3-(1,1,1-TRIBUTYLSTANNYL)PYRIDINE
- Product Name
- 3-(1,1,1-TRIBUTYLSTANNYL)PYRIDINE
- CAS No.
- 59020-10-9
- Chemical Name
- 3-(1,1,1-TRIBUTYLSTANNYL)PYRIDINE
- Synonyms
- SKL989;3-PYRIDYLTRI-N-BUTYLTIN;3-(tributyltin) pyridine;3-Pyridyltributylstannane;tributyl(3-pyridyl)stannane;3-(TRIBUTYLSTANNYL)PYRIDINE;3-PYRIDYLTRI-n-BUTYLTIN 95%;Pyridine,3-(tributylstannyl)-;tributyl(pyridin-3-yl)stannane;3-Tris(but-1-ylstannyl)pyridine
- CBNumber
- CB9701083
- Molecular Formula
- C17H31NSn
- Formula Weight
- 368.14
- MOL File
- 59020-10-9.mol
3-(1,1,1-TRIBUTYLSTANNYL)PYRIDINE Property
- Boiling point:
- 132°C 0,3mm
- Density
- 1,15 g/cm3
- Flash point:
- 110 °C
- storage temp.
- -20°C
- form
- liquid
- pka
- 5.21±0.12(Predicted)
- Specific Gravity
- 1.150
- color
- Dark brown
- Hydrolytic Sensitivity
- 7: reacts slowly with moisture/water
- Exposure limits
- ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3
Safety
- Hazard Codes
- T,Xi,N
- Risk Statements
- 20/21/22-36/37/38-50/53-48/23/25-36/38-25-21
- Safety Statements
- 26-36/37/39-61-60-45-35
- RIDADR
- UN 2788 6.1/PG 3
- WGK Germany
- 3
- TSCA
- No
- HazardClass
- IRRITANT, KEEP COLD, TOXIC
- HazardClass
- 6.1
- HS Code
- 29333990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H301Toxic if swalloed
H312Harmful in contact with skin
H315Causes skin irritation
H319Causes serious eye irritation
H372Causes damage to organs through prolonged or repeated exposure
H400Very toxic to aquatic life
H410Very toxic to aquatic life with long lasting effects
- Precautionary statements
-
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P309IF exposed or if you feel unwell:
P310Immediately call a POISON CENTER or doctor/physician.
P314Get medical advice/attention if you feel unwell.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- T4412
- Product name
- 3-(Tributylstannyl)pyridine
- Purity
- 90-95%
- Packaging
- 1g
- Price
- $7
- Updated
- 2021/12/16
- Product number
- 007393
- Product name
- 3-Tributylstannylpyridine
- Purity
- 93%
- Packaging
- 500mg
- Price
- $15
- Updated
- 2021/12/16
- Product number
- 007393
- Product name
- 3-Tributylstannylpyridine
- Purity
- 93%
- Packaging
- 1g
- Price
- $19
- Updated
- 2021/12/16
- Product number
- T4412
- Product name
- 3-(Tributylstannyl)pyridine
- Purity
- 90-95%
- Packaging
- 5g
- Price
- $24
- Updated
- 2021/12/16
- Product number
- 007393
- Product name
- 3-Tributylstannylpyridine
- Purity
- 93%
- Packaging
- 5g
- Price
- $79
- Updated
- 2021/12/16
3-(1,1,1-TRIBUTYLSTANNYL)PYRIDINE Chemical Properties,Usage,Production
Uses
3-Tributylstannylpyridine (CAS# 59020-10-9) can be used to prepare polyimide material that is resistant to atomic oxygen.
Synthesis
626-55-1
1461-22-9
59020-10-9
In a two-necked round-bottomed flask 0.5 mL (5.19 mmol) of 3-bromopyridine was dissolved in 25 mL of anhydrous ether and the reaction system was cooled to -78 °C. 3.89 mL (6.23 mmol) of n-butyllithium (1.6 M hexane solution) was slowly added dropwise and the reaction was stirred for 3 hours keeping the temperature at -78 °C. Subsequently, 1.55 mL (5.71 mmol) of tributyltin chloride was added and stirring was continued at -78°C for 30 minutes, then gradually warmed to room temperature and stirred for 12 hours. Upon completion of the reaction, the reaction was quenched by the addition of saturated aqueous ammonium chloride and extracted with ether. The organic layer was separated, dried with anhydrous magnesium sulfate and concentrated under reduced pressure to remove the solvent. Purification by column chromatography (eluent: hexane/ethyl acetate=9:1, v/v) afforded 1.58 g of the target product 3-(1,1,1-tributylmethylstannyl)pyridine as a clear oil (yield: 83%).
References
[1] Patent: KR2015/142709, 2015, A. Location in patent: Paragraph 0441-0443
[2] Patent: US6498159, 2002, B1
[3] Patent: US6599917, 2003, B1
[4] Tetrahedron, 2013, vol. 69, # 2, p. 902 - 909
[5] Advanced Synthesis and Catalysis, 2017, vol. 359, # 5, p. 832 - 840
3-(1,1,1-TRIBUTYLSTANNYL)PYRIDINE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 3-(1,1,1-TRIBUTYLSTANNYL)PYRIDINE manufacturers
- Product
- 3-(1,1,1-TRIBUTYLSTANNYL)PYRIDINE 59020-10-9
- Price
- US $2.00/KG
- Min. Order
- 1g
- Purity
- 98%min
- Supply Ability
- ask
- Release date
- 2020-01-08