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Perfluoro-2-methyl-2-pentene

Product Name
Perfluoro-2-methyl-2-pentene
CAS No.
1584-03-8
Chemical Name
Perfluoro-2-methyl-2-pentene
Synonyms
-2-pentene), 97%;Hexafluoropropene dimer;Perfluoro-2-methyl-2-penten;Perfluoro-2-methyl-2-pentene;-Methylpent-2-ene, perfluoro-;2-Methylpent-2-ene, perfluoro-;Dodecafluoro-2-methyl-2-pentene;PERFLUORO-2-METHYL-2-PENTENE 98;Perfluoro(2-methylpent-2-ene)90%;2-(Trifluoromethyl)perfluoro-2-pentene
CBNumber
CB9499175
Molecular Formula
C6F12
Formula Weight
300.05
MOL File
1584-03-8.mol
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Perfluoro-2-methyl-2-pentene Property

Melting point:
48-50 °C
Boiling point:
53-61 °C(lit.)
Density 
1.622 g/mL at 25 °C(lit.)
vapor pressure 
4.31 psi ( 20 °C)
Flash point:
10 °F
refractive index 
ca. 1.3
storage temp. 
Flammables area
form 
Liquid
Specific Gravity
1.62
color 
Clear colorless to light yellow
Water Solubility 
insoluble
InChI
InChI=1S/C6F12/c7-2(3(8,9)6(16,17)18)1(4(10,11)12)5(13,14)15
InChIKey
FAEGGADNHFKDQX-UHFFFAOYSA-N
SMILES
C(F)(F)(F)/C(/C(F)(F)F)=C(\F)/C(F)(F)C(F)(F)F
CAS DataBase Reference
1584-03-8(CAS DataBase Reference)
NIST Chemistry Reference
Perfluoro-2-methyl-2-pentene(1584-03-8)
EPA Substance Registry System
Perfluoro(2-methylpent-2-ene) (1584-03-8)
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Safety

Hazard Codes 
F,Xi
Risk Statements 
11
Safety Statements 
16-29-33
RIDADR 
UN 1993 3/PG 2
WGK Germany 
3
Hazard Note 
Irritant
HazardClass 
3
PackingGroup 
II
HS Code 
29033990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H225Highly Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

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N-Bromosuccinimide Price

Alfa Aesar
Product number
A18394
Product name
Perfluoro(2-methyl-2-pentene), 97%
Packaging
5g
Price
$83.65
Updated
2024/03/01
Alfa Aesar
Product number
A18394
Product name
Perfluoro(2-methyl-2-pentene), 97%
Packaging
25g
Price
$319.65
Updated
2024/03/01
Alfa Aesar
Product number
A18394
Product name
Perfluoro(2-methyl-2-pentene)
Purity
97%
Packaging
1g
Price
$30.7
Updated
2021/12/16
Usbiological
Product number
451847
Product name
Hexafluoropropene Dimer
Packaging
5g
Price
$355
Updated
2021/12/16
TRC
Product number
P999460
Product name
Perfluoro(2-methyl-2-pentene)
Packaging
50mg
Price
$45
Updated
2021/12/16
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Perfluoro-2-methyl-2-pentene Chemical Properties,Usage,Production

Chemical Properties

clear colourless to light yellow liquid

Uses

Hexafluoropropene Dimer is used in the production of waterproof and oilproof Si/F-modified polyurethane finishing agent for textile and leather. Hexafluoropropene Dimer is also used as a blowing agent for manufacture of polyurethane foams.

Reactions

Perfluoro-2-methyl-2-pentene reacts withα-oxides in the presence of CsF, like perfluoro isobutylene. Olefins containing a perfluoro(dimethylpropyl)methyl group and cesium perfluoro-2-methyl-penten-3-olate are formed.
The reaction of this compound with epichlorohydrin in the presence of CSP results in the formation of trans-1,1,1,7,7,8,8,9,9,9-decafluoro-2,6,6-tris(trifluoromethyl)-4-nonene, 2-fluoro-2-pentafluoroethyl-3,3-bis(trifluoromethyl)-5-[α,α-(hydro-β,β-bis(trifluoromethyl)perfluoroamyl] tetrahydrofuran, and 2-H-perfluoro-2-methylpentane.
The hexafluoropropylene dimer perfluoro-2-methyl-2-pentene is partially converted under the action of CsF into the thermodynamically most stable hexafluoropropylene trimer perfluoro-2,4-dimiethyl-3-heptene[1].
It reacts with alcohols to give either fluorine substitution products or addition products, depending on the amount of essential catalyst used. Alcohols containing branched substituents give another product in addition to those derived from the substitution of a vinyl fluorine atom in perfluoro-2-methyl-2-pentene, namely isomeric vinyl ethers, which are derivatives of perfluoro-2-methyl-1-pentene[2].

References

[1] L. L. Gervits, I. L. Knunyants, K. N. Makarov. “Reaction of perfluoro-2-methyl-2-pentene and perfluoroisobutylene with α-oxides in the presence of cesium fluoride.” Russian Chemical Bulletin 30 5 (1981): 846–852.
[2] V. F. Snegirev, K. N. Makarov. “Reaction of perfluoro-2-methylpent-2-ene with oxygen nucleophiles.” Russian Chemical Bulletin 35 1 (1986): 91–103.

Perfluoro-2-methyl-2-pentene Preparation Products And Raw materials

Raw materials

Preparation Products

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Perfluoro-2-methyl-2-pentene Suppliers

Changzhou Sifluoro Chemical Co.,Ltd
Tel
13275212658
Email
sales@neofluoride.com
Country
China
ProdList
2043
Advantage
58
Hubei Guangao Biotechnology Co., Ltd
Tel
027-027-59223056 18162699093
Fax
027-59223056
Email
1208480011@qq.com
Country
China
ProdList
9924
Advantage
58
Xi'an duokai Trading Co., Ltd
Tel
029-82283472 15091869467
Email
1055507341@qq.com
Country
China
ProdList
30
Advantage
58
Shandong Binchen Chemical Co.,Ltd
Tel
18351216136 18338758121;18351216281
Email
3846935277@qq.com
Country
China
ProdList
926
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Wuhan Chemwish Technology Co., Ltd
Tel
86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35896
Advantage
56
Shanghai Sinch Parmaceuticals Tech. Co. Ltd.
Tel
+86-21-54098501
Fax
+86-21-54096319
Email
sales@sinch.com.cn
Country
China
ProdList
11598
Advantage
64
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View Lastest Price from Perfluoro-2-methyl-2-pentene manufacturers

Shanghai UCHEM Inc.
Product
Perfluoro-2-methyl-2-pentene 1584-03-8
Price
US $105.00-373.00/kg
Min. Order
1kg
Purity
0.98
Supply Ability
25kg
Release date
2023-11-14
Henan Fengda Chemical Co., Ltd
Product
Perfluoro-2-methyl-2-pentene 1584-03-8
Price
US $35.00-1.20/kg
Min. Order
1kg
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-03-28

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