TRI-TERT-BUTYL BORATE

Product Name: TRI-TERT-BUTYL BORATE
CAS No.: 7397-43-5
Chemical Name: TRI-TERT-BUTYL BORATE
Synonyms: BORON T-BUTOXIDE;ritert-butylborate;BORON TERT-BUTOXIDE;TRI-TERT-BUTOXYBORANE;TRI-TERT-BUTYL BORATE;Tri-tert-butyl borate 98%;Tri-tert-butyl borate,98%;boricacidtri-tert-butylester;Tri(1,1-dimethylethoxy)borane;Boric acid tri(1,1-dimethylethyl) ester
CBNumber: CB9457210
Molecular Formula: C12H27BO3
Formula Weight: 230.15
MOL File: 7397-43-5.mol

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TRI-TERT-BUTYL BORATE Property

Melting point:: 18-19 °C (lit.)
Boiling point:: 101 °C/74 mmHg (lit.)
Density: 0.811 g/mL at 25 °C (lit.)
refractive index: n20/D 1.389(lit.)
Flash point:: 85 °F
storage temp.: Flammables area
form: Liquid
Specific Gravity: 0.811
color: Colorless
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water

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Safety

Risk Statements: 10
Safety Statements: 16-33
RIDADR: UN 1993 3/PG 3
WGK Germany: 3
TSCA: No
HazardClass: 3.2
PackingGroup: III

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H226Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 236608
Product name: Tri-tert-butyl borate
Purity: 98%
Packaging: 50g
Price: $90
Updated: 2024/03/01

Alfa Aesar

Product number: H55461
Product name: Tri-tert-butyl borate
Purity: 97%
Packaging: 5g
Price: $57.65
Updated: 2024/03/01

Alfa Aesar

Product number: H55461
Product name: Tri-tert-butyl borate
Purity: 97%
Packaging: 25g
Price: $216.65
Updated: 2024/03/01

TRC

Product number: T795298
Product name: tris(Oxo[(oxoboranyl)oxy]borane)bis(tris(Propan-2-yloxy)borane)
Packaging: 500mg
Price: $90
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: ING0006878
Product name: TRI-TERT-BUTYL BORATE
Purity: 95.00%
Packaging: 50G
Price: $2583.16
Updated: 2021/12/16

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TRI-TERT-BUTYL BORATE Chemical Properties,Usage,Production

Chemical Properties

CLEAR COLOURLESS LIQUID

Uses

Tri-tert-butyl borate can be used as:

An additive in the synthesis of chiral α-hydroxy esters by reacting dimethylzinc with α-ketoesters using (?)-2-exo-morpholinoisobornane-10-thiol.
A starting material in the synthesis of boronate of (+)-pinane-2,3-diol.

Synthesis Reference(s)

The Journal of Organic Chemistry, 43, p. 2731, 1978 DOI: 10.1021/jo00407a051

General Description

Tri-tert-butyl borate is an organoborate commonly used to prepare other borate esters. It is also used as a substrate in Rh-catalyzed carbonylation reactions.

TRI-TERT-BUTYL BORATE Preparation Products And Raw materials

Raw materials

Preparation Products

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TRI-TERT-BUTYL BORATE Suppliers

Belgium 1 China 24 Germany 2 India 1 Russia 1 Singapore 1 Switzerland 1 United Kingdom 3 United States 8 Global 42

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7397-43-5, TRI-TERT-BUTYL BORATERelated Search:

Orthoboric acid TRI-TERT-BUTYL BORATE Triisopropyl borate 2-METHYL-2,4-PENTANEDIOL DIBORATE Trimethyl borate Triethyl borate

Tri(1,1-dimethylethoxy)borane

Tri-tert-butyl borate,98%

Tri-tert-butyl borate,Boron tert-butoxide, Tri-tert-butoxyborane

Tri-tert-butyl borate 98%

Boric acid,tris(1,1-dimethylethyl) ester

boricacidtri-tert-butylester

BORON T-BUTOXIDE

TRI-TERT-BUTYL BORATE

TRI-TERT-BUTOXYBORANE

BORON TERT-BUTOXIDE

Boron tert-butoxide, Tri-tert-butoxyborane

Boric acid tri(1,1-dimethylethyl) ester

ritert-butylborate

tris(Oxo[(oxoboranyl)oxy]borane) bis(tris(Propan-2-yloxy)borane)

7397-43-5

CH33CO3B

Organoborates

Organometallic Reagents

Boronic Acids and Derivatives