl;2-AMINO-2-METHYL-D3-PROPANE-D6;TERT-BUTYL-D9-AMINE, 98 ATOM % D;tert-Butyl-d9-amine;2-Amino-2-methyl-Ds-propane-1,1,1,3,3,3-D6
- CBNumber
- CB9435654
- Molecular Formula
- C4H2D9N
- Formula Weight
- 82.19
- MOL File
- 6045-08-5.mol
TERT-BUTYL-D9-AMINE Property
- Melting point:
- -67 °C (lit.)
- Boiling point:
- 46 °C (lit.)
- Density
- 0.933 g/mL at 25 °C
- refractive index
- n20/D 1.401(lit.)
- Flash point:
- 16 °F
- storage temp.
- 0-6°C
- solubility
- Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
- form
- Oil
- color
- Colourless to Yellow
- Stability:
- Volatile
- InChI
- 1S/C4H11N/c1-4(2,3)5/h5H2,1-3H3/i1D3,2D3,3D3
- InChIKey
- YBRBMKDOPFTVDT-GQALSZNTSA-N
- SMILES
- [2H]C([2H])([2H])C(N)(C([2H])([2H])[2H])C([2H])([2H])[2H]
Safety
- Hazard Codes
- F,C
- Risk Statements
- 11-20/22-35
- Safety Statements
- 26-36/37/39-45
- RIDADR
- UN 3286 3/PG 2
- WGK Germany
- 3
- Storage Class
- 3 - Flammable liquids
- Hazard Classifications
- Acute Tox. 3 Inhalation
Acute Tox. 4 Oral
Aquatic Chronic 3
Eye Dam. 1
Flam. Liq. 2
Skin Corr. 1A
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 486353
- Product name
- tert-Butyl-d9-amine
- Purity
- 98 atom % D
- Packaging
- 5G
- Price
- $2330
- Updated
- 2025/07/31
- Product number
- 166729
- Product name
- tert-Butyl-d9-amine
- Packaging
- 100mg
- Price
- $425
- Updated
- 2021/12/16
- Product number
- B690777
- Product name
- tert-Butyl-d9-amine
- Packaging
- 1g
- Price
- $1485
- Updated
- 2021/12/16
- Product number
- RDL0014714
- Product name
- TERT-BUTYL-D9-AMINE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $496.58
- Updated
- 2021/12/16
- Product number
- D1161
- Product name
- Tert-butyl-d9-amine
- Packaging
- 0.5g
- Price
- $805
- Updated
- 2021/12/16
TERT-BUTYL-D9-AMINE Chemical Properties,Usage,Production
Chemical Properties
Clear Colourless Oil
Uses
tert-Butylamine is common reagent in pharmaceuticals syntheses. Used in the preparation of aminoBODIPY compounds for chemical analyses. Also it aids in the synthesis of benzylurea-based insecticides c ontaining amide and sulfonate groups. It has also been used in the synthesis of BPTES analogs, that act as glutaminase inhibitors, which can attenuate the growth of human lymphoma B cells. This is the labeled analog.
Synthesis
In a 100 mL flask with a thermometer and condenser tube, 3.607 g (0.1 mol) of methanol-D4 was added and cooled to 0 C. Under stirring conditions, 38.071 g (0.15 mol) of iodine, and an appropriate amount of red phosphorus were added slowly in batches, and at the end of the reaction, was obtained by distillation. of iodomethane-D3, and then use the above-prepared iodomethane-D3 to prepare into a format reagent, and slowly add 6.412 g of dropwise at 2 ??C (0.1 mol) acetone-D6, and the reaction was carried out at room temperature for 3 h. The reaction was quenched by dilute hydrochloric acid to obtain tert-butanol-D6. The obtained tert-butanol-D6 was distilled After purification, the reaction temperature was controlled at -10 ??, 7.722 g (0.15 mol) of iminium chloride was added dropwise to tert-butanol-D6 and the catalyst, and the dropwise was added. After the addition was completed, the reaction was continued for 2h, and the reaction solution was distilled to obtain 3.734g of tert-butylamine-D9 product, with a yield of by methanol-D4 45.4% in methanol-D4, the chromatographic purity was more than 99.0%, and the abundance of D isotope was 98.8atom%D by mass spectrometry.
TERT-BUTYL-D9-AMINE Preparation Products And Raw materials
Raw materials
Preparation Products
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