ChemicalBook > CAS DataBase List > TRI-TERT-BUTYL BORATE

TRI-TERT-BUTYL BORATE

Product Name
TRI-TERT-BUTYL BORATE
CAS No.
7397-43-5
Chemical Name
TRI-TERT-BUTYL BORATE
Synonyms
BORON T-BUTOXIDE;ritert-butylborate;BORON TERT-BUTOXIDE;TRI-TERT-BUTOXYBORANE;TRI-TERT-BUTYL BORATE;Tri-tert-butyl borate 98%;Tri-tert-butyl borate,98%;boricacidtri-tert-butylester;Tri(1,1-dimethylethoxy)borane;Boric acid tri(1,1-dimethylethyl) ester
CBNumber
CB9457210
Molecular Formula
C12H27BO3
Formula Weight
230.15
MOL File
7397-43-5.mol
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TRI-TERT-BUTYL BORATE Property

Melting point:
18-19 °C (lit.)
Boiling point:
101 °C/74 mmHg (lit.)
Density 
0.811 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.389(lit.)
Flash point:
85 °F
storage temp. 
Flammables area
form 
Liquid
Specific Gravity
0.811
color 
Colorless
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
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Safety

Risk Statements 
10
Safety Statements 
16-33
RIDADR 
UN 1993 3/PG 3
WGK Germany 
3
TSCA 
No
HazardClass 
3.2
PackingGroup 
III
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
236608
Product name
Tri-tert-butyl borate
Purity
98%
Packaging
50g
Price
$90
Updated
2024/03/01
Alfa Aesar
Product number
H55461
Product name
Tri-tert-butyl borate
Purity
97%
Packaging
5g
Price
$57.65
Updated
2024/03/01
Alfa Aesar
Product number
H55461
Product name
Tri-tert-butyl borate
Purity
97%
Packaging
25g
Price
$216.65
Updated
2024/03/01
TRC
Product number
T795298
Product name
tris(Oxo[(oxoboranyl)oxy]borane)bis(tris(Propan-2-yloxy)borane)
Packaging
500mg
Price
$90
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ING0006878
Product name
TRI-TERT-BUTYL BORATE
Purity
95.00%
Packaging
50G
Price
$2583.16
Updated
2021/12/16
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TRI-TERT-BUTYL BORATE Chemical Properties,Usage,Production

Chemical Properties

CLEAR COLOURLESS LIQUID

Uses

Tri-tert-butyl borate can be used as:

  • An additive in the synthesis of chiral α-hydroxy esters by reacting dimethylzinc with α-ketoesters using (?)-2-exo-morpholinoisobornane-10-thiol.
  • A starting material in the synthesis of boronate of (+)-pinane-2,3-diol.

Synthesis Reference(s)

The Journal of Organic Chemistry, 43, p. 2731, 1978 DOI: 10.1021/jo00407a051

General Description

Tri-tert-butyl borate is an organoborate commonly used to prepare other borate esters. It is also used as a substrate in Rh-catalyzed carbonylation reactions.

TRI-TERT-BUTYL BORATE Preparation Products And Raw materials

Raw materials

Preparation Products

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TRI-TERT-BUTYL BORATE Suppliers

Meryer (Shanghai) Chemical Technology Co., Ltd.
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021-61259108 18621169109
Fax
86-21-61259102
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market03@meryer.com
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China
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Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
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China
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30132
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84
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Shanghai Shenyue Chemical Co., Ltd.
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021-021-52212593 15300879511
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+86 (21) 51062076
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China
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Shanghai Balmxy Pharmaceutical Co., Ltd
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Sigma-Aldrich
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orderCN@merckgroup.com
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Aikon International Limited
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(7)02557626880
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Dayang Chem (Hangzhou) Co.,Ltd.
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Energy Chemical
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Shanghai Guchen Biotechnology Co., LTD
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Zibo Run Hang Seng material Technology Co., LTD
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GIHI CHEMICALS CO.,LIMITED
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Shanghai Haosu Chemistry & Technology Inc
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7397-43-5, TRI-TERT-BUTYL BORATERelated Search:


  • Tri(1,1-dimethylethoxy)borane
  • Tri-tert-butyl borate,98%
  • Tri-tert-butyl borate,Boron tert-butoxide, Tri-tert-butoxyborane
  • Tri-tert-butyl borate 98%
  • Boric acid,tris(1,1-dimethylethyl) ester
  • boricacidtri-tert-butylester
  • BORON T-BUTOXIDE
  • TRI-TERT-BUTYL BORATE
  • TRI-TERT-BUTOXYBORANE
  • BORON TERT-BUTOXIDE
  • Boron tert-butoxide, Tri-tert-butoxyborane
  • Boric acid tri(1,1-dimethylethyl) ester
  • ritert-butylborate
  • tris(Oxo[(oxoboranyl)oxy]borane) bis(tris(Propan-2-yloxy)borane)
  • 7397-43-5
  • CH33CO3B
  • Organoborates
  • Organometallic Reagents
  • Boronic Acids and Derivatives