TETRAHYDROFURAN-D8
- Product Name
- TETRAHYDROFURAN-D8
- CAS No.
- 1693-74-9
- Chemical Name
- TETRAHYDROFURAN-D8
- Synonyms
- THF-D8;Tetrahydrofuran-d;d8-tetrahydrofuran;Tetrahydrofuran-D8,for NMR,99.5 atom % D;TETRAHYDROFURAN-D8;(2H8)Tetrahydrofuran;Tetrahydro(2H8)furan;TetrahydrofuranD8>99.5%;Furan-d4, tetrahydro-d4-;Perdeuterotetrahydrofuran
- CBNumber
- CB9695988
- Molecular Formula
- C4D8O
- Formula Weight
- 80.16
- MOL File
- 1693-74-9.mol
TETRAHYDROFURAN-D8 Property
- Melting point:
- −106 °C(lit.)
- Melting point:
- -108,5°C
- Boiling point:
- 66°C
- Boiling point:
- 65-66 °C(lit.)
- Density
- 0.985 g/mL at 25 °C(lit.)
- Density
- d = 0,99
- refractive index
- n20/D 1.403(lit.)
- Flash point:
- 1 °F
- storage temp.
- 2-8°C
- solubility
- Chloroform (Slightly), Methanol (Slightly)
- form
- Liquid
- color
- Colorless
- Specific Gravity
- 0.99
- Water Solubility
- Soluble in water.
- BRN
- 111854
- Henry's Law Constant
- 2.3×10-1 mol/(m3Pa) at 25℃, Hiatt (2013)
- Stability:
- Stable. Incompatible with strong oxidizing agents, strong reducing agents, strong bases, oxygen. May generate peroxides in storage if in contact with air. Highly flammable. Store under nitrogen. Hazardous polymerisation may occur.
- InChI
- 1S/C4H8O/c1-2-4-5-3-1/h1-4H2/i1D2,2D2,3D2,4D2
- InChIKey
- WYURNTSHIVDZCO-SVYQBANQSA-N
- SMILES
- [2H]C1([2H])OC([2H])([2H])C([2H])([2H])C1([2H])[2H]
- CAS DataBase Reference
- 1693-74-9(CAS DataBase Reference)
- EPA Substance Registry System
- Furan-2,3,4,5-d4, tetrahydro-d4- (1693-74-9)
Safety
- Hazard Codes
- F,Xn,Xi
- Risk Statements
- 11-19-36/37-40
- Safety Statements
- 16-29-33-46-37-36-13-36/37
- RIDADR
- UN 2056 3/PG 2
- WGK Germany
- 3
- RTECS
- LU5950000
- Autoignition Temperature
- 215 °C
- HS Code
- 2845 90 10
- HazardClass
- 3
- PackingGroup
- II
- Storage Class
- 3 - Flammable liquids
- Hazard Classifications
- Acute Tox. 4 Oral
Carc. 2
Eye Irrit. 2
Flam. Liq. 2
STOT SE 3 - Toxicity
- LD50 orally in Rabbit: 1650 mg/kg
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H319Causes serious eye irritation
H335May cause respiratory irritation
H351Suspected of causing cancer
- Precautionary statements
-
P201Obtain special instructions before use.
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313IF exposed or concerned: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- 441406
- Product name
- Tetrahydrofuran-d8
- Purity
- ≥99.5 atom % D
- Packaging
- 5x0.5mL
- Price
- $280
- Updated
- 2026/03/19
- Product number
- 441406
- Product name
- Tetrahydrofuran-d8
- Purity
- ≥99.5 atom % D
- Packaging
- 10x0.75mL
- Price
- $541
- Updated
- 2026/03/19
- Product number
- 441406
- Product name
- Tetrahydrofuran-d8
- Purity
- ≥99.5 atom % D
- Packaging
- 10x1mL
- Price
- $705
- Updated
- 2026/03/19
- Product number
- 184314
- Product name
- Tetrahydrofuran-d8
- Purity
- ≥99.5 atom % D
- Packaging
- 1g
- Price
- $94.4
- Updated
- 2026/03/19
- Product number
- 184314
- Product name
- Tetrahydrofuran-d8
- Purity
- ≥99.5 atom % D
- Packaging
- 5g
- Price
- $350
- Updated
- 2026/03/19
TETRAHYDROFURAN-D8 Chemical Properties,Usage,Production
Chemical Properties
colourless liquid with an ether-like odour
Uses
Tetrahydrofuran-d_8 is a deuterated THF that is used in various synthesis reactions and also used as a precursor for various polymers.
Definition
ChEBI: Oxolane-d8 is a deuterated compound, a cyclic ether, a member of oxolanes, a saturated organic heteromonocyclic parent and a volatile organic compound.
General Description
Tetrahydrofuran-d8 may be used as a solvent in the synthesis of deuteriotris[bis(trimethylsilyl)amido]thorium and deuteriotris[bis(trimethylsiiyl)amido]uranium.
Synthesis
Tetrahydrofuran-d8 was prepared from the exchange of tetrahydrofuran with heavy water catalyzed by a transition metal: a CD3OD mixture of tetrahydrofuran (0.22 mmol) and pyrene-imidazolylidene-iridium(III) complex (2 mol% based on the metal) was heated in a Schlenk tube equipped with a Teflon cap at 100C. AgOTf (8.8 10-3 mmol) was added to the solution. After 12 h, a 50-L aliquot was withdrawn from the reaction vessel. An aliquot was added to an NMR tube containing 0.6 mL of CDCl3. Highly substituted tetrahydrofuran-d8 was obtained using a standard capillary consisting of a solution of ferrocene in CDCl3 (0.025 mg L-1) and the deuteration level was monitored by 1H NMR.
TETRAHYDROFURAN-D8 Preparation Products And Raw materials
Raw materials
Preparation Products
TETRAHYDROFURAN-D8 Suppliers
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View Lastest Price from TETRAHYDROFURAN-D8 manufacturers
- Product
- TETRAHYDROFURAN-D8 1693-74-9
- Price
- US $2.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- ask
- Release date
- 2018-12-19