Bis[alpha,alpha-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur
- Product Name
- Bis[alpha,alpha-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur
- CAS No.
- 32133-82-7
- Chemical Name
- Bis[alpha,alpha-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur
- Synonyms
- MARTIN SULFURANE;MARTIN SULFURANE DEHYDRATING AGENT;bis[α,α-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur;Bis[αMAR SULFU(MARTIN SULFURANE);Bis[α,α-bis(trifluoromethyl)b;MARTIN SULFURANE DEHYDRATING AGENT, TECH .;Martin Sulfurane Dehydrating agent technical grade;-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur;Bis[bis(trifluoromet?hyl)?phenylmethoxy]?diphenylsulfurane
- CBNumber
- CB9483039
- Molecular Formula
- C30H20F12O2S
- Formula Weight
- 672.52
- MOL File
- 32133-82-7.mol
Bis[alpha,alpha-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur Property
- Melting point:
- 106-108 °C(lit.)
- Density
- 1.32±0.1 g/cm3(Predicted)
- storage temp.
- Freezer
- solubility
- soluble in Methanol
- form
- powder to crystal
- color
- White to Orange to Green
- BRN
- 1416879
- Stability:
- Extremely Moisture Sensitive
- InChIKey
- RMIBJVUYNZSLSD-UHFFFAOYSA-N
- SMILES
- S(C1=CC=CC=C1)(C1=CC=CC=C1)(OC(C(F)(F)F)(C(F)(F)F)C1=CC=CC=C1)OC(C(F)(F)F)(C(F)(F)F)C1=CC=CC=C1
Safety
- Hazard Codes
- C
- Risk Statements
- 34
- Safety Statements
- 26-36/37/39-45
- RIDADR
- UN 3261 8/PG 3
- WGK Germany
- 3
- F
- 10-21
- HazardClass
- 8
- PackingGroup
- II
- HS Code
- 29309090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P363Wash contaminated clothing before reuse.
N-Bromosuccinimide Price
- Product number
- 428841
- Product name
- Martin Sulfurane Dehydrating agent
- Purity
- technical grade
- Packaging
- 1g
- Price
- $136
- Updated
- 2024/03/01
- Product number
- 428841
- Product name
- Martin Sulfurane Dehydrating agent
- Purity
- technical grade
- Packaging
- 5g
- Price
- $307
- Updated
- 2024/03/01
- Product number
- B2200
- Product name
- Bis[α,α-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur
- Purity
- >96.0%(T)
- Packaging
- 1g
- Price
- $120
- Updated
- 2024/03/01
- Product number
- B2200
- Product name
- Bis[α,α-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur
- Purity
- >96.0%(T)
- Packaging
- 5g
- Price
- $340
- Updated
- 2024/03/01
- Product number
- B585828
- Product name
- Bis[α,α-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur
- Packaging
- 50mg
- Price
- $45
- Updated
- 2021/12/16
Bis[alpha,alpha-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur Chemical Properties,Usage,Production
Chemical Properties
IUPAC Name: [2-({diphenyl[(1,1,1,3,3,3-hexafluoro-2-phenylpropan-2-yl)oxy]-λ?-sulfanyl}oxy)-1,1,1,3,3,3-hexafluoropropan-2-yl]benzene
Uses
Versatile dehydrating and oxidizing agent. For chemistry and references, see Aldrichimica Acta .
Preparation
Bis[alpha,alpha-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur can be prepared by the reaction of the potassium salt of 1,1,1,3,3,3-hexafluoro-2-phenylisopropanol with diphenyl sulfide in the presence of chlorine in ether at -78 °C.
storage
avoid moisture; readily hydrolyzed; stable at rt; decomposes slowly at rt in solution.
Bis[alpha,alpha-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur Preparation Products And Raw materials
Raw materials
Preparation Products
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