ChemicalBook > CAS DataBase List > DICHLORO[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]NICKEL(II)
DICHLORO[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]NICKEL(II)
- Product Name
- DICHLORO[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]NICKEL(II)
- CAS No.
- 18750-53-3
- Chemical Name
- DICHLORO[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]NICKEL(II)
- Synonyms
- DICHLORO[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]NICKEL(II)
- CBNumber
- CB9663107
- Molecular Formula
- C28H30Cl2NiP2
- Formula Weight
- 558.09
- MOL File
- Mol file
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DICHLORO[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]NICKEL(II) Property
- solubility
- sol benzene
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DICHLORO[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]NICKEL(II) Chemical Properties,Usage,Production
Uses
Dichloro[1,4-bis(diphenylphosphino)butane]nickel(II) is used as a catalyst for allylic alkylation of stable enolates, dialkylation of dithioacetals and electrochemical carboxylation of terminal alkynes.
Preparation
Dichloro[1,4-bis(diphenylphosphino)butane]nickel(II) is prepared by adding a solution of NiCl2.6H2O in n-butanol to a solution of 1,4- bis(diphenylphosphino)butane (dppb) in n-butanol and refluxing until the complex drops out of solution as a light purple powder.
storage
Dichloro[1,4-bis(diphenylphosphino)butane]nickel(II) should be stored in dry, dark-colored bottles under an inert atmosphere.
DICHLORO[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]NICKEL(II) Preparation Products And Raw materials
Raw materials
Preparation Products
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