ChemicalBook > CAS DataBase List > 2,5-Dichlorobenzophenone

2,5-Dichlorobenzophenone

Product Name
2,5-Dichlorobenzophenone
CAS No.
16611-67-9
Chemical Name
2,5-Dichlorobenzophenone
Synonyms
2,5-Dichlorobenzophe;2,5-DICHLOROBENZOPHENONE;2,5-Dichlorobenzophenone 98%;2,5-Dichlorophenylphenyl ketone;Methanone, (2,5-dichlorophenyl)phenyl-;(2,5-Dichlorophenyl)-(phenyl)methanone
CBNumber
CB9699315
Molecular Formula
C13H8Cl2O
Formula Weight
251.11
MOL File
16611-67-9.mol
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2,5-Dichlorobenzophenone Property

Melting point:
87-88°C
Boiling point:
240-260 °C
Density 
1.311±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
form 
crystals
color 
Off-white to brown
CAS DataBase Reference
16611-67-9(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
Hazard Note 
Harmful
HazardClass 
IRRITANT
HS Code 
2914790090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P330Rinse mouth.

P363Wash contaminated clothing before reuse.

P403Store in a well-ventilated place.

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N-Bromosuccinimide Price

TRC
Product number
D438425
Product name
2,5-Dichlorobenzophenone
Packaging
250mg
Price
$45
Updated
2021/12/16
Matrix Scientific
Product number
005212
Product name
2,5-Dichlorobenzophenone
Purity
98%
Packaging
5g
Price
$24
Updated
2021/12/16
SynQuest Laboratories
Product number
2617-5-Z3
Product name
2,5-Dichlorobenzophenone
Purity
98%
Packaging
5G
Price
$28
Updated
2021/12/16
Apolloscientific
Product number
OR3586
Product name
2,5-Dichlorobenzophenone
Purity
98%
Packaging
5g
Price
$16
Updated
2021/12/16
Apolloscientific
Product number
OR3586
Product name
2,5-Dichlorobenzophenone
Purity
98%
Packaging
25g
Price
$58
Updated
2021/12/16
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2,5-Dichlorobenzophenone Chemical Properties,Usage,Production

Uses

2,5-Dichlorobenzophenones can be used as starting materials for general, pharmaceutical and polymer synthesis. For example, using such compounds to prepare substituted para-polyphenylenes should proceed readily by metal-catalyzed aryl coupling of the 2,5-dichlorophenyl group of these compounds. Polyphenylenes formed from these compounds will have pendant side groups comprising the carbonyl, and the aryl or pyridyl group bonded thereto.

Synthesis

To a 22 L, three-necked flask fitted with a thermometer, mechanical stirrer and a Vigreux column connected to an aqueous NaOH scrubbing tower, was added 1,4-dichlorobenzene (3 Kg, 26.4 mol) and benzoyl chloride (2.6 Kg, 18.55 mol). The mixture was heated to 80° C. to give a homogeneous solution. Aluminum chloride (5.5 Kg, 41.25 mol) was added over 12 min. with stirring. (The molar ratio of reactants was 2.2:1.4:1.0 (AlCl3 : Dichlorobenzene: Benzoyl Chloride)). The resulting mixture was heated to 140° C. over 60 min, followed by heating to 175° C. over 30 min. The heating was stopped at 175° C. The mixture was allowed to cool to 80° C. over two hours and poured into a well-stirred mixture of ice and water (ca. 25 L water and 15 Kg of ice) over 30 min. The organic solid was collected by filtration and dissolved in 7 L of toluene. The solution was washed with aqueous sodium bicarbonate and dried. Toluene was removed by distillation. Pure 2,5-dichlorobenzophenone was isolated in 80% yield after recrystallization from hexane and toluene.

2,5-Dichlorobenzophenone Preparation Products And Raw materials

Raw materials

Preparation Products

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2,5-Dichlorobenzophenone Suppliers

Carbosynth
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Apollo Scientific Ltd.
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MOLEKULA Ltd.
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CARBONE SCIENTIFIC CO.,LTD
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Fluorochem Ltd
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Fluorochem Ltd.
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View Lastest Price from 2,5-Dichlorobenzophenone manufacturers

Hebei Yanxi Chemical Co., Ltd.
Product
2,5-Dichlorobenzophenone 16611-67-9
Price
US $0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20tons
Release date
2023-10-09
Hebei Mojin Biotechnology Co.,Ltd
Product
2,5-Dichlorobenzophenone 16611-67-9
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
50000KG/month
Release date
2024-09-26
Hebei Weibang Biotechnology Co., Ltd
Product
2,5-Dichlorobenzophenone 16611-67-9
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2022-10-08