2-(2'-DI-TERT-BUTYLPHOSPHINE)BIPHENYLPA&
Uses- Product Name
- 2-(2'-DI-TERT-BUTYLPHOSPHINE)BIPHENYLPA&
- CAS No.
- 577971-19-8
- Chemical Name
- 2-(2'-DI-TERT-BUTYLPHOSPHINE)BIPHENYLPA&
- Synonyms
- phosphine)biphenyL;2-(2′-Di-tert-butyL;2-(2'-DI-TERT-BUTYLPHOSPHINE)BIPHENYLPA&;2-(2'-Di-tert-butylphosphine)biphenylpalladium(II) acetate;acetoxy-[2-(2-ditert-butylphosphanylphenyl)phenyl]palladium;acetic acid,ditert-butyl-(2-phenylphenyl)phosphane,palladium ;2-(2′-Di-tert-butylphosphine)biphenylpalladium(II) acetate 97%;2-(2′-Di-tert-butylphosphine)biphenylpalladium(II) acetate;Acetoxy[2’-(di-tert-butylphosphino)-[1,1’-biphenyl]-2-yl]palladium;Acetato(2'-di-t-butylphosphino-1,1'-biphenyl-2-yl)palladium(II),97%
- CBNumber
- CB9498916
- Molecular Formula
- C22H29O2PPd
- Formula Weight
- 462.863
- MOL File
- 577971-19-8.mol
2-(2'-DI-TERT-BUTYLPHOSPHINE)BIPHENYLPA& Property
- Melting point:
- 130-140 °C (dec.) (lit.)
- storage temp.
- 2-8°C, protect from light, stored under nitrogen
- form
- Powder
- color
- off-white
- InChI
- InChI=1S/C20H26P.C2H4O2.Pd/c1-19(2,3)21(20(4,5)6)18-15-11-10-14-17(18)16-12-8-7-9-13-16;1-2(3)4;/h7-12,14-15H,1-6H3;1H3,(H,3,4);/q;;+1/p-1
- InChIKey
- IEYDYAASBZOBOC-UHFFFAOYSA-M
- SMILES
- C1(=CC=CC=C1C1C=CC=CC=1[Pd]OC(C)=O)P(C(C)(C)C)C(C)(C)C
Safety
- WGK Germany
- 3
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 655414
- Product name
- 2-(2′-Di-tert-butylphosphine)biphenylpalladium(II) acetate
- Purity
- 97%
- Packaging
- 1g
- Price
- $148
- Updated
- 2023/06/20
- Product number
- 46-0025
- Product name
- Acetato(2'-di-t-butylphosphino-1,1'-biphenyl-2-yl)palladium(II), min. 98%
- Packaging
- 250mg
- Price
- $52
- Updated
- 2024/03/01
- Product number
- 46-0025
- Product name
- Acetato(2'-di-t-butylphosphino-1,1'-biphenyl-2-yl)palladium(II), min. 98%
- Packaging
- 1g
- Price
- $144
- Updated
- 2024/03/01
- Product number
- D429470
- Product name
- 2-(2′-Di-tert-butylphosphine)biphenylpalladium(II) acetate
- Packaging
- 1g
- Price
- $495
- Updated
- 2021/12/16
- Product number
- OGM0001639
- Product name
- 2-(2'-DI-TERT-BUTYLPHOSPHINE)BIPHENYLPALLADIUM(II) ACETATE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $495.35
- Updated
- 2021/12/16
2-(2'-DI-TERT-BUTYLPHOSPHINE)BIPHENYLPA& Chemical Properties,Usage,Production
Uses
Air and thermally stable, one-component precatalyst for the amination of aryl halides.
Uses
2-(2′-Di-tert-butylphosphine)biphenylpalladium(II) Acetate is a precatalyst for Buchwald-Hartwig amination reaction. It is also used to prepare anticancer LPA2 antagonists.
Uses
It can be used as a pre-catalyst for the amination of aryl chlorides. It can also be used to prepare N-methyl-6-heterocyclic-1-oxoisoindoline derivatives via Buchwald-Hartwig amination reaction of N-methyl-6- bromoisoindoline-1-one with different amines under microwave condition.
General Description
2-(2′-Di-tert-butylphosphine)biphenylpalladium(II) acetate is a novel, air- and moisture-and thermally stable catalyst.
reaction suitability
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
2-(2'-DI-TERT-BUTYLPHOSPHINE)BIPHENYLPA& Preparation Products And Raw materials
Raw materials
Preparation Products
2-(2'-DI-TERT-BUTYLPHOSPHINE)BIPHENYLPA& Suppliers
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View Lastest Price from 2-(2'-DI-TERT-BUTYLPHOSPHINE)BIPHENYLPA& manufacturers
- Product
- 2-(2'-Di-tert-butylphosphine)biphenylpalladium(II) acetate 577971-19-8
- Price
- US $20.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10000KG
- Release date
- 2020-11-11