ChemicalBook > CAS DataBase List > Bis[alpha,alpha-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur

Bis[alpha,alpha-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur

Product Name
Bis[alpha,alpha-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur
CAS No.
32133-82-7
Chemical Name
Bis[alpha,alpha-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur
Synonyms
MARTIN SULFURANE;MARTIN SULFURANE DEHYDRATING AGENT;bis[α,α-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur;Bis[αMAR SULFU(MARTIN SULFURANE);Bis[α,α-bis(trifluoromethyl)b;MARTIN SULFURANE DEHYDRATING AGENT, TECH .;Martin Sulfurane Dehydrating agent technical grade;-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur;Bis[bis(trifluoromet?hyl)?phenylmethoxy]?diphenylsulfurane
CBNumber
CB9483039
Molecular Formula
C30H20F12O2S
Formula Weight
672.52
MOL File
32133-82-7.mol
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Bis[alpha,alpha-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur Property

Melting point:
106-108 °C(lit.)
Density 
1.32±0.1 g/cm3(Predicted)
storage temp. 
Freezer
solubility 
soluble in Methanol
form 
powder to crystal
color 
White to Orange to Green
BRN 
1416879
Stability:
Extremely Moisture Sensitive
InChIKey
RMIBJVUYNZSLSD-UHFFFAOYSA-N
SMILES
S(C1=CC=CC=C1)(C1=CC=CC=C1)(OC(C(F)(F)F)(C(F)(F)F)C1=CC=CC=C1)OC(C(F)(F)F)(C(F)(F)F)C1=CC=CC=C1
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3261 8/PG 3
WGK Germany 
3
10-21
HazardClass 
8
PackingGroup 
II
HS Code 
29309090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
428841
Product name
Martin Sulfurane Dehydrating agent
Purity
technical grade
Packaging
1g
Price
$136
Updated
2024/03/01
Sigma-Aldrich
Product number
428841
Product name
Martin Sulfurane Dehydrating agent
Purity
technical grade
Packaging
5g
Price
$307
Updated
2024/03/01
TCI Chemical
Product number
B2200
Product name
Bis[α,α-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur
Purity
>96.0%(T)
Packaging
1g
Price
$120
Updated
2024/03/01
TCI Chemical
Product number
B2200
Product name
Bis[α,α-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur
Purity
>96.0%(T)
Packaging
5g
Price
$340
Updated
2024/03/01
TRC
Product number
B585828
Product name
Bis[α,α-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur
Packaging
50mg
Price
$45
Updated
2021/12/16
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Bis[alpha,alpha-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur Chemical Properties,Usage,Production

Chemical Properties

IUPAC Name: [2-({diphenyl[(1,1,1,3,3,3-hexafluoro-2-phenylpropan-2-yl)oxy]-λ?-sulfanyl}oxy)-1,1,1,3,3,3-hexafluoropropan-2-yl]benzene

Uses

Versatile dehydrating and oxidizing agent. For chemistry and references, see Aldrichimica Acta .

Preparation

Bis[alpha,alpha-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur can be prepared by the reaction of the potassium salt of 1,1,1,3,3,3-hexafluoro-2-phenylisopropanol with diphenyl sulfide in the presence of chlorine in ether at -78 °C.

storage

avoid moisture; readily hydrolyzed; stable at rt; decomposes slowly at rt in solution.

Bis[alpha,alpha-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur Preparation Products And Raw materials

Raw materials

Preparation Products

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Bis[alpha,alpha-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur Suppliers

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32133-82-7, Bis[alpha,alpha-bis(trifluoromethyl)benzenemethanolato]diphenylsulfurRelated Search:


  • Bis[a,a-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur
  • Bis[α,α-bis(trifluoromethyl)b
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  • MAR SULFU(MARTIN SULFURANE)
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  • Bis[alpha,alpa-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur
  • 32133-82-7
  • C6H5CCF32O2SC6H52
  • C30H20F12O2S
  • Dehydrating Reagents
  • Synthetic Reagents