ChemicalBook > CAS DataBase List > Cyclopentadienylzirconium trichloride

Cyclopentadienylzirconium trichloride

Product Name
Cyclopentadienylzirconium trichloride
CAS No.
34767-44-7
Chemical Name
Cyclopentadienylzirconium trichloride
Synonyms
zirconium(IV) trichL;Cyclopentadienylzirkoniumtrichlorid;CYCLOPENTADIENYLZIRCONIUM TRICHLORIDE;TRICHLORO(CYCLOPENTADIENYL)ZIRCONIUM(IV);CYCLOPENTADIENYLZIRCONIUM TRICHLORIDE, 9;(Cyclopentadienyl)zircornium trichloride;CYCLOPENTADIENYLZIRCONIUM(IV) TRICHLORIDE;Cyclopentadienylzirconium trichloride, 98+%;Cyclopentadienylzirconiumtrichloride,min.98%;Cyclopentadienylzirconium(IV) Trichloride >
CBNumber
CB9446326
Molecular Formula
C5Cl3Zr
Formula Weight
257.63
MOL File
34767-44-7.mol
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Cyclopentadienylzirconium trichloride Property

Melting point:
210 °C (dec.)(lit.)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Powder
color 
off-white to tan
Water Solubility 
reacts
Sensitive 
Moisture Sensitive
CAS DataBase Reference
34767-44-7(CAS DataBase Reference)
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Safety

Hazard Codes 
C
Risk Statements 
34-29-20/21/22
Safety Statements 
26-27-36/37/39-45
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
HazardClass 
8
PackingGroup 
II
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
475203
Product name
Cyclopentadienylzirconium(IV) trichloride
Purity
97%
Packaging
1g
Price
$76.7
Updated
2024/03/01
TCI Chemical
Product number
C1995
Product name
Cyclopentadienylzirconium(IV) Trichloride
Purity
>96.0%(T)
Packaging
1g
Price
$55
Updated
2021/12/16
Alfa Aesar
Product number
020617
Product name
Cyclopentadienylzirconium trichloride, 98+%
Packaging
5g
Price
$260
Updated
2023/06/20
Alfa Aesar
Product number
020617
Product name
Cyclopentadienylzirconium trichloride, 98+%
Packaging
250mg
Price
$20.1
Updated
2021/12/16
Strem Chemicals
Product number
40-1100
Product name
Cyclopentadienylzirconium trichloride, min. 98%
Packaging
1g
Price
$62
Updated
2024/03/01
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Cyclopentadienylzirconium trichloride Chemical Properties,Usage,Production

Chemical Properties

white to light brown powder. Insoluble in most noncoordinating solvents; however, it becomes soluble in benzene or chloroform in the presence of two equiv of donor agents such as ether, THF, triethylamine, or pyridine.

Uses

Catalyst for:

  • Homo- and copolymerization reactions
  • Catalytic dehydrogenation of cyclooctane
  • Cross-coupling reaction of aryl fluorides with a phenethyl Grignard reagents

reaction suitability

core: zirconium
reagent type: catalyst

Synthesis

Trichloro(cyclopentadienyl)zirconium is prepared by the photoinduced chlorination of Dichlorobis(cyclopentadienyl)zirconium.

Cyclopentadienylzirconium trichloride Preparation Products And Raw materials

Raw materials

Preparation Products

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Cyclopentadienylzirconium trichloride Suppliers

Belgium 1 China 62 Germany 3 India 2 Japan 2 Russia 1 Switzerland 1 United Kingdom 3 United States 13 Global 88
Wako Pure Chemical Industries, Ltd.
Tel
--
Fax
--
Email
labchem-tec@wako-chem.co.jp
Country
Japan
ProdList
6819
Advantage
80
Kanto Chemical Co., Inc.
Tel
--
Fax
--
Email
reag-info@gms.kanto.co.jp
Country
Japan
ProdList
6756
Advantage
74

34767-44-7, Cyclopentadienylzirconium trichlorideRelated Search:

Tetramethylammonium chloride 1,3-Cyclopentadiene Benzyltrimethylammonium chloride Zirconyl chloride octahydrate Benzyltriethylammonium chloride METHYLCYCLOPENTADIENE DIMER rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride rac-Dimethylsilylbis(1-indenyl)zirconium dichloride (Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dimethyl (Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride Bis(1-butyl-3-methylcyclopentadienyl)zirconium dichloride Zirconium tetrachloride Zirconium Pentamethylcyclopentadienyl zirconium trichloride N-BUTYLCYCLOPENTADIENYLZIRCONIUM TRICHLORIDE 1,2,4-Trimethylcyclopentadienyl zirconium Trichloride (TETRAMETHYLCYCLOPENTADIENYL)ZIRCONIUM TRICHLORIDE Cyclopentadienylzirconium trichloride

  • CYCLOPENTADIENYLZIRCONIUM(IV) TRICHLORIDE
  • CYCLOPENTADIENYLZIRCONIUM TRICHLORIDE
  • TRICHLORO(CYCLOPENTADIENYL)ZIRCONIUM(IV)
  • Cyclopentadienylzirconium trichloride, 98+%
  • CYCLOPENTADIENYLZIRCONIUM TRICHLORIDE, 9
  • Cyclopentadienylzirkoniumtrichlorid
  • Cyclopentadienyl Zirconium Trichloride (CpZrCl3)
  • Cyclopentadienylzirconium trichloride, min. 98%
  • CyclopentadienylzirconiuM trichloride, 98% 1GR
  • Cyclopentadienylzirconiumtrichloride,min.98%
  • Trichloro(η5-2,4-cyclopentadien-1-yl)zirconium
  • (Cyclopentadienyl)zircornium trichloride
  • Cyclopentadienylzirconium(IV) Trichloride &gt
  • zirconium(IV) trichL
  • Cyclopentadienylzirconium trichloride ISO 9001：2015 REACH
  • 34767-44-7
  • C5H5ZrCl3
  • C5H5Cl3Zr
  • CpZrCl3
  • Catalysis and Inorganic Chemistry
  • Zirconium
  • Homogeneous Catalysts
  • Classes of Metal Compounds
  • Titanium Alkoxides, etc. (Homogeneous Catalysts)
  • Metallocenes
  • Half Metallocenes
  • Catalysts for Organic Synthesis
  • Transition Metal Compounds
  • Zr (Zirconium) Compounds
  • Zr
  • metallocene
  • Zr (Zirconium) Compounds
  • Catalysts for Organic Synthesis
  • Classes of Metal Compounds
  • Half Metallocenes
  • Homogeneous Catalysts
  • Metallocenes
  • Synthetic Organic Chemistry
  • Titanium Alkoxides, etc. (Homogeneous Catalysts)
  • Transition Metal Compounds
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Zirconium